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Abstract. Reliable quantification of the sources and sinks of greenhouse gases, together with trends and uncertainties, is essential to monitoring the progress in mitigating anthropogenic emissions under the Paris Agreement. This study provides a consolidated synthesis of CH4 and N2O emissions with consistently derived state-of-the-art bottom-up (BU) and top-down (TD) data sources for the European Union and UK (EU27+UK). We integrate recent emission inventory data, ecosystem process-based model results, and inverse modelling estimates over the period 1990–2018. BU and TD products are compared with European National GHG Inventories (NGHGI) reported to the UN climate convention secretariat UNFCCC in 2019. For uncertainties, we used for NGHGI the standard deviation obtained by varying parameters of inventory calculations, reported by the Member States following the IPCC guidelines recommendations. For atmospheric inversion models (TD) or other inventory datasets (BU), we defined uncertainties from the spread between different model estimates or model specific uncertainties when reported. In comparing NGHGI with other approaches, a key source of bias is the activities included, e.g. anthropogenic versus anthropogenic plus natural fluxes. In inversions, the separation between anthropogenic and natural emissions is sensitive to the geospatial prior distribution of emissions. Over the 2011–2015 period, which is the common denominator of data availability between all sources, the anthropogenic BU approaches are directly comparable, reporting mean emissions of 20.8 Tg CH4 yr−1 (EDGAR v5.0) and 19.0 Tg CH4 yr−1 (GAINS), consistent with the NGHGI estimates of 18.9 ± 1.7 Tg CH4 yr−1. TD total inversions estimates give higher emission estimates, as they also include natural emissions. Over the same period regional TD inversions with higher resolution atmospheric transport models give a mean emission of 28.8 Tg CH4 yr−1. Coarser resolution global TD inversions are consistent with regional TD inversions, for global inversions with GOSAT satellite data (23.3 Tg CH4yr−1) and surface network (24.4 Tg CH4 yr−1). The magnitude of natural peatland emissions from the JSBACH-HIMMELI model, natural rivers and lakes emissions and geological sources together account for the gap between NGHGI and inversions and account for 5.2 Tg CH4 yr−1. For N2O emissions, over the 2011–2015 period, both BU approaches (EDGAR v5.0 and GAINS) give a mean value of anthropogenic emissions of 0.8 and 0.9 Tg N2O yr−1 respectively, agreeing with the NGHGI data (0.9 ± 0.6 Tg N2O yr−1). Over the same period, the average of the three total TD global and regional inversions was 1.3 ± 0.4 and 1.3 ± 0.1 Tg N2O yr−1 respectively, compared to 0.9 Tg N2O yr−1 from the BU data. The TU and BU comparison method defined in this study can be operationalized for future yearly updates for the calculation of CH4 and N2O budgets both at EU+UK scale and at national scale. The referenced datasets related to figures are visualized at https://doi.org/10.5281/zenodo.4288969 (Petrescu et al., 2020).

This paper deals the study of the lead-acid behavior and its modelling based on the Kinetic Battery Model. Results of experimental tests are used to realize the analysis and to estimate the model parameters. These last can serve for prediction and estimation of the battery lifetime according to the actual operating conditions.

Abstract Floods are challenging the resilience of societies all over the world. In many countries there are discussions on diversifying the strategies for flood risk management, which implies some sort of policy change. To understand the possibilities of such change, a thorough understanding of the forces of stability and change of underlying governance arrangements is required. It follows from the path dependency literature that countries which rely strongly on flood infrastructures, as part of flood defense strategies, would be more path dependent. Consequently there is a higher chance to find more incremental change in these countries than in countries that have a more diversified set of strategies. However, comparative and detailed empirical studies that may help scrutinize this assumption are lacking. To address this knowledge gap, this paper investigates how six European countries (Belgium, England, France, The Netherlands, Poland and Sweden) essentially differ with regard to their governance of flood risks. To analyze stability and change, we focus on how countries are responding to certain societal and ecological driving forces (ecological turn; climate change discourses; European policies; and the increasing prevalence of economic rationalizations) that potentially affect the institutional arrangements for flood risk governance. Taking both the variety of flood risk governance in countries and their responses to driving forces into account, we can clarify the conditions of stability or change of flood risk governance arrangements more generally. The analysis shows that the national-level impact of driving forces is strongly influenced by the flood risk governance arrangements in the six countries. Path dependencies are indeed visible in countries with high investments in flood infrastructure accompanied by strongly institutionalized governance arrangements (Poland, the Netherlands) but not only there. Also more diversified countries that are less dependent on flood infrastructure and flood defense only (England) show path dependencies and mostly incremental change. More substantial changes are visible in countries that show moderate diversification of strategies (Belgium, France) or countries that ‘have no strong path yet’ in comprehensive flood risk governance (Sweden). This suggests that policy change can be expected when there is both the internal need and will to change and a barrage of (external) driving forces pushing for change.

Ambitious international targets are being developed to protect and restore biodiversity under the Convention on Biological Diversity's post-2020 Global Biodiversity Framework and the European Union's Green Deal. Yet, the land system consequences of meeting such targets are unclear, as multiple pathways may be able to deliver on the set targets. This paper introduces a novel scenario approach assessing the plural implementations of these targets. The Nature Futures Framework (NFF) developed by the Intergovernmental Science-Policy Platform on Biodiversity and Ecosystem Services aims to illustrate the different, positive ways in which society can value nature. It therefore offers a lens through which the spatial implementation of sustainability targets may be envisioned. We used CLUMondo, a spatially explicit model, to simulate plural land system scenarios for Europe for 2050. The model builds on current land system representations of Europe and explores how and where sustainability targets can be implemented under projected population trends and commodity demands. We created three different scenarios in which the sustainability targets are met, each representing an alternative, normative view on nature as represented by the NFF, favoring land systems providing strong climate regulation (Nature for Society), species conservation (Nature for Nature), or agricultural heritage features (Nature as Culture). Our results show that, irrespective of the NFF view, meeting sustainability targets will require European land systems to drastically change, as natural grasslands and forests are forecast to expand while productive areas are projected to undergo a dual intensification and diversification trajectory. Despite each NFF perspective showcasing a similar direction of change, 20% of Europe's land area will differ based on the adopted NFF perspective, with hotspots of disagreement identified in eastern and western Europe. These simulations go beyond existing scenario approaches by not only depicting broad societal developments for Europe, but also by quantifying the land system synergies and trade-offs associated with alternative, archetypal, interpretations and values of how nature may be managed for sustainability. This quantification exemplifies a means towards constructive dialogue, on the one hand by acknowledging areas of contention, and bringing such issues to the fore, and on the other by highlighting points of convergence in a vision for a sustainable Europe.

Thermal energy storage systems (TES) based on shape-stabilized phase change materials (SSPCM) designed from recycled Tetra Pak (TP) waste, paraffin wax (PW), and expanded graphite (EG) were investigated in this study. This work represents the first study to explore TP waste composed of low-density polyethylene (LDPE)/aluminum (Al) components for energy storage applications. The LDPE part serves as a matrix conserving a material in a compact, solid shape after PW melting; PW acts as an active phase change component contributing to heat absorption/release through a phase change (from a solid to a liquid state, and vice versa) of its crystalline phase. EG serves as a filler that enhances the thermal conductivity and mechanical properties of materials. The focus was put on the optimization of the composition of SSPCM including PW, and EG, to check thermal, mechanical, and rheological properties which influence the future processability of such systems through extrusion, as well as to investigate the synergic effect of graphite and residual Al component on thermal conductivity and leakage of PW. There are two main demands on polymer/PW blends, namely well-separated melting peaks for both components at significantly different temperatures, and good compatibility between polymer and PW. The best performance of SSPCM investigated in this study was found for a mixture having the composition TP/PW/EG = 50/40/10 w/w/w. This mixture shows well-balanced properties, including appropriate heat storage and release parameters, thermal conductivity, thermal diffusivity, toughness and strength, and low leakage of PW from the material. This system can store 116.2 J/g of heat energy and release 93.8 J/g of heat energy. The determination of the heat energy storage and release was performed by the transient guarded hot plate technique. Tensile testing revealed that Young's modulus of the TP/PW/EG = 50/40/10 w/w/w composition was 924 ± 71 MPa and the stress at break was 8.2 ± 1.2 MPa, which are sufficient values from the applicability ...

We summarize and critically evaluate the available data on nuclear fusion cross sections important to energy generation in the Sun and other hydrogen-burning stars and to solar neutrino production. Recommended values and uncertainties are provided for key cross sections, and a recommended spectrum is given for 8B solar neutrinos. We also discuss opportunities for further increasing the precision of key rates, including new facilities, new experimental techniques, and improvements in theory. This review, which summarizes the conclusions of a workshop held at the Institute for Nuclear Theory, Seattle, in January 2009, is intended as a 10-year update and supplement to Reviews of Modern Physics 70 (1998) 1265. 54 pages, 20 figures, version to be published in Reviews of Modern Physics; various typos corrected and several updates made

Thermal performance of phase change material (PCM) glazing unit in summer under different climatic conditions is studied by numerical simulation in this paper. Through analyzing the data of meteorological stations in all provinces of China, the law that strong solar radiation (SR) will be accompanied by large diurnal temperature range (DTR) and weak SR will be accompanied by small DTR is discovered. Taking the inner surface temperature of glazing unit ($T_{sur}$) and total heat flow entering indoor side through glazing unit ($Q_{total}$) as the evaluation indexes, the applicability of PCM glazing unit under twelve different working conditions of strong SR with large DTR and weak SR with small DTR is analyzed. The results show that, from the point of view of $T_{sur}$, PCM glazing unit has better thermal performance than ordinary double-layer glazing unit under all working conditions ($T_{sur}$ is reduced by 1 \% - 19 \%). In addition, compared with the conditions of weak SR and small DTR ($T_{sur}$ is reduced by 6 \% on average), PCM glazing unit is more applicable under conditions of strong SR and large DTR ($T_{sur}$ is reduced by 13 \% on average). From the perspective of $Q_{total}$, PCM glazing unit still shows a better thermal performance than ordinary double-layer window unit ($Q_{total}$ is decreased by 4 \%-80 \%). Different from the conclusions when $T_{sur}$ is used as the evaluation index, PCM glazing unit seems to be more suitable for the condition of weak SR and small DTR ($Q_{total}$ is decreased by 35 \% on average) rather than strong SR and large DTR conditions ($Q_{total}$ is decreased by 26 \% on average). This may be the result of inappropriate thickness of the PCM layer in this simulation, resulting in insufficient heat storage capacity of PCM glazing unit to meet the intensity of SR. Therefore, the heat storage capacity of PCM should be matched with outdoor meteorological parameters to avoid excessive use of PCM (will make increasing costs and deteriorating indoor light environment) or inadequate amount of PCM (PCM will melts prematurely and does not conducive to indoor thermal environment).

The co-production of biohydrogen and methane from the organic fraction of municipal solid waste was investigated using a two-stage AD system, composed of a pilot scale dark fermenter (DF) and a continuous methanogenic biofilm reactor. From the DF process, a biohydrogen yield of 41.7 (± 2.3) ml H2/gVSadded was achieved. The liquid DF effluent (DFE) was rich in short chain volatile fatty acids, i.e., mainly acetic and butyric acid. The DFE was valorized by producing methane in the methanogenic biofilm reactor. Two methanogenic biofilm reactors were used to assess the biotic and abiotic role of the DFE on the performance of the reactors. Regardless of the different DFE feeding (i.e., biotic and abiotic), similar and stable operational performance of the two methanogenic biofilm reactors were observed with a respective methane yield and COD removal efficiency of 280–300 ml CH4/gCODremoved and 80–90%. Both methanogenic biofilm reactors showed significant resistance toward organic shock loads and recovered fast after reactor disturbance. The total estimated energy recovered in the form of hydrogen and methane gas was, respectively, 28 and 72%, of the initial COD.HIGHLIGHTSSimultaneous production of biohydrogen and methane from OFMSW was investigated.A pilot scale dark fermenter and methanogenic biofilm reactor were used for, respectively, biohydrogen and methane production.The biotic and abiotic role of the dark fermentation effluent on the methanogenic biofilm reactor was assessed.Anaerobic biofilm reactors demonstrated a high tolerance toward an increased OLR.H2 and CH4 was 28 and 72%, respectively, of the total energy recovery from the OFMSW.