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This study highlights how Chinese economic development detrimentally impacted water quality in recent decades and how this has been improved by enormous investment in environmental remediation funded by the Chinese government. To our knowledge, this study is the first to describe the variability of surface water quality in inland waters in China, the affecting drivers behind the changes, and how the government-financed conservation actions have impacted water quality. Water quality was found to be poorest in the North and the Northeast China Plain where there is greater coverage of developed land (cities + cropland), a higher gross domestic product (GDP), and higher population density. There are significant positive relationships between the concentration of the annual mean chemical oxygen demand (COD) and the percentage of developed land use (cities + cropland), GDP, and population density in the individual watersheds (p < 0.001). During the past decade, following Chinese government-financed investments in environmental restoration and reforestation, the water quality of Chinese inland waters has improved markedly, which is particularly evident from the significant and exponentially decreasing GDP-normalized COD and ammonium (NH4+-N) concentrations. It is evident that the increasing GDP in China over the past decade did not occur at the continued expense of its inland water ecosystems. This offers hope for the future, also for other industrializing countries, that with appropriate environmental investments a high GDP can be reached and maintained, while simultaneously preserving inland aquatic ecosystems, particularly through management of sewage discharge.

This study highlights how Chinese economic development detrimentally impacted water quality in recent decades and how this has been improved by enormous investment in environmental remediation funded by the Chinese government. To our knowledge, this study is the first to describe the variability of surface water quality in inland waters in China, the affecting drivers behind the changes, and how the government-financed conservation actions have impacted water quality. Water quality was found to be poorest in the North and the Northeast China Plain where there is greater coverage of developed land (cities + cropland), a higher gross domestic product (GDP), and higher population density. There are significant positive relationships between the concentration of the annual mean chemical oxygen demand (COD) and the percentage of developed land use (cities + cropland), GDP, and population density in the individual watersheds (p < 0.001). During the past decade, following Chinese government-financed investments in environmental restoration and reforestation, the water quality of Chinese inland waters has improved markedly, which is particularly evident from the significant and exponentially decreasing GDP-normalized COD and ammonium (NH4+-N) concentrations. It is evident that the increasing GDP in China over the past decade did not occur at the continued expense of its inland water ecosystems. This offers hope for the future, also for other industrializing countries, that with appropriate environmental investments a high GDP can be reached and maintained, while simultaneously preserving inland aquatic ecosystems, particularly through management of sewage discharge.

Abstract The kinetics of methane hydrate decomposition was studied using a semibatch stirred-tank reactor. The decomposition was accomplished by reducing the pressure on a hydrate slurry in water to a value below the three-phase equilibrium pressure at the reactor temperature. The data were obtained at temperatures from 274 to 283 K and pressures from 0.17 to 6.97 MPa. The stirring rates were high enough to eliminate mass-transfer effects. Analysis of the data indicated that the decomposition rate was proportional to the particle surface area and to the difference in the fugacity of methane at the equilibrium pressure and the decomposition pressure. The proportionality constant showed an Arrhenius temperature dependence. An estimate of the hydrate particle diameters in the experiments permitted the development of an intrinsic model for the kinetics of hydrate decomposition.

Abstract The kinetics of methane hydrate decomposition was studied using a semibatch stirred-tank reactor. The decomposition was accomplished by reducing the pressure on a hydrate slurry in water to a value below the three-phase equilibrium pressure at the reactor temperature. The data were obtained at temperatures from 274 to 283 K and pressures from 0.17 to 6.97 MPa. The stirring rates were high enough to eliminate mass-transfer effects. Analysis of the data indicated that the decomposition rate was proportional to the particle surface area and to the difference in the fugacity of methane at the equilibrium pressure and the decomposition pressure. The proportionality constant showed an Arrhenius temperature dependence. An estimate of the hydrate particle diameters in the experiments permitted the development of an intrinsic model for the kinetics of hydrate decomposition.

ABSTRACTWind power forecasts are useful tools for power load balancing, energy trading and wind farm operations. Long range monthly‐to‐seasonal forecasting allows the prediction of departures from average weather conditions beyond traditional weather forecast timescales, months in advance. However, it has not yet been demonstrated how these forecasts can be optimally transformed to wind power. The predictable part of a seasonal forecast is for longer monthly averages, not daily averages, but to use monthly averages misses information on variability. To investigate, here a model relating average weather conditions to average wind power output was built, based on the relationship between instantaneous wind speed and power production and incorporating fluctuations in air density due to temperature and wind speed variability. Observed monthly average power output from UK stations was used to validate the model and to investigate the optimal temporal resolution for the data used to drive the model. Multiple simulations of wind power were performed based on reanalysis data, making separate simulations based on monthly, daily and sub‐daily averages, using a distribution defined by the mean across the period to incorporate information on variability. Basing the simulation on monthly averages alone is sub‐optimal: using daily average winds gives the highest correlation against observations. No improvement over this is gained by using sub‐daily averages or including temperature variability. This signifies that to transform seasonal forecasts to wind power a compromise must be made between using the daily averages with debatable skill and the more predictable monthly averages, losing information on day‐to‐day variability.

ABSTRACTWind power forecasts are useful tools for power load balancing, energy trading and wind farm operations. Long range monthly‐to‐seasonal forecasting allows the prediction of departures from average weather conditions beyond traditional weather forecast timescales, months in advance. However, it has not yet been demonstrated how these forecasts can be optimally transformed to wind power. The predictable part of a seasonal forecast is for longer monthly averages, not daily averages, but to use monthly averages misses information on variability. To investigate, here a model relating average weather conditions to average wind power output was built, based on the relationship between instantaneous wind speed and power production and incorporating fluctuations in air density due to temperature and wind speed variability. Observed monthly average power output from UK stations was used to validate the model and to investigate the optimal temporal resolution for the data used to drive the model. Multiple simulations of wind power were performed based on reanalysis data, making separate simulations based on monthly, daily and sub‐daily averages, using a distribution defined by the mean across the period to incorporate information on variability. Basing the simulation on monthly averages alone is sub‐optimal: using daily average winds gives the highest correlation against observations. No improvement over this is gained by using sub‐daily averages or including temperature variability. This signifies that to transform seasonal forecasts to wind power a compromise must be made between using the daily averages with debatable skill and the more predictable monthly averages, losing information on day‐to‐day variability.

The aims of this work are to provide an overview of the current stresses of estuaries in Argentina and to propose adaptation strategies from an ecohydrological approach. Several Argentinian estuaries are impacted by pollutants, derived mainly from sewage discharge and agricultural or industrial activities. Anthropogenic impacts are expected to rise with increasing human population. Climate-driven warmer temperature and hydrological changes will alter stratification, residence time, oxygen content, salinity, pollutant distribution, organism physiology and ecology, and nutrient dynamics. Good water quality is essential in enhancing estuarine ecological resilience to disturbances brought on by global change. The preservation, restoration, and creation of wetlands will help to protect the coast from erosion, increase sediment accretion rates, and improve water quality by removing excess nutrients and pollutants. The capacity of hydrologic basin ecosystems to absorb human and natural impacts can be improved through holistic management, which should consider social vulnerability in complex human-natural systems.