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Abstract. Reliable quantification of the sources and sinks of greenhouse gases, together with trends and uncertainties, is essential to monitoring the progress in mitigating anthropogenic emissions under the Paris Agreement. This study provides a consolidated synthesis of CH4 and N2O emissions with consistently derived state-of-the-art bottom-up (BU) and top-down (TD) data sources for the European Union and UK (EU27+UK). We integrate recent emission inventory data, ecosystem process-based model results, and inverse modelling estimates over the period 1990–2018. BU and TD products are compared with European National GHG Inventories (NGHGI) reported to the UN climate convention secretariat UNFCCC in 2019. For uncertainties, we used for NGHGI the standard deviation obtained by varying parameters of inventory calculations, reported by the Member States following the IPCC guidelines recommendations. For atmospheric inversion models (TD) or other inventory datasets (BU), we defined uncertainties from the spread between different model estimates or model specific uncertainties when reported. In comparing NGHGI with other approaches, a key source of bias is the activities included, e.g. anthropogenic versus anthropogenic plus natural fluxes. In inversions, the separation between anthropogenic and natural emissions is sensitive to the geospatial prior distribution of emissions. Over the 2011–2015 period, which is the common denominator of data availability between all sources, the anthropogenic BU approaches are directly comparable, reporting mean emissions of 20.8 Tg CH4 yr−1 (EDGAR v5.0) and 19.0 Tg CH4 yr−1 (GAINS), consistent with the NGHGI estimates of 18.9 ± 1.7 Tg CH4 yr−1. TD total inversions estimates give higher emission estimates, as they also include natural emissions. Over the same period regional TD inversions with higher resolution atmospheric transport models give a mean emission of 28.8 Tg CH4 yr−1. Coarser resolution global TD inversions are consistent with regional TD inversions, for global inversions with GOSAT satellite data (23.3 Tg CH4yr−1) and surface network (24.4 Tg CH4 yr−1). The magnitude of natural peatland emissions from the JSBACH-HIMMELI model, natural rivers and lakes emissions and geological sources together account for the gap between NGHGI and inversions and account for 5.2 Tg CH4 yr−1. For N2O emissions, over the 2011–2015 period, both BU approaches (EDGAR v5.0 and GAINS) give a mean value of anthropogenic emissions of 0.8 and 0.9 Tg N2O yr−1 respectively, agreeing with the NGHGI data (0.9 ± 0.6 Tg N2O yr−1). Over the same period, the average of the three total TD global and regional inversions was 1.3 ± 0.4 and 1.3 ± 0.1 Tg N2O yr−1 respectively, compared to 0.9 Tg N2O yr−1 from the BU data. The TU and BU comparison method defined in this study can be operationalized for future yearly updates for the calculation of CH4 and N2O budgets both at EU+UK scale and at national scale. The referenced datasets related to figures are visualized at https://doi.org/10.5281/zenodo.4288969 (Petrescu et al., 2020).

Abstract. Regional land carbon budgets provide insights on the spatial distribution of the land uptake of atmospheric carbon dioxide, and can be used to evaluate carbon cycle models and to define baselines for land-based additional mitigation efforts. The scientific community has been involved in providing observation-based estimates of regional carbon budgets either by downscaling atmospheric CO2 observations into surface fluxes with atmospheric inversions, by using inventories of carbon stock changes in terrestrial ecosystems, by upscaling local field observations such as flux towers with gridded climate and remote sensing fields or by integrating data-driven or process-oriented terrestrial carbon cycle models. The first coordinated attempt to collect regional carbon budgets for nine regions covering the entire globe in the RECCAP-1 project has delivered estimates for the decade 2000–2009, but these budgets were not comparable between regions, due to different definitions and component fluxes reported or omitted. The recent recognition of lateral fluxes of carbon by human activities and rivers, that connect CO2 uptake in one area with its release in another also requires better definition and protocols to reach harmonized regional budgets that can be summed up to the globe and compared with the atmospheric CO2 growth rate and inversion results. In this study, for the international initiative RECCAP-2 coordinated by the Global Carbon Project, which aims as an update of regional carbon budgets over the last two decades based on observations, for 10 regions covering the globe, with a better harmonization that the precursor project, we provide recommendations for using atmospheric inversions results to match bottom-up carbon accounting and models, and we define the different component fluxes of the net land atmosphere carbon exchange that should be reported by each research group in charge of each region. Special attention is given to lateral fluxes, inland water fluxes and land use fluxes.

Le changement d'utilisation des terres/de couverture est la principale cause de dégradation des écosystèmes terrestres. Cependant, ses impacts seront exacerbés en raison du changement climatique et de la croissance démographique, entraînant une expansion agricole en raison de la demande accrue de denrées alimentaires et de la baisse des rendements agricoles dans certaines zones tropicales. Les stratégies internationales visant à atténuer les impacts du changement climatique et du changement du couvert terrestre sont difficiles dans les régions en développement. Cette étude vise à évaluer des alternatives pour minimiser les impacts de ces menaces dans le cadre de trajectoires socio-économiques, dans l'une des régions les plus biologiquement riches du Guatemala et du Mexique. Cette étude est située dans le bassin versant d'Usumacinta, une région transfrontalière qui partage une histoire commune, avec des propriétés biophysiques et des contraintes économiques similaires qui ont conduit à d'importants changements dans l'utilisation/la couverture des terres. Pour comprendre les impacts sur la déforestation et les émissions de carbone des différentes pratiques de gestion des terres, nous avons développé trois scénarios (1) : le statu quo (BAU), (2) un scénario de réduction des émissions visant à réduire la déforestation et la dégradation (REDD+) et (3) zéro déforestation à partir de 2030 sur la base des engagements internationaux. Nos résultats suggèrent que d'ici 2050, la couverture terrestre naturelle pourrait réduire de 22,3 et 12,2% son étendue dans les scénarios BAU et REDD +, respectivement par rapport à 2012. Cependant, le scénario zéro déforestation montre que d'ici 2050, il serait possible d'éviter de perdre 22,4 % du bassin versant boisé (1,7 million d'hectares) et d'en récupérer 5,9 % (0,4 million d'hectares). En termes de séquestration du carbone, les projets REDD + peuvent réduire les pertes de carbone dans la végétation naturelle, mais une politique de zéro déforestation peut doubler la séquestration du carbone produite par les projets REDD + uniquement. Cette étude montre que pour réduire les pressions sur les écosystèmes, en particulier dans les régions fortement marginalisées avec des migrations importantes, il est nécessaire de mettre en œuvre des politiques transfrontalières de gestion des terres qui intègrent également des stratégies de réduction de la pauvreté. El cambio en el uso/cobertura de la tierra es la principal causa de la degradación de los ecosistemas terrestres. Sin embargo, sus impactos se exacerbarán debido al cambio climático y al crecimiento de la población, impulsando la expansión agrícola debido a una mayor demanda de alimentos y menores rendimientos agrícolas en algunas áreas tropicales. Las estrategias internacionales destinadas a mitigar los impactos del cambio climático y el cambio en la cobertura del uso de la tierra son un desafío en las regiones en desarrollo. Este estudio tiene como objetivo evaluar alternativas para minimizar los impactos de estas amenazas bajo trayectorias socioeconómicas, en una de las regiones biológicamente más ricas de Guatemala y México. Este estudio se encuentra en la cuenca de Usumacinta, una región transfronteriza que comparte una historia común, con propiedades biofísicas y limitaciones económicas similares que han llevado a grandes cambios en el uso/cobertura de la tierra. Para comprender los impactos en la deforestación y las emisiones de carbono de las diferentes prácticas de gestión de la tierra, desarrollamos tres escenarios (1): negocios como siempre (BAU), (2) un escenario de reducción de emisiones destinado a reducir la deforestación y la degradación (REDD+) y (3) cero deforestación a partir de 2030 en función de los compromisos internacionales. Nuestros resultados sugieren que para 2050, la cobertura natural de la tierra podría reducir el 22.3 y el 12.2% de su extensión bajo los escenarios BAU y REDD +, respectivamente, en comparación con 2012. Sin embargo, el escenario de deforestación cero muestra que para 2050, sería posible evitar la pérdida del 22,4% de la cuenca forestal (1,7 millones de ha) y recuperar el 5,9% (0,4 millones de hectáreas) de la misma. En términos de secuestro de carbono, los proyectos REDD + pueden reducir las pérdidas de carbono en la vegetación natural, pero una política de deforestación cero puede duplicar el secuestro de carbono producido solo por los proyectos REDD +. Este estudio muestra que para reducir las presiones sobre los ecosistemas, particularmente en regiones altamente marginadas con una migración significativa, es necesario implementar políticas transfronterizas de gestión de la tierra que también integren estrategias de alivio de la pobreza. Land-use/cover change is the major cause of terrestrial ecosystem degradation. However, its impacts will be exacerbated due to climate change and population growth, driving agricultural expansion because of higher demand of food and lower agricultural yields in some tropical areas. International strategies aimed to mitigate impacts of climate change and land use-cover change are challenging in developing regions. This study aims to evaluate alternatives to minimize the impacts of these threats under socioeconomic trajectories, in one of the biologically richest regions in Guatemala and Mexico. This study is located at the Usumacinta watershed, a transboundary region that shares a common history, with similar biophysical properties and economic constraints which have led to large land use/cover changes. To understand the impacts on deforestation and carbon emissions of different land-management practices, we developed three scenarios (1): business as usual (BAU), (2) a reducing emissions scenario aimed to reduce deforestation and degradation (REDD+), and (3) zero-deforestation from 2030 onwards based on the international commitments. Our results suggest that by 2050, natural land cover might reduce 22.3 and 12.2% of its extent under the BAU and REDD + scenarios, respectively in comparison with 2012. However, the zero-deforestation scenario shows that by 2050, it would be possible to avoid losing 22.4% of the forested watershed (1.7 million ha) and recover 5.9% (0.4 million hectares) of it. In terms of carbon sequestration, REDD + projects can reduce the carbon losses in natural vegetation, but a zero-deforestation policy can double the carbon sequestration produced by REDD + projects only. This study shows that to reduce the pressures on ecosystems, particularly in regions highly marginalized with significant migration, it is necessary to implement transboundary land-management policies that also integrate poverty alleviation strategies. استخدام الأراضي/تغيير الغطاء هو السبب الرئيسي لتدهور النظام الإيكولوجي الأرضي. ومع ذلك، ستتفاقم آثاره بسبب تغير المناخ والنمو السكاني، مما يؤدي إلى التوسع الزراعي بسبب ارتفاع الطلب على الغذاء وانخفاض الغلة الزراعية في بعض المناطق الاستوائية. تشكل الاستراتيجيات الدولية الرامية إلى التخفيف من آثار تغير المناخ وتغير استخدام الأراضي تحدياً في المناطق النامية. تهدف هذه الدراسة إلى تقييم البدائل لتقليل آثار هذه التهديدات في إطار المسارات الاجتماعية والاقتصادية، في واحدة من أغنى المناطق بيولوجيًا في غواتيمالا والمكسيك. تقع هذه الدراسة في مستجمع مياه أوسوماسينتا، وهي منطقة عابرة للحدود تشترك في تاريخ مشترك، مع خصائص فيزيائية حيوية مماثلة وقيود اقتصادية أدت إلى تغييرات كبيرة في استخدام الأراضي/تغطيتها. لفهم تأثيرات ممارسات إدارة الأراضي المختلفة على إزالة الغابات وانبعاثات الكربون، وضعنا ثلاثة سيناريوهات (1): العمل كالمعتاد (BAU)، (2) سيناريو خفض الانبعاثات الذي يهدف إلى الحد من إزالة الغابات وتدهورها (REDD+)، و (3) إزالة الغابات الصفرية اعتبارًا من عام 2030 فصاعدًا بناءً على الالتزامات الدولية. تشير نتائجنا إلى أنه بحلول عام 2050، قد يقلل الغطاء الأرضي الطبيعي بنسبة 22.3 و 12.2 ٪ من مداه في إطار سيناريو العمل الاعتيادي وسيناريو خفض الانبعاثات الناجمة عن إزالة الغابات وتدهورها في البلدان النامية، على التوالي مقارنة بعام 2012. ومع ذلك، يُظهر سيناريو إزالة الغابات الصفرية أنه بحلول عام 2050، سيكون من الممكن تجنب فقدان 22.4 ٪ من مستجمعات المياه الحرجية (1.7 مليون هكتار) واستعادة 5.9 ٪ (0.4 مليون هكتار) منها. من حيث عزل الكربون، يمكن لمشاريع خفض الانبعاثات الناجمة عن إزالة الغابات وتدهورها في البلدان النامية أن تقلل من خسائر الكربون في الغطاء النباتي الطبيعي، ولكن سياسة إزالة الغابات الصفرية يمكن أن تضاعف عزل الكربون الناتج عن مشاريع خفض الانبعاثات الناجمة عن إزالة الغابات وتدهورها في البلدان النامية فقط. تُظهر هذه الدراسة أنه للحد من الضغوط على النظم الإيكولوجية، لا سيما في المناطق المهمشة للغاية مع الهجرة الكبيرة، من الضروري تنفيذ سياسات إدارة الأراضي العابرة للحدود التي تدمج أيضًا استراتيجيات التخفيف من حدة الفقر.

This work analyzes gendered processes by a methodology based on clustering factors with influence in the decision-making process of women as users or employees of the transport system. Considering gender as a social construction which changes over time and space, this study is based on the concept of a woman as a person who adopts this role in society. This paper performs a deep analysis of those factors women consider as needs and barriers to use or work in the transport system in four scenarios: railway public transport infrastructures, automated vehicles, bicycle sharing, and jobholders. A literature review and focus group discussions were performed under the consideration that the definition of woman includes the addition of several personal characteristics (age, sexual orientation, family responsibilities, and culture). The data analysis allowed the identification of fairness characteristics (FCs) that affect the interaction of women with the transport system for each scenario. A methodology for clustering the fairness characteristics identified the main areas of action to improve the inclusion of women within each use case. Further studies will be focused on the quantification and prioritization of the FCs through mathematical methods and the suggestion of inclusive measures by an interdisciplinary panel.

In the present article, the thermodynamic potential of a sustainable plasma-assisted nitrogen fixation process for co-production of ammonia and hydrogen is investigated. The developed process takes advantage of chemical looping system by using a liquid metal such as gallium to drive nitrogen fixation reaction using three reactors including reactor R1 to produce gallium nitride from gallium and nitrogen, reactor R2 to produce ammonia and hydrogen from gallium nitride, and plasma reactor R3 to convert gallium oxide to pure gallium. The results of the thermodynamic assessments showed that the proposed reactions are spontaneous and feasible to occur in the reactors. Likewise, the first two reactions are exothermic with ΔH=-230[Formula presented] and ΔH=-239[Formula presented] in the reactors R1 and R2, respectively with an equilibrium chemical conversion of 100%. The plasma reactor requires thermal energy to drive an endothermic reaction of gallium oxide dissociation withΔH=+870[Formula presented]. Thermochemical equilibrium analysis showed that the molar ratio of steam to GaN, as well as the operating pressure and temperature of reactor R2 are the main operating parameters identifying the product composition in the reactor such that by increasing the temperature, the molar ratio of hydrogen to ammonia increases. However, by increasing the molar ratio of steam/GaN (φ value) from 0.1 to 1, the hydrogen content of the reactor increases from 45% to 70% at 400 °C. For φ > 1.0, the hydrogen content decreases while more hydrogen participate in the formation of NH3 thereby increasing the mole fraction of ammonia in the reactor. The equilibrium chemical conversion of all three reactors is expected to reach the completion point (χ = 100%) due to the highly negative Gibbs free energy of the liquid metal-based reactions together with a large thermal driving force supported by thermal plasma reactor. Finally, a scalability study points at a possible use of the new disruptive process design at small scale, and possible industrial transformation scenarios for a distributed production at a local site of consumption are depicted.

AbstractLarge‐scale bioenergy plays a key role in climate change mitigation scenarios, but its efficacy is uncertain. This study aims to quantify that uncertainty by contrasting the results of three different types of models under the same mitigation scenario (RCP2.6‐SSP2), consistent with a 2°C temperature target. This analysis focuses on a single bioenergy feedstock, Miscanthus × giganteus, and contrasts projections for its yields and environmental effects from an integrated assessment model (IMAGE), a land surface and dynamic global vegetation model tailored to Miscanthus bioenergy (JULES) and a bioenergy crop model (MiscanFor). Under the present climate, JULES, IMAGE and MiscanFor capture the observed magnitude and variability in Miscanthus yields across Europe; yet in the tropics JULES and IMAGE predict high yields, whereas MiscanFor predicts widespread drought‐related diebacks. 2040–2049 projections show there is a rapid scale up of over 200 Mha bioenergy cropping area in the tropics. Resulting biomass yield ranges from 12 (MiscanFor) to 39 (JULES) Gt dry matter over that decade. Change in soil carbon ranges from +0.7 Pg C (MiscanFor) to −2.8 Pg C (JULES), depending on preceding land cover and soil carbon.2090–99 projections show large‐scale biomass energy with carbon capture and storage (BECCS) is projected in Europe. The models agree that <2°C global warming will increase yields in the higher latitudes, but drought stress in the Mediterranean region could produce low yields (MiscanFor), and significant losses of soil carbon (JULES and IMAGE). These results highlight the uncertainty in rapidly scaling‐up biomass energy supply, especially in dry tropical climates and in regions where future climate change could result in drier conditions. This has important policy implications—because prominently used scenarios to limit warming to ‘well below 2°C’ (including the one explored here) depend upon its effectiveness.