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Purpose This paper aims to investigate the current energy status in the West Balkan countries and the related perspectives for renewable energy sources (RES) cooperation mechanisms, within the framework of RES Directive 2009/28/European Commission (EC), through the elaboration of a SWOT (strengths, weaknesses, opportunities, threats) analysis. Particular emphasis is laid on the case of Bosnia-Herzegovina, Croatia and Serbia. The SWOT analysis provides a clearer view of expanding RES in the West Balkans, as well as the level of utilization and potential of cooperation mechanisms and renewable energy in each country. Design/methodology/approach The adopted approach is mainly based on the context of a project co-financed by the Intelligent Energy Europe Programme, titled “Bringing Europe and Third countries closer together through renewable Energies (BETTER)” (project number: IEE/11/845/SI2.616378). The adopted approach incorporates the steps of desktop analysis, stakeholders’ mapping and engagement, key factors’ identification and analysis of results. Findings The barriers to expand RES in the region are significant. Currently, the region is electricity importer and by far not in the position to efficiently exploit the large RES potentials. It remains to be seen whether and to what extent cooperation mechanisms may be used in the Western Balkans and the EU by 2020. The unification of the fragmented electricity system and market-oriented reforms aim to join regional power markets and then to integrate with the European Union power market. There is a multitude of market barriers for RES, resulting in a high risk perception n by investors. Cooperation mechanisms could strengthen the regions’ policy frameworks and be a starting point to integrate the region’s energy systems and to overcome the fragmentation of the past two decades. Originality/value The potential of West Balkan countries to make use of the cooperation mechanisms provides opportunities for RES exporting between West Balkan and other European countries. An analysis of these opportunities for cooperation will allow drawing clearer conclusions on cooperation potentials and business cases for the region.

SummaryEnvironmentally extended multiregional input‐output (EE MRIO) tables have emerged as a key framework to provide a comprehensive description of the global economy and analyze its effects on the environment. Of the available EE MRIO databases, EXIOBASE stands out as a database compatible with the System of Environmental‐Economic Accounting (SEEA) with a high sectorial detail matched with multiple social and environmental satellite accounts. In this paper, we present the latest developments realized with EXIOBASE 3—a time series of EE MRIO tables ranging from 1995 to 2011 for 44 countries (28 EU member plus 16 major economies) and five rest of the world regions. EXIOBASE 3 builds upon the previous versions of EXIOBASE by using rectangular supply‐use tables (SUTs) in a 163 industry by 200 products classification as the main building blocks. In order to capture structural changes, economic developments, as reported by national statistical agencies, were imposed on the available, disaggregated SUTs from EXIOBASE 2. These initial estimates were further refined by incorporating detailed data on energy, agricultural production, resource extraction, and bilateral trade. EXIOBASE 3 inherits the high level of environmental stressor detail from its precursor, with further improvement in the level of detail for resource extraction. To account for the expansion of the European Union (EU), EXIOBASE 3 was developed with the full EU28 country set (including the new member state Croatia). EXIOBASE 3 provides a unique tool for analyzing the dynamics of environmental pressures of economic activities over time.

In our continued efforts in the synthesis of ruthenium(II) polypyridine complexes as potential dyes for use in varied applications, such as the dye-sensitized solar cells (DSSCs), this work particularly describes the synthesis, absorption spectrum, redox behavior and luminescence properties of a new homoleptic ruthenium(II) complex bearing a simple trans-2-methyl-2-butenoic acid functionality as the anchoring ligand on terpyridine moiety. The functionalized terpyridine ligand: 4’-(trans-2-methyl-2-butenoic acid)-terpyridyl (L1) was synthesized by aryl bromide substitution on terpyridine in a basic reaction condition under palladium carbide catalysis. In particular, the photophysical and redox properties of the complex formulated as: bis-4’-(trans-2-methyl-2-butenoic acid)-terpyridyl ruthenium(II) bis-hexafluorophosphate [Ru(L1)2(PF6)2] are significantly better compared to those of [Ru(tpy)2]2+ and compare well with those of the best emitters of Ru(II) polypyridine family containing tridentate ligands. Reasons for the improved photophysical and redox properties of the complex may be attributed partly to the presence of a substituted α,β-unsaturated carboxylic acid moiety leading to increase in the length of π-conjugation bond thereby enhancing the MLCT-MC (Metal-to-ligand-charge transfer-metal centred) energy gap, and to the reduced difference between the minima of the excited and ground states potential energy surfaces.

Due to the progresses in exhaust emission after-treatment systems and in the development of new combustion processes, the S.I. engine has been booming in the past few years. But the efficiency will have to be improved in the future. Because of its thermodynamic benefits, the S.I. direct injection engine of the second generation — so called air guided system — shows the highest potential for gasoline engines to reduce fuel consumption. However, there are restrictions when using conventional spark ignition system. They concern the optimum position of ignition initialization and spark-plug wear, the latter being caused by inhomogeneous mixture distribution. The laser-induced ignition enables a flexible choice of the ignition location and a wear resistant initialization of the combustion process. The most crucial component here is the optics (the combustion-chamber window), through which the laser beam passes into the combustion chamber. In this paper, laser-induced ignition is discussed and its potential compared to a conventional ignition system is presented. In addition, several optic configurations are presented as well as tests regarding the minimum required laser energy and the optic contamination and self-cleaning effect of the optics. At the Institute of Internal Combustion Engines at the Vienna University of Technology the optic contamination and self-cleaning effect, which is crucial for a long-term operation, was tested on a two-cylinder research engine.

Energy efficiency is an objective of public interventions at least since the Public Utility Regulatory Policy Act of 1978 (PURPA). Recently, conservation has received considerable attention in the United States and in particular in the European Union but this time in order to mitigate global warming. Policy measures include regulations at the technical level and the introduction of white certificates in order to force utilities and firms to invest into conservation in a way similar to the already existing renewable energy quota. This paper derives the optimal mechanism if utilities must deal with white certificates facing consumers holding private information. The optimal mechanism has some theoretically interesting features like restricted participation and a discontinuity.

AbstractDeriving active pharmaceutical agents from renewable resources is crucial to increasing the economic feasibility of modern biorefineries and promises to alleviate critical supply‐chain dependencies in pharma manufacturing. Our multidisciplinary approach combines research in lignin‐first biorefining, sustainable catalysis, and alternative solvents with bioactivity screening, an in vivo efficacy study, and a structural‐similarity search. The resulting sustainable path to novel anti‐infective, anti‐inflammatory, and anticancer molecules enabled the rapid identification of frontrunners for key therapeutic indications, including an anti‐infective against the priority pathogen Streptococcus pneumoniae with efficacy in vivo and promising plasma and metabolic stability. Our catalytic methods provided straightforward access, inspired by the innate structural features of lignin, to synthetically challenging biologically active molecules with the core structure of dopamine, namely, tetrahydroisoquinolines, quinazolinones, 3‐arylindoles and the natural product tetrahydropapaveroline. Our diverse array of atom‐economic transformations produces only harmless side products and uses benign reaction media, such as tunable deep eutectic solvents for modulating reactivity in challenging cyclization steps.

AbstractChemical looping combustion is a highly efficient CO2 separation technology without direct contact between combustion air and fuel. A metal oxide is used as an oxygen carrier in dual fluidized beds to generate clean CO2. The use of biomass is the focus of current research because of the possibility of negative CO2 emissions and the utilization of biogenic carbon. The most commonly proposed OC are natural ores and residues, but complete combustion has not yet been achieved. In this work, the direct utilization of CLC exhaust gas for methane synthesis as an alternative route was investigated, where the gas components CO, CH4 and H2 are not disadvantageous but benefit the reactions in a methanation step. The whole process chain, the coupling of an 80 kWth pilot plant with gas cleaning and a 10 kW fluidized bed methanation unit were for this purpose established. As OC, ilmenite enhanced with limestone was used, combusting bark pellets in autothermal operation at over 1000 °C reaching high combustion efficiencies of up to 91.7%. The fuel reactor exhaust gas was mixed with hydrogen in the methanation reactor at 360 °C and converted with a methane yield of up to 97.3%. The study showed especially high carbon utilization efficiencies of 97% compared to competitor technologies. Based on the experimental results, a scale-up concept study showed the high potential of the combination of the technologies concerning the total efficiency and the adaptability to grid injection. Graphical Abstract