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Abstract The kinetics of methane hydrate decomposition was studied using a semibatch stirred-tank reactor. The decomposition was accomplished by reducing the pressure on a hydrate slurry in water to a value below the three-phase equilibrium pressure at the reactor temperature. The data were obtained at temperatures from 274 to 283 K and pressures from 0.17 to 6.97 MPa. The stirring rates were high enough to eliminate mass-transfer effects. Analysis of the data indicated that the decomposition rate was proportional to the particle surface area and to the difference in the fugacity of methane at the equilibrium pressure and the decomposition pressure. The proportionality constant showed an Arrhenius temperature dependence. An estimate of the hydrate particle diameters in the experiments permitted the development of an intrinsic model for the kinetics of hydrate decomposition.

Wave power is a potential technology for generating sustainable renewable energy. Several types of wave energy converters (WECs) have been proposed for this purpose. WECs operate in a harsh maritime environment that sets strict limitations on how and when the device can be economically and safely reached for maintenance. Thus, to ensure profitable energy generation over the system life cycle, system reliability is a key aspect to be considered in WEC development. In this article, we describe a reliability analysis approach for WEC development, based on the use of reliability block diagram (RBD) modelling. We apply the approach in a case study involving a submerged oscillating wave surge converter device concept that utilizes hydraulics in its power take-off system. In addition to describing the modelling approach, we discuss the data sources that were used for gathering reliability data for the components used in a novel system concept with very limited historical or experimental data available. This includes considerations of the data quality from various sources. As a result, we present examples of applying the RBD modelling approach in the context of WEC development and discuss the applicability of the approach in supporting the development of new technologies.

Wave energy conversion is a promising field of renewable energy, but it still faces several technological and economic challenges. One of these challenges is to improve the energy efficiency and adaptability of Wave Energy Converters to varying wave conditions. A technological approach to solve this efficiency challenge is the negative spring mechanisms illustrated in recent studies. This paper proposes and analyzes a novel negative spring technological concept that dynamically modifies the mass and inertia of a Wave Energy Converter by transferring seawater between its compartments. The added value of the presented technology relies on interoperability, ease of manufacturing and operating, and increased energy efficiency for heterogeneous sea states. The concept is presented in two analyzed alternatives: a passive one, which requires no electrical consumption and is purely based on the relative motion of the bodies, and an active one, which uses a controlled pump system to force the water transfer. The system is evaluated numerically using widely accepted simulation tools, such as WECSIM, and validated by physical testing in a wave flume using decay and regular test scenarios. Key findings include a relevant discussion about system limitations and a demonstrated increase in the extracted energy efficiency up to 12.7% while limiting the maximum power extraction for a singular wave frequency to 3.41%, indicating an increased adaptability to different wave frequencies because of the amplified range of near-resonance operation of the WEC up to 0.21 rad/s.

Research to date has suggested that both individual marine species and ecological processes are expected to exhibit diverse responses to the environmental effects of climate change. Evolutionary responses can occur on rapid (ecological) timescales, and yet studies typically do not consider the role that adaptive evolution will play in modulating biological responses to climate change. Investigations into such responses have typically been focused at particular biological levels (e.g., cellular, population, community), often lacking interactions among levels. Since all levels of biological organisation are sensitive to global climate change, there is a need to elucidate how different processes and hierarchical interactions will influence species fitness. Therefore, predicting the responses of communities and populations to global change will require multidisciplinary efforts across multiple levels of hierarchy, from the genetic and cellular to communities and ecosystems. Eventually, this may allow us to establish the role that acclimatisation and adaptation will play in determining marine community structures in future scenarios.

Transport is an important source of air pollution and greenhouse gas emissions. Although the applications of information and communication technologies (ICTs) for transport, also known as intelligent transport systems, are seen as having great potential to help reduce emissions from road transport, their exact impact on CO2 emissions are uncertain for decision makers from government to industry. This uncertainty hinders the deployment of such applications. Therefore there is a need for a common evaluation approach to assess the CO2 impact of ICT measures in a systemic and realistic way. In this study, a methodology framework to evaluate the impact of ICT measures on CO2 emissions is explained. The methodology was developed within the European Union FP7 project Amitran. In particular, this study focuses on the outline and the framework architecture of the methodology as well as the required interfaces between the required models. The use of the methodology is demonstrated by applying it to a use case of dynamic traffic light systems. Finally, the efforts made to validate the methodology and make it accessible to users are explained.

AbstractAccelerated warming and melting of Arctic sea-ice has been associated with significant increases in phytoplankton productivity in recent years. Here, utilizing a multiproxy approach, we reconstruct an annually resolved record of Labrador Sea productivity related to sea-ice variability in Labrador, Canada that extends well into the Little Ice Age (LIA; 1646 AD). Barium-to-calcium ratios (Ba/Ca) and carbon isotopes (δ13C) measured in long-lived coralline algae demonstrate significant correlations to both observational and proxy records of sea-ice variability, and show persistent patterns of co-variability broadly consistent with the timing and phasing of the Atlantic Multidecadal Oscillation (AMO). Results indicate reduced productivity in the Subarctic Northwest Atlantic associated with AMO cool phases during the LIA, followed by a step-wise increase from 1910 to present levels—unprecedented in the last 363 years. Increasing phytoplankton productivity is expected to fundamentally alter marine ecosystems as warming and freshening is projected to intensify over the coming century.