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<div class="section abstract"><div class="htmlview paragraph">A study has been conducted into icephobic properties of some highly durable “off-the-shelf” elastomer materials using a rotating ice adhesion test rig installed in the NRC’s Altitude Icing Wind Tunnel. This enabled the formation of ice at environmental conditions similar to those experienced during in-flight icing encounters. Initially, the tests indicated some very positive results with ice adhesion shear stress as low as 8KPa. On further examination, however, it became apparent that the test preparation process, in which the samples were cleaned with an ethanol alcohol solution, influenced the results due to absorption and prolonged retention of the cleaning fluid. The uptake of the ethanol alcohol solution by the elastomer was found to be a function of the surface temperature and remained absorbed into the coating during the ice accretion process changing the characteristics of the coating in such a way that led to a reduction in the ice/surface bond strength.</div></div>

AbstractThe impacts of the changing climate on the biological world vary across latitudes, habitats and spatial scales. By contrast, the time of day at which these changes are occurring has received relatively little attention. As biologically significant organismal activities often occur at particular times of day, any asymmetry in the rate of change between the daytime and night‐time will skew the climatic pressures placed on them, and this could have profound impacts on the natural world. Here we determine global spatial variation in the difference in the mean annual rate at which near‐surface daytime maximum and night‐time minimum temperatures and mean daytime and mean night‐time cloud cover, specific humidity and precipitation have changed over land. For the years 1983–2017, we derived hourly climate data and assigned each hour as occurring during daylight or darkness. In regions that showed warming asymmetry of >0.5°C (equivalent to mean surface temperature warming during the 20th century) we investigated corresponding changes in cloud cover, specific humidity and precipitation. We then examined the proportional change in leaf area index (LAI) as one potential biological response to diel warming asymmetry. We demonstrate that where night‐time temperatures increased by >0.5°C more than daytime temperatures, cloud cover, specific humidity and precipitation increased. Conversely, where daytime temperatures increased by >0.5°C more than night‐time temperatures, cloud cover, specific humidity and precipitation decreased. Driven primarily by increased cloud cover resulting in a dampening of daytime temperatures, over twice the area of land has experienced night‐time warming by >0.25°C more than daytime warming, and has become wetter, with important consequences for plant phenology and species interactions. Conversely, greater daytime relative to night‐time warming is associated with hotter, drier conditions, increasing species vulnerability to heat stress and water budgets. This was demonstrated by a divergent response of LAI to warming asymmetry.

Increased use of ethanol-blended gasoline (gasohol) and its potential release into the subsurface have spurred interest in studying the biodegradation of and interactions between ethanol and gasoline components such as benzene, toluene, ethylbenzene and xylene isomers (BTEX) in groundwater plumes. The preferred substrate status and the high biological oxygen demand (BOD) posed by ethanol and its biodegradation products suggests that anaerobic electron acceptors (EAs) will be required to support in situ bioremediation of BTEX. To develop a strategy for aromatic hydrocarbon bioremediation and to understand the impacts of ethanol on BTEX biodegradation under strictly anaerobic conditions, a microcosm experiment was conducted using pristine aquifer sand and groundwater obtained from Canadian Forces Base Borden, Canada. The initial electron accepter pool included nitrate, sulfate and/or ferric iron. The microcosms typically contained 400 g of sediment, 600 approximately 800 ml of groundwater, and with differing EAs added, and were run under anaerobic conditions. Ethanol was added to some at concentrations of 500 and 5000 mg/L. Trends for biodegradation of aromatic hydrocarbons for the Borden aquifer material were first developed in the absence of ethanol, The results showed that indigenous microorganisms could degrade all aromatic hydrocarbons (BTEX and trimethylbenzene isomers-TMB) under nitrate- and ferric iron-combined conditions, but not under sulfate-reducing conditions. Toluene, ethylbenzene and m/p-xylene were biodegraded under denitrifying conditions. However, the persistence of benzene indicated that enhancing denitrification alone was insufficient. Both benzene and o-xylene biodegraded significantly under iron-reducing conditions, but only after denitrification had removed other aromatics. For the trimethylbenzene isomers, 1,3,5-TMB biodegradation was found under denitrifying and then iron-reducing conditions. Biodegradation of 1,2,3-TMB or 1,2,4-TMB was slower under iron-reducing conditions. This study suggests that addition of excess ferric iron combined with limited nitrate has promise for in situ bioremediation of BTEX and TMB in the Borden aquifer and possibly for other sites contaminated by hydrocarbons. This study is the first to report 1,2,3-TMB biodegradation under strictly anaerobic condition. With the addition of 500 mg/L ethanol but without EA addition, ethanol and its main intermediate, acetate, were quickly biodegraded within 41 d with methane as a major product. Ethanol initially present at 5000 mg/L without EA addition declined slowly with the persistence of unidentified volatile fatty acids, likely propionate and butyrate, but less methane. In contrast, all ethanol disappeared with repeated additions of either nitrate or ferric iron, but acetate and unidentified intermediates persisted under iron-enhanced conditions. With the addition of 500 mg/L ethanol and nitrate, only minor toluene biodegradation was observed under denitrifying conditions and only after ethanol and acetate were utilized. The higher ethanol concentration (5000 mg/L) essentially shut down BTEX biodegradation likely due to high EA demand provided by ethanol and its intermediates. The negative findings for anaerobic BTEX biodegradation in the presence of ethanol and/or its biodegradation products are in contrast to recent research reported by Da Silva et al. [Da Silva, M.L.B., Ruiz-Aguilar, G.M.L., Alvarez, P.J.J., 2005. Enhanced anaerobic biodegradation of BTEX-ethanol mixtures in aquifer columns amended with sulfate, chelated ferric iron or nitrate. Biodegradation. 16, 105-114]. Our results suggest that the apparent conservation of high residual labile carbon as biodegradation products such as acetate makes natural attenuation of aromatics less effective, and makes subsequent addition of EAs to promote in situ BTEX biodegradation problematic.

Multifrequency observations are presented of three BL Lac objects, including the first UV measurements of 0912 + 297 and 1219 + 285. An eight day optical flare was measured from 0422 = 004 in which a doubling in visual flux density was noted; other sources displayed smaller daily fluctuations. The 5-15 GHz radio flux from these three objects remained constant for two months, although the 15-20 GHz emission from 0912 + 297 varied slightly over a period of a month. Constraints which are provided by these and other Bl Lac data are discussed for inhomogeneous relativistically beamed jet models. It is concluded that a tapered jet model is in good agreement with the data for each source and that additional emission regions are not required.

Biomass burning is a global source of climate- and health-affecting emissions. The impacts of biomass burning emissions (BBE) are tied to their complex and variable chemical makeup. For instance, the nitrogen content of BBE influences their capacity to absorb light, and therefore affect the Earth's radiative budget. Factors such as temperature, biomass type, or air flow rate during the combustion all modify the composition of BBE, making accurate characterization challenging. Herein, for the first time, principal component analysis (PCA) was applied to emissions gathered during laboratory-based combustion of wood and cow dung biomass in a tube furnace. A thermal desorption two dimensional time-of-flight gas chromatography mass spectrometry (TD-GC × GC-ToF-MS) setup was employed to separate and identify chemical species. By combining these techniques with a feature selection algorithm, we determined that low temperature and air flow rate lead to greater feature separation on PCA scores plots. Of the 729 variables used to construct the plots, 61 were identified as significant. These species - including sugars such as d-Allose and melezitose, as well as tracers such as levoglucosan and guaiacol - significantly differentiated emissions from wood versus cow dung biomass, especially at lower temperatures. In particular, combustion of either fuel at 0.2 slpm and 500 °C, lead to 20 times the variability in levoglucosan peak area over more efficient furnace parameters. Chemical species evolved only from dung burning contained on average 0.595 nitrogen atoms versus 0.515 for wood, indicating that a higher nitrogen content of the base fuel may not necessarily translate into emission of unique nitrogen containing species, potentially causing the underestimation of dung burning impacts. Overall, TD-GC × GC-ToF-MS coupled to PCA reliably separated emissions from wood and dung biomass while simultaneously identifying significant chemical features, displaying the suitability of this combination of techniques towards characterizing complex BBE matrices in the future.

Wound-rotor induction generators have numerous advantages in wind power generation over other types of generators. One scheme is realized when a converter cascade is used between the slip-ring terminals and the utility grid to control the rotor power. This configuration is called the doubly-fed induction generator (DFIG). In this paper, a vector control scheme is developed to control the rotor side voltage source converter that allows independent control of the generated active and reactive power as well as the rotor speed to track the maximum wind power point. A neuro-fuzzy gain tuner is proposed to control the DFIG. The input for each neuro-fuzzy system is the error value of generator speed, active or reactive power. The choice of only one input to the system simplifies the design. Experimental investigations have also been conducted on a laboratory DFIG to verify the calculated results.

Analysis of coal-bearing strata in the Paleocene Firkanten Formation in the Central Tertiary Basin of Spitsbergen (Svalbard) has shown that deposition was in a coastal plain setting. Interpretation of numerous cores indicates that deposition occurred in coastal plain mires, lagoons, tidal inlets, barrier bars and shoreface environments. These form a series of shallowing-up successions metres to tens of metres thick. Correlation between boreholes over distances in excess of 100 km proved challenging with no regional marker horizons. However, by constructing paleogeographic maps as part of the process of correlating, and by using analogous modern coastal areas as indicators of facies belt widths, a correlation scheme that provides patterns of facies distribution that are consistent in three dimensions has been created. The resulting stratigraphic framework comprises parasequences grouped into parasequence sets that show an overall retrogradational pattern representing a stepwise transgression over a basin floor that was subsiding due to flexural subsidence. Absence of incision or other evidence for relative sea-level fall within the whole succession suggests that flexural subsidence was sufficient to keep pace with eustatic sea-level falls. The basal unconformity surface is overlain by a poorly sorted deposit of reworked regolith that forms a strongly diachronous unit, occurring at the base of successive parasequences. Individual parasequences formed in response to relative sea-level rises that are considered likely to be eustatic in origin and resulted in flooding of the coastal plain. Centimetre-scale analysis of the coal maceral distribution through the thickness of the lowermost major coal seam indicates that there were also higher-frequency fluctuations of relative sea level, possibly at Milankovitch-scale, during the deposition of individual parasequences. This new facies model and interpretation of the subsidence history of the basin provides a framework for understanding the distribution of sediments within a coal-bearing coastal plain succession.

Thermal ratcheting is a critical phenomenon associated with the cyclic operation of dual-medium thermocline tanks in solar energy applications. Although thermal ratcheting poses a serious impediment to thermocline operation, this failure mode in dual-medium thermocline tanks is not yet well understood. To study the potential for the occurrence of ratcheting, a comprehensive model of a thermocline tank that includes both the heterogeneous filler region as well as the composite tank wall is formulated. The filler region consists of a rock bed with interstitial molten salt, while the tank wall is composed of a steel shell with two layers of insulation (firebrick and ceramic). The model accounts separately for the rock and molten-salt regions in view of their different thermal properties. Various heat loss conditions are applied at the external tank surface to evaluate the effect of energy losses to the surroundings. Hoop stresses, which are governed by the magnitude of temperature fluctuations, are determined through both a detailed finite-element analysis and simple strain relations. The two methods are found to yield almost identical results. Temperature fluctuations are damped by heat losses to the surroundings, leading to a reduction in hoop stresses with increased heat losses. Failure is prevented when the peak hoop stress is less than the material yield strength of the steel shell. To avoid ratcheting without incurring excessive energy loss, insulation between the steel shell and the filler region should be maximized.