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Polycyclic aromatic hydrocarbons (PAHs) are airborne pollutants that are deposited on soils. As climate change is already altering temperature and solar radiation, the global warming is suggested to impact the environmental fate of PAHs. This study was aimed at evaluating the effect of climate change on the PAH photodegradation in soils. Samples of Mediterranean soils were subjected to different temperature and light radiation conditions in a climate chamber. Two climate scenarios were considered according to IPCC projections: 1) a base (B) scenario, being temperature and light intensity 20°C and 9.6W/m(2), respectively, and 2) a climate change (CC) scenario, working at 24°C and 24W/m(2), respectively. As expected, low molecular weight PAHs were rapidly volatilized when increasing both temperature and light intensity. In contrast, medium and high molecular weight PAHs presented different photodegradation rates in soils with different texture, which was likely related to the amount of photocatalysts contained in both soils. In turn, the hydrogen isotopic composition of some of the PAHs under study was also investigated to verify any degradation process. Hydrogen isotopes confirmed that benzo(a)pyrene is degraded in both B and CC scenarios, not only under light but also in the darkness, revealing unknown degradation processes occurring when light is lacking. Potential generation pathways of PAH photodegradation by-products were also suggested, being a higher number of metabolites formed in the CC scenario. Consequently, in a more or less near future, although humans might be less exposed to PAHs, they could be exposed to new metabolites of these pollutants, which might be even more toxic.

AbstractFloating photovoltaic system for reservoirs is a recent innovative technology that is highly advantageous in reducing evaporation while generating solar power. In addition, the integration of floating photovoltaic systems with the existing hydroelectric power plants will increase renewable power production. The present study aims to assess the electrical performance of floating photovoltaic systems in major reservoirs with existing hydroelectric power plants in India. The reservoirs with large water surface area were selected for the study, and a model floating photovoltaic system with a 5-MW capacity was designed for the selected reservoirs. The numerical analysis showed that installing floating photovoltaic systems will result in an annual energy yield of 160 GWh. Further, the systems also save 1.40 million cubic meters of water per day and also help in generating additional energy of 514.80 MWh/day from the saved water through its integration with hydroelectric power plants. A single-axis tracking mechanism to the floating photovoltaic systems will increase the annual energy generation by 11%. The detailed cost analysis and carbon emission analysis were also carried out. The results indicate that the tracking mechanisms increase the total installation cost of the systems. The annual carbon emission reduction from the floating photovoltaic systems accounts for about 3.30 million tons of CO2. The obtained results highlight the suitability of this innovative technology for installation in Indian reservoirs and its effectiveness in reducing evaporation and carbon emission. Graphic abstract

In this paper we argue for the need to apply a cognitive approach to understand deep dynamics and determinants of technological evolutions. After examining main contributions from innovation studies to the conceptualization of innovation and change in complex socio-technical environments, we highlight the contribution coming from the application of the cognitive approach to evolutionary studies on technologies and we introduce the concept of technological memory as an interpretative tool to understand those changes. We discuss our hypothesis with reference to several observations carried out in different local contexts – Mexico, India and Italy – in relation to technological change in the water sector. In those cases deliberate attempts to substitute traditional technologies with modern ones led to interesting trajectories of change ranging from the collapse of old technologies to the development of multifaceted hybridization patterns. Tema. Journal of Land Use, Mobility and Environment, 2014: INPUT 2014 - Smart City: planning for energy, transportation and sustainability of the urban system

Syngas (CO, CO2, and H2) has attracted special attention due to the double benefit of syngas fermentation for carbon sequestration (pollution reduction), while generating energy. Syngas can be either produced by gasification of biomasses or as a by-product of industrial processes. Only few microorganisms, mainly clostridia, were identified as capable of using syngas as a substrate to produce medium chain acids, or alcohols (such as butyric acid, butanol, hexanoic acid, and hexanol). Since CO plays a critical role in the availability of reducing equivalents and carbon conversion, this work assessed the effects of constant CO partial pressure (PCO), ranging from 0.5 to 2.5 atm, on cell growth, acid production, and solvent production, using Clostridium carboxidivorans. Moreover, this work focused on the effect of the liquid to gas volume ratio (VL/VG) on fermentation performances; in particular, two VL/VG were considered (0.28 and 0.92). The main results included—(a) PCO affected the growth kinetics of the microorganism; indeed, C. carboxidivorans growth rate was characterized by CO inhibition within the investigated range of CO concentration, and the optimal PCO was 1.1 atm (corresponding to a dissolved CO concentration of about 25 mg/L) for both VL/VG used; (b) growth differences were observed when the gas-to-liquid volume ratio changed; mass transport phenomena did not control the CO uptake for VL/VG = 0.28; on the contrary, the experimental CO depletion rate was about equal to the transport rate in the case of VL/VG = 0.92.

Nitrogen is an element present on Earth in different forms, such as gaseous in the air, dissolved in water, immobilized in the soil, as well as biologically bound in all living organisms. The transition from one form to another constitutes the nitrogen cycle. Current agricultural systems rely on nitrogen fertilizers, which represent the reactive or biologically available nitrogen in soil. The excessive presence of reactive nitrogen in the environment has become a threat to soil, water, and air. The increasing demands for food in the world are associated with significant increase in nitrogen fertilizers inputs which threatens the environment and living organisms. The quantities of nitrogen used per capita in developed countries exceed those in developing countries. However, developed countries are regulated by restrictions of fertilizers inputs in agriculture, whereas such regulations do not exist in most of the developing countries. The need to resort to alternative and eco-sustainable strategies to mitigate the pollution related to human activities, is increasingly evident. This review aims to highlight the fate of nitrogen through the main agricultural practices in modern agriculture. Special attention was given to rocket (Eruca sativa) which is considered a nitrate hyper-accumulator and was used as a case study in the present review. Finally, some eco-sustainable solutions, useful for mitigating or preventing the excessive release of harmful forms of nitrogen into the environment, were also discussed.

The co-production of biohydrogen and methane from the organic fraction of municipal solid waste was investigated using a two-stage AD system, composed of a pilot scale dark fermenter (DF) and a continuous methanogenic biofilm reactor. From the DF process, a biohydrogen yield of 41.7 (± 2.3) ml H2/gVSadded was achieved. The liquid DF effluent (DFE) was rich in short chain volatile fatty acids, i.e., mainly acetic and butyric acid. The DFE was valorized by producing methane in the methanogenic biofilm reactor. Two methanogenic biofilm reactors were used to assess the biotic and abiotic role of the DFE on the performance of the reactors. Regardless of the different DFE feeding (i.e., biotic and abiotic), similar and stable operational performance of the two methanogenic biofilm reactors were observed with a respective methane yield and COD removal efficiency of 280–300 ml CH4/gCODremoved and 80–90%. Both methanogenic biofilm reactors showed significant resistance toward organic shock loads and recovered fast after reactor disturbance. The total estimated energy recovered in the form of hydrogen and methane gas was, respectively, 28 and 72%, of the initial COD.HIGHLIGHTSSimultaneous production of biohydrogen and methane from OFMSW was investigated.A pilot scale dark fermenter and methanogenic biofilm reactor were used for, respectively, biohydrogen and methane production.The biotic and abiotic role of the dark fermentation effluent on the methanogenic biofilm reactor was assessed.Anaerobic biofilm reactors demonstrated a high tolerance toward an increased OLR.H2 and CH4 was 28 and 72%, respectively, of the total energy recovery from the OFMSW.

Abstract This ‘reflective practice’ presents and critically describes the case of the “Schools for Tourism” (CAT), a case of promoting tourism and tourist culture in Colombian public schools through early vocational training, reporting the idea, development, outreach, and achievements of this program, as this initiative has experienced significant growth over the last few years. The methodology to this paper is of qualitative nature, i.e. primary literature sources as well as a focus group with high-school students and in-depth interviews with initiators of the project were carried out. Appraisals on the ground suggest that teachers' enthusiasm and commitment are primary factors driving the success of this kind of tourism and hospitality training programs, as is the support given to the teachers implementing CAT. More funding (in form of college scholarships or loans) would be very welcome. While the program's benefits are more than clear to all of the stakeholders, a thorough evaluation is still to be carried out so as to fully assess the benefits but also the weaknesses of the program.

School violence and bullying re worrying problems due to their growing prevalence and severe consequences for adolescent and youth health and wellbeing. Sociocultural factors can contribute to, complicate, and increase the cases of violence in classrooms and spaces related to educational centers. Transphobic violence in this article is defined as the type of violence suffered by transgender and nonbinary adolescents and youth as a manifestation of the problem of discrimination and hate against gender and sexual diversity. This work intends to study the complex sociocultural dynamics of violence detected in educational contexts affecting transgender and nonbinary adolescents and youth identified by recent high- impact studies. At the same time, we aim to fill the gap in the scientific literature on transphobic violence and articulate successful strategies to prevent and combat it. In this review, transphobic violence is defined as the violence affecting transgender adolescents and youth, continuous in time, influenced by peers, and taking place in spaces or realities related to educational centers. The reviewed studies point at the complexity of this kind of violence due to the combination of socio-personal factors and its variety in manifestations. Furthermore, we study the consequences of transphobic violence for the wellbeing and health of transgender and nonbinary adolescents and youth to deepen the knowledge of their mental health repercussions. We end by providing suggestions for how this problem can be prevented in educational environments, grounded on scientific evidence in the materialization of a transformative approach.