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AbstractEarthworms may promote the biodegradation of polycyclic aromatic hydrocarbons (PAHs) in soil, but the mechanism through which they exert such influence is still unknown. To determine if the stimulation of PAH degradation by earthworms is related to changes in microbial communities, a microcosm experiment was conducted consisting of columns with natural uncontaminated soil covered with PAH‐contaminated dredge sediment. Columns without and with low and high Eisenia andrei densities were prepared. Organic matter and PAH content, microbial biomass, and dehydrogenase activity (DHA) were measured in soil and sediment over time. Biolog Ecoplate™ and polymerase chain reaction using denaturing gradient gel electrophoresis were used to evaluate changes in metabolic and structural diversity of the microbial community, respectively. Earthworm activity promoted PAH degradation in soil, which was significant for biphenyl, benzo[a]pyrene, and benzo[e]pyrene. Microbial biomass and DHA activity generally did not change over the experiment. Earthworm activity did change microbial community structure, but this did not affect its functioning in terms of carbon substrate consumption. Results suggest no relationship between changes in the microbial community by earthworm activity and increased PAH disappearance. The role of shifts in soil microbial community structure induced by earthworms in PAH removal needs further investigation. Environ. Toxicol. Chem. 2012;31:794–803. © 2011 SETAC

The Indian Ocean Experiment (INDOEX) was an international, multiplatform field campaign to measure long-range transport of air pollution from South and Southeast Asia toward the Indian Ocean during the dry monsoon season in January to March 1999. Surprisingly high pollution levels were observed over the entire northern Indian Ocean toward the Intertropical Convergence Zone at about 6°S. We show that agricultural burning and especially biofuel use enhance carbon monoxide concentrations. Fossil fuel combustion and biomass burning cause a high aerosol loading. The growing pollution in this region gives rise to extensive air quality degradation with local, regional, and global implications, including a reduction of the oxidizing power of the atmosphere.

Major reorganizations in climate and tectonic regime occurred in East Asia during the Pleistocene, resulting in large-scale environmental changes. In this paper a detailed geochemical and mineralogical record of these changes is presented from a distal alluvial fan sedimentary sequence in the northern Weihe Basin. We established that, in addition to glacial-interglacial variation, there are three distinctly different units deposited over the past 1 m.y. These units are the result of variations in the overall tectonic regime in the northern Weihe Basin. Fine-grained detrital minerals were predominantly delivered during colder climatic periods, whereas evaporative minerals were dominantly deposited during the warmer, interglacial periods, probably as a result of strong seasonal contrast. This compositional variation demonstrates the importance of climate control on hinterland erosion, surface runoff, chemical weathering and evaporation. Al-normalized ratios of indicative major elements relative to average loess composition, indicate important variations in sedimentary processes, mostly related to sediment flux. Si-enrichment is an index for past flooding events, while Fe enrichment, just like K and Ti, reflects influx of clays. In contrast, Ca and Mn are strongly enriched throughout the core, associated with the authigenic precipitation of carbonates, especially during interglacial periods. The lower (~ 1000–690 ka) and upper (~ 330–0 ka) units of the core are characterized by relative intense and frequent flooding, which coincided with extensive ponding in the study area. In the middle unit (~ 690–330 ka) increased salinity levels caused by evaporation, as reflected in the high Sr/Ca ratio and dolomite abundance, led to increased carbonate precipitation. Simultaneously, the increased influx of fine sediments indicates increased clay production in the source area as a result of a more intense summer monsoon strength after 600 ka. © 2017 Elsevier B.V.

This paper studies the initiation of a partnership between a corporation and a nongovernmental organization (NGO) for environmentally sustainable innovation, as well as its development over time. Proceeding from a dynamic capabilities approach, it provides a retrospective, longitudinal examination of a 10-year partnership between KLM Royal Dutch Airlines (KLM) and the World Wildlife Fund for Nature Netherlands (WNF), which promoted a market for aviation biofuels. The case study suggests that the progress of the partnership is determined by three specific dynamic capabilities of KLM and WNF: learning, coordination, and reconfiguration. The results reveal two microfoundations for each of these dynamic capabilities. For learning, these microfoundations are the sensing of strategic partners and the co-specialization of resources. For coordination, these consist of finding a fit between partners and having an integrated mission. Finally, the microfoundations of reconfiguration are the fostering of an institutional dialogue and the setting of new industry standards. This study is beneficial to scholars as it opens a research avenue concerning the dynamic capabilities and microfoundations that support corporate-NGO partnering for environmentally sustainable innovation. Practitioners can use these dynamic capabilities and microfoundations as guidelines for developing their own specific corporate-NGO partnerships.

Better prediction of turbulent airflow around urban trees is necessary because it impacts urban pollutant dispersion, outdoor thermal comfort, energy efficiency, pedestrian-level comfort and urban heat island mitigation. A major challenge is how to obtain an accurate numerical model of the turbulent flow field around trees and an improved parameterization of the turbulent momentum deficit using the drag coefficient (Cd). To address this challenge, we use wind tunnel tests and real trees to measure Cd for four common subtropical tree species: Ficus microcarpa, Mangifera indica, Michelia alba and Bauhinia blakeana. The results show that the Cd of the four trees ranges from 0.523 to 0.932, and that the negative relationship between Cd and wind speed (U) can be expressed by the exponential formula Cd=a*U−b. A three-dimensional model of wind modification by trees is proposed, and its accuracy is verified with wind tunnel measurements. With precise Cd and model, the predictability of the influence of trees on urban wind in subtropical areas is enhanced (root mean square error RMSE ranging from 2.89 m/s to 0.45 m/s). Future development and applications of the numerical model will help provide useful guidelines for urban landscape management and sustainable urban planning in terms of urban ventilation.

Hybrid life cycle assessment (LCA), through combining input-output (IO) models and process-based LCA for a complete system boundary, is widely recognized as a more accurate approach than process-based LCA with an incomplete system boundary. Without a complete process model for verification, however, the performance of hybrid LCA remains unclear. Here, using a counterexample we show that hybrid LCA does not necessarily provide more accurate results than process-based LCA, simply because the aggregation of heterogeneous processes in IO models may introduce more errors. In so doing, we prove that only when IO-based LCA and process-based LCA have the same level of detail would they yield the same results. Whether hybrid LCA provides more accurate estimates depends on whether the IO model introduced serves as an adequate proxy for the missing products as opposed to if they were estimated by a complete process model. The use of a highly-aggregated IO model runs the risk of overestimation, and could result in a larger relative error than the truncation error resulting from an incomplete process model. Our study seeks to provide a balanced view of hybrid LCA, and our findings offer important insights for future hybrid LCA studies to improve the accuracy and realm of applicability of the approach.

Devolatilization and oxidation kinetics of torrefied wood have been studied by evaluating thermogravimetric curves measured in nitrogen and air at various heating rates. Samples consist of Norway spruce wood chips torrefied at several process temperatures and residence times. Data about untreated wood have also been obtained for comparison. Measured curves are well predicted by means of a five-reaction mechanism, consisting of three devolatilization reactions for the pseudo-components hemicellulose, cellulose and lignin and, in air, of two additional reactions for char devolatilization and combustion. The torrefaction pre-treatment only requires model modifications in the amounts of volatiles generated from the decomposition of pseudo-components, indicating that only their relative percentages and not their reactivities are modified. On the other hand, a slightly different thermal stability is found for the char generated from torrefied wood, which results in higher activation energy and lower reaction order for the oxidation step. Hence torrefaction conditions can affect the subsequent conversion characteristics of the char product.