• Energy Research
• 6. Clean water close
• GB close
• ES close
• CN close
• Aurora Universities Network close

China is confronted with an unprecedented water crisis regarding its quantity and quality. In this study, we quantified the dynamics of China?s embodied water use and chemical oxygen demand (COD) discharge from 2010 to 2015. The analysis was conducted with the latest available water use data across sectors in primary, secondary and tertiary industries and input?output models. The results showed that (1) China?s water crisis was alleviated under urbanisation. Urban consumption occupied the largest percentages (over 30%) of embodied water use and COD discharge, but embodied water intensities in urban consumption were far lower than those in rural consumption. (2) The ?new normal? phase witnessed the optimisation of China?s water use structures. Embodied water use in light-manufacturing and tertiary sectors increased while those in heavy-manufacturing sectors (except chemicals and transport equipment) dropped. (3) Transformation of China?s international market brought positive effects on its domestic water use. China?s water use (116?80 billion tonnes (Bts))(9) and COD discharge (3.95?2.22 million tonnes (Mts)) embodied in export tremendously decreased while its total export values (11?25 trillion CNY) soared. Furthermore, embodied water use and COD discharge in relatively low-end sectors, such as textile, started to transfer from international to domestic markets when a part of China?s production activities had been relocated to other developing countries.

Polycyclic aromatic hydrocarbons (PAHs) are airborne pollutants that are deposited on soils. As climate change is already altering temperature and solar radiation, the global warming is suggested to impact the environmental fate of PAHs. This study was aimed at evaluating the effect of climate change on the PAH photodegradation in soils. Samples of Mediterranean soils were subjected to different temperature and light radiation conditions in a climate chamber. Two climate scenarios were considered according to IPCC projections: 1) a base (B) scenario, being temperature and light intensity 20°C and 9.6W/m(2), respectively, and 2) a climate change (CC) scenario, working at 24°C and 24W/m(2), respectively. As expected, low molecular weight PAHs were rapidly volatilized when increasing both temperature and light intensity. In contrast, medium and high molecular weight PAHs presented different photodegradation rates in soils with different texture, which was likely related to the amount of photocatalysts contained in both soils. In turn, the hydrogen isotopic composition of some of the PAHs under study was also investigated to verify any degradation process. Hydrogen isotopes confirmed that benzo(a)pyrene is degraded in both B and CC scenarios, not only under light but also in the darkness, revealing unknown degradation processes occurring when light is lacking. Potential generation pathways of PAH photodegradation by-products were also suggested, being a higher number of metabolites formed in the CC scenario. Consequently, in a more or less near future, although humans might be less exposed to PAHs, they could be exposed to new metabolites of these pollutants, which might be even more toxic.

Abstract An assessment of the human impact on the global water cycle requires estimating the volume of water withdrawn for irrigated agriculture. A key parameter in this calculation is the irrigation efficiency, which corrects for the fraction of water lost between irrigation withdrawals and the crop due to management, distribution or conveyance losses. Here we show that the irrigation efficiency used in global irrigation models is flawed for it overlooks key ambiguities in partial efficiencies, irrigation technologies, the definition of ‘large-scale’ irrigated areas or managerial factors. Once accounted for, these uncertainties can make irrigation withdrawal estimates fluctuate by more than one order of magnitude at the country level. Such variability is larger and leads to more extreme values than that caused by the uncertainties related with climate change. Our results highlight the need to embrace deep uncertainties in irrigation efficiency to prevent the design of shortsighted policies at the river basin-water-agricultural interface.

Silver nanoparticles (AgNP) are currently defined as emerging pollutants in surface water ecosystems. Whether the toxic effects of AgNP towards freshwater organisms are fully explainable by the release of ionic silver (Ag(+)) has not been conclusively elucidated. Long-term effects to benthic microbial communities (periphyton) that provide essential functions in stream ecosystems are unknown. The effects of exposure of periphyton to 2 and 20 μg/L Ag(+) (AgNO3) and AgNP (polyvinylpyrrolidone stabilised) were investigated in artificial indoor streams. The extracellular polymeric substances (EPS) and 3D biofilm structure, biomass, algae species, Ag concentrations in the water phase and bioassociated Ag were analysed. A strong decrease in total Ag was observed within 4 days. Bioassociated Ag was proportional to dissolved Ag indicating a rate limitation by diffusion across the diffusive boundary layer. Two micrograms per liter of AgNO3 or AgNP did not induce significant effects despite detectable bioassociation of Ag. The 20-μg/L AgNO3 affected green algae and diatom communities, biomass and the ratio of polysaccharides to proteins in EPS. The 20-μg/L AgNO3 and AgNP decreased biofilm volume to about 50 %, while the decrease of biomass was lower in 20 μg/L AgNP samples than the 20-μg/L AgNO3 indicating a compaction of the NP-exposed biofilms. Roughness coefficients were lower in 20 μg/L AgNP-treated samples. The more traditional endpoints (biomass and diversity) indicated silver ion concentration-dependent effects, while the newly introduced parameters (3D structure and EPS) indicated both silver ion concentration-dependent effects and effects related to the silver species applied.

Global-scale hydrological models are routinely used to assess water scarcity, flood hazards and droughts worldwide. Recent efforts to incorporate anthropogenic activities in these models have enabled more realistic comparisons with observations. Here we evaluate simulations from an ensemble of six models participating in the second phase of the Inter-Sectoral Impact Model Inter-comparison Project (ISIMIP2a). We simulate monthly runoff in 40 catchments, spatially distributed across eight global hydrobelts. The performance of each model and the ensemble mean is examined with respect to their ability to replicate observed mean and extreme runoff under human-influenced conditions. Application of a novel integrated evaluation metric to quantify the models' ability to simulate timeseries of monthly runoff suggests that the models generally perform better in the wetter equatorial and northern hydrobelts than in drier southern hydrobelts. When model outputs are temporally aggregated to assess mean annual and extreme runoff, the models perform better. Nevertheless, we find a general trend in the majority of models towards the overestimation of mean annual runoff and all indicators of upper and lower extreme runoff. The models struggle to capture the timing of the seasonal cycle, particularly in northern hydrobelts, while in southern hydrobelts the models struggle to reproduce the magnitude of the seasonal cycle. It is noteworthy that over all hydrological indicators, the ensemble mean fails to perform better than any individual model—a finding that challenges the commonly held perception that model ensemble estimates deliver superior performance over individual models. The study highlights the need for continued model development and improvement. It also suggests that caution should be taken when summarising the simulations from a model ensemble based upon its mean output. Environmental Research Letters, 13 (6) ISSN:1748-9326 ISSN:1748-9318

The Ganges-Brahmaputra-Meghna (GBM) delta is one of the world's largest deltas. It is currently experiencing high rates of relative sea-level rise of about 5 mm/year, reflecting anthropogenic climate change and land subsidence. This is expected to accelerate further through the 21st Century, so there are concerns that the GBM delta will be progressively submerged. In this context, a core question is: can sedimentation on the delta surface maintain its elevation relative to sea level? This research seeks to answer this question by applying a two-dimensional flow and morphological model which is capable of handling dynamic interactions between the river and floodplain systems and simulating floodplain sedimentation under different flow-sediment regimes and anthropogenic interventions. We find that across a range of flood frequencies and adaptation scenarios (including the natural polder-free state), the retained volume of sediment varies between 22% and 50% of the corresponding sediment input. This translates to average rates of sedimentation on the delta surface of 5.5 mm/yr to 7.5 mm/yr. Hence, under present conditions, sedimentation associated with quasi-natural conditions can exceed current rates of relative sea-level rise and potentially create new land mass. These findings highlight that encouraging quasi-natural conditions through the widespread application of active sediment management measures has the potential to promote more sustainable outcomes for the GBM delta. Practical measures to promote include tidal river management, and appropriate combinations of cross-dams, bandal-like structures, and dredging.