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Technological change has altered labor market demands within well-developed societies implying global competition for skilled labor and, as a consequence, new forms of labor migration. So far, patterns of this labor migration have been underexplored. Thus, the article analyzes characteristics, geographies and possible underlying drivers of workers migrating from Germany as an exemplary case for a well-developed country. Relying on probability-based and unique data, our findings reveal that, besides demand for people with higher levels of education, performing specific occupational tasks is also in demand in the global competition for talent. Hence, Germans in jobs with a high proportion of analytical non-routine tasks are more likely to emigrate than those with predominantly manual routine tasks. Moreover, the results show that global discrepancies concerning the technological development between the country of origin and the country to which they emigrate are a crucial contextual driver attracting this specifically demanded work force. Workers mainly performing analytical non-routine tasks within their job tend to move to countries which are technologically more developed than Germany while individuals performing jobs with a high share of non-routine manual or interactive tasks tend to emigrate to countries that are less technologically developed than Germany.

Hybrid electric propulsion in the aviation field is becoming an effective alternative propulsion technology with potential advantages, including fuel savings, lower pollution, and reduced noise emission. On the one hand, the aeroengine manufacturers are working to improve fuel consumption and reduce pollutant emissions with new combustion systems; on the other hand, much attention is given to reducing the weight of the batteries increasing the energy density. Hybrid electric propulsion systems (HEPS) can take advantage of the synergy between two technologies by utilizing both internal combustion engines (ICEs) and electric motors (EMs) together, each operating at their respective optimum conditions. In the present work, some numerical investigations were carried out by using a zero-dimensional code able to simulate the flight mission of a turboprop aircraft, comparing fuel consumption and pollutant emissions of the original engine with other two smaller gas turbines working in hybrid configuration. An algorithm has been implemented to calculate the weight of the batteries for the different configurations examined, evaluating the feasibility of the hybrid propulsion system in terms of number of non-revenue passengers.

In this paper, the modifications realized to make optically accessible a commercial high performance spark ignition and direct injection (DI) 4-cylinder engine are reported. The engine has been designed trying to keep as much as possible its thermo-fluid dynamic configuration in order to maintain its performance and emissions. Two optical accesses have been realized in order to interfere as little as possible with the combustion chamber geometry. A first optical access has been achieved in the piston head and a second by inserting an endoscopic fiber probe in the head. Preliminary results demonstrated that this optical assessment responds to the design targets and allowed a characterization of a commercial GDI engine working with homogeneous and stratified charge mode.

As Earth’s climate has varied strongly through geological time, studying the impacts of past climate change on biodiversity helps to understand the risks from future climate change. However, it remains unclear how paleoclimate shapes spatial variation in biodiversity. Here, we assessed the influence of Quaternary climate change on spatial dissimilarity in taxonomic, phylogenetic, and functional composition among neighboring 200-kilometer cells (beta-diversity) for angiosperm trees worldwide. We found that larger glacial-interglacial temperature change was strongly associated with lower spatial turnover (species replacements) and higher nestedness (richness changes) components of beta-diversity across all three biodiversity facets. Moreover, phylogenetic and functional turnover was lower and nestedness higher than random expectations based on taxonomic beta-diversity in regions that experienced large temperature change, reflecting phylogenetically and functionally selective processes in species replacement, extinction, and colonization during glacial-interglacial oscillations. Our results suggest that future human-driven climate change could cause local homogenization and reduction in taxonomic, phylogenetic, and functional diversity of angiosperm trees worldwide.

Abstract District heating dynamic models arise as an alternative approach to in-situ experimental investigations. The main advantage of dynamic modeling and simulation is the possibility to avoid technical and operational risks that might occur during in-situ experimental investigations (e.g. heat demand is not met, damages in the energy systems etc.). Within this study, the authors present two models for an existing district heating system in Cottbus, Germany. One model is developed using the tool EBSILON Professional, while the other one is developed using the Simscape toolbox for physical modeling in Matlab/Simulink. The models were experimentally validated against measured data from the considered district heating system. The results show that the Simscape model has a better fit and better response than the EBSILON model. Yet, some discrepancies were found between the measured and the simulated data and, therefore, the uncertainties of the models were addressed. A comparative study between both tools is presented. The EBSILON models permit only unidirectional flow, whereas the Simscape toolbox permits reverse flow. Nevertheless, the EBSILON model outperforms the Simscape model in computation time. In addition, this study presents an approach for dynamic thermo-hydraulic modeling of district heating networks. This approach is utilized to examine the role of district heating networks as heat storage as an optimization configuration. The numerical results show less start-ups for additional heat sources. Yet, higher heat losses from the network are observed due to the installation of unburied pipelines.

The possibility of artificially inducing activation of MII buffalo oocytes may allow us to evaluate indirectly the quality of oocytes after in vitro maturation. The aim of this work was to compare buffalo embryo development after IVF and after chemical activation by two different agents. A further goal was to evaluate the effects of aging of oocytes on post-parthenogenetic and post-fertilization development. In Experiment 1 cumulus-oocyte complexes (COCs) were recovered from abattoir-derived ovaries and matured in vitro. After IVM the COCs were either fertilized in vitro (positive control) or activated with ethanol and ionomycin, both followed by immediate exposure to 6-diethylaminopurine (6-DMAP) for 4 h. In vitro culture (IVC) was carried out up to the blastocyst stage. In Experiment 2 COCs were matured in vitro for 18, 21, 24, 27 and 30 h before activation was triggered with ethanol, followed by 6-DMAP. In Experiment 3 COCs were fertilized in vitro at 18, 21, 24, 27 and 30 h post-maturation. Ethanol activation gave better results than the IVF control group, with higher cleavage rate (71.4 +/- 7.8 versus 55.8 +/- 5.8, respectively; P < 0.05) and a higher proportion of oocytes developing into morulae-blastocysts (32.6 +/- 6.5 versus 22.9 +/- 7.5, respectively; P < 0.05). Within the activation groups, ethanol supported the highest development in terms of cleavage (71.4 +/- 7.8 versus 59.4 +/- 10.7; P < 0.05) and morulae-blastocysts rate (32.6 +/- 6.5 versus 25.7 +/- 8.3; n.s.). It was also demonstrated that aging negatively affects post-parthenogenetic and post-fertilization development.

In this work, a vibro-acoustic numerical and experimental analysis was carried out for the chain cover of a low powered four-cylinder four-stroke diesel engine, belonging to the FPT (FCA Power Train) family called SDE (Small Diesel Engine). By applying a methodology used in the acoustic optimization of new FPT engine components, firstly a finite element model (FEM) of the engine was defined, then a vibration analysis was performed for the whole engine (modal analysis), and finally a forced response analysis was developed for the only chain cover (separated from the overall engine). The boundary conditions applied to the chain cover were the accelerations experimentally measured by accelerometers located at the points of connection among chain cover, head cover, and crankcase. Subsequently, a boundary element (BE) model of the only chain cover was realized to determine the chain cover noise emission, starting from the previously calculated structural vibrations. The numerical vibro-acoustic outcomes were compared with those experimentally observed, obtaining a good correlation. All the information thus obtained allowed the identification of those critical areas, in terms of noise generation, in which to undertake necessary improvements.

Cytochrome bc 1 complexes are ubiquinol:cytochrome c oxidoreductases, and as such, they are centrally important components of respiratory and photosynthetic electron transfer chains in many species of bacteria and in mitochondria. The minimal complex has three catalytic components, which are cytochrome b , cytochrome c 1 , and the Rieske iron–sulfur subunit, but the function of mitochondrial cytochrome bc 1 complexes is modified by up to eight supernumerary subunits. The cytochrome bc 1 complex from the purple phototrophic bacterium Rhodobacter sphaeroides has a single supernumerary subunit called subunit IV, which is absent from current structures of the complex. In this work we use the styrene–maleic acid copolymer to purify the R. sphaeroides cytochrome bc 1 complex in native lipid nanodiscs, which retains the labile subunit IV, annular lipids, and natively bound quinones. The catalytic activity of the four-subunit cytochrome bc 1 complex is threefold higher than that of the complex lacking subunit IV. To understand the role of subunit IV, we determined the structure of the four-subunit complex at 2.9 Å using single particle cryogenic electron microscopy. The structure shows the position of the transmembrane domain of subunit IV, which lies across the transmembrane helices of the Rieske and cytochrome c 1 subunits. We observe a quinone at the Q o quinone-binding site and show that occupancy of this site is linked to conformational changes in the Rieske head domain during catalysis. Twelve lipids were structurally resolved, making contacts with the Rieske and cytochrome b subunits, with some spanning both of the two monomers that make up the dimeric complex.