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Filament seals, such as brush seals and leaf seals, are investigated as a potential improved seal for gas turbine applications. As these seals operate in contact with the rotor, a good understanding of their stiffness is required in order to minimize seal wear and degradation. This paper demonstrates that the filament and complete seal stiffness is affected in comparable magnitudes by mechanical and aerodynamic forces. In certain cases, the aerodynamic forces can also lead to an overall negative seal stiffness which may affect stable seal operation. In negative stiffness, the displacement of the seal or rotor into an eccentric position causes a resultant force, which, rather than restoring the rotor to a central position, acts to amplify its displacement. Insight into the forces acting on the seal filaments is gained by investigating a leaf seal, which consists of a pack of thin planar leaves arranged around the rotor, with coverplates on either side of the leaf pack, offset from the pack surfaces. The leaf seal is chosen due to its geometry being more suitable for analysis compared to alternative filament seals such as the brush seal. Data from two experimental campaigns are presented which show a seal exhibiting negative stiffness and a seal exhibiting a stiffness reduction due to aerodynamic effects. An empirical model for the forces acting on leaf filaments is developed based on the experimental data, which allows separation of mechanical and aerodynamic forces. In addition a numerical model is developed to analyze the flow approaching the leaf pack and the interleaf flow, which gives an insight into the causes of the aerodynamic forces. Using the empirical and numerical models together, a full picture of the forces affecting leaf stiffness is created. Validation of the models is achieved by successfully predicting seal stiffness for a further data set across the full range of operating conditions. The understanding of aerodynamic forces and their impact on filament and seal stiffness allows for their consideration in leaf seal design. A qualitative assessment of how they may be used to improve seal operation in filament seals is given.

The lifetime and reliability of power transformers are primarily dependent on the hot-spot temperature in the windings, as temperature is the most important factor determining the insulation degradation rate. Key to removing the heat from the transformer is the radiator which must be carefully designed to keep the temperatures within limits under all operating conditions whilst minimizing the transformer size, weight and cost. This paper compares the analytical method used to predict the radiator performance with computational fluid dynamics (CFD) models in terms of heat dissipation. It is found that the analytical method and CFD models give similar results in the air natural (AN) cooling modes, whereas the analytical method overestimates the heat dissipation in the air forced (AF) cooling modes. Moreover, the thermal conduction effect in the radiator wall is investigated under different operating conditions and for different radiator sizes using the CFD models. The simulation results indicate that the radiator wall contributes to 6%-10% of the total heat dissipation under some circumstances and therefore should not be simply ignored in radiator models.

Engineered cementitious composites (ECCs) are special types of fibre-reinforced cementitious composites (FRCC) with higher strain capacity which can be achieved with low fibre volume as low as 2% and total elimination of coarse aggregates. Due to the outstanding performance of ECCs, they are suitable for various construction and repair applications. However, in order for ECCs to achieve their properties; a high amount of binder which is primarily composed of Portland cement (PC) is used alongside a special type of ultrafine silica sand (USS) which is different from the conventional natural fine aggregates. The production of PC is known to be detrimental to the environment due to its high carbon dioxide emissions coupled with the high consumption of natural resources. Thus, the high use of PC content in ECCs posed a sustainability threat. Similarly, the USS used in ECCs are not readily available everywhere and are expensive. The processing of the USS coupled with its transportation over long distances would also increase the cost and embodied carbon of ECCs. Hence, in order to promote more development and applications of ECCs for various applications; this dissertation aims to provide innovative ways to improve the sustainability of ECCs and their performances. This dissertation offers four solutions to improve the sustainability of ECCs which are (i) use of unconventional industrial by-products as partial replacement of PC (ii) total replacement of PC in ECCs with alternative sustainable binders (iii) replacement of USS in ECCs with recycled materials and (iv) the use of supplementary cementitious materials to replace a high volume of PC. The findings from this study revealed sustainable ECCs with acceptable mechanical and durability performance can be achieved with the use of alternative binders or replacement of the conventional USS used in ECC mixtures. The sustainability and cost assessment of the ECCs indicated that the incorporation of industrial by-products such as blast furnace slag (BFS) especially at higher content is beneficial to reducing the negative environmental impact and economic burden associated with ECCs compared to the conventional ECC. The sustainability index and cost index of the ECCs further showed that the use of BFS is more beneficial when the sustainability and cost of the ECCs are compared with the corresponding performance. Similarly, the use of recycled materials as an alternative to USS was found to result in a significant reduction in the embodied carbon and cost of ECCs. The use of recycled materials such as expanded glass (EG) as aggregates in ECCs was also found to improve the thermal insulation properties of ECCs making such ECC suitable for the production of building envelope elements.

Modelling the economics of climate change is daunting. Many existing methodologies from social and physical sciences need to be deployed, and new modelling techniques and ideas still need to be developed. Existing bread-and-butter micro- and macroeconomic tools, such as the expected utility framework, market equilibrium concepts and representative agent assumptions, are far from adequate. Four key issues—along with several others—remain inadequately addressed by economic models of climate change, namely: (1) uncertainty, (2) aggregation, heterogeneity and distributional implications (3) technological change, and most of all, (4) realistic damage functions for the economic impact of the physical consequences of climate change. This paper assesses the main shortcomings of two generations of climate-energy-economic models and proposes that a new wave of models need to be developed to tackle these four challenges. This paper then examines two potential candidate approaches—dynamic stochastic general equilibrium (DSGE) models and agent-based models (ABM). The successful use of agent-based models in other areas, such as in modelling the financial system, housing markets and technological progress suggests its potential applicability to better modelling the economics of climate change.

An important limitation of polymer electrolyte fuel cell technology is the low mechanical strength and dimensional instability with changes of water content of proton exchange membranes (PEMs). A range of different approaches to more stable PEMs based on Nafion have been studied of which composite materials of Nafion with mechanically stronger polymers is one of the most promising directions. If successful, they will lead to thinner composite PEMs with enhanced fuel cell performance, life span, and cost-effectiveness. Developed in this thesis are electrospinning conditions for the fabrication of electrospun mats for potential application in PEMs. Polysulfone (PSU), poly vinylidene fluoride-co-hexafluoropropylene (PVDF-HFP), and polyvinylidene fluoride (PVDF) were tested as mechanically stronger but inert (minimal contribution to proton transport) polymers that can tolerate the fuel cell condition. PVDF-HFP generated defect free electrospun mats over a wide range of spinning conditions, while PSU required very specific conditions and no successful conditions were found for PVDF mostly due to over-wetting. These mats might function as mechanical support and could be tested as PEMs when filled with Nafion, but the complete filling of electrospun mats with Nafion has been proven difficult. Instead, the electrospinning of Nafion was tested to explore options of electrospinning mixed mats of two different polymers and co-electrospinning of core-sheath fibers. Two commercial Nafion solutions D520 and D2020 with 5 wt% and 20 wt% content of Nafion were electrospun together with polyethylene oxide of two different molecular weights as a carrier polymer. Mats of sufficient quality for PEM tests were obtained with solutions based on 20 wt% content of Nafion, a low flow rate of 0.2 mL/h, and the lower molecular weight polyethylene oxide as the carrier. Finally, coaxial electrospinning conditions for the formation of core-sheath fibers were developed for Nafion as sheath material and PVDF-HFP or PSU as the core material. Defect-free, core-sheath fibers were generated when the concentration of both solutions was high (20 wt%), the Nafion flow rate was about 0.2 mL/h for the sheath, and the core flow rate was below the flow rate of the sheath (0.1-0.15 mL/h for PVDF-HFP and 0.15 mL/h for PSU). Mats of these core-sheath fibers should provide good mechanical strength combined with much better compatibility with Nafion. A straightforward pore filling with Nafion solutions is expected and their investigation as PEMs in fuel cells is planned as future work.

The stability of winter wheat-flowering-date is crucial for ensuring consistent and robust crop performance across diverse climatic conditions. However, the impact of climate change on wheat-flowering-dates remains uncertain. This study aims to elucidate the influence of climate change on wheat-flowering-dates, predict how projected future climate conditions will affect flowering date stability, and identify the most stable wheat genotypes in the study region. We applied a multi-locus genotype-based (MLG-based) model for simulating wheat-flowering-dates, which we calibrated and evaluated using observed data from the Northern China winter wheat region (NCWWR). This MLG-based model was employed to project flowering dates under different climate scenarios. The simulated flowering dates were then used to assess the stability of flowering dates under varying allelic combinations in projected climatic conditions. Our MLG-based model effectively simulated flowering dates, with a root mean square error (RMSE) of 2.3 days, explaining approximately 88.5 % of the genotypic variation in flowering dates among 100 wheat genotypes. We found that, in comparison to the baseline climate, wheat-flowering-dates are expected to shift earlier within the target sowing window by approximately 11 and 14 days by 2050 under the Representative Concentration Pathways 4.5 (RCP4.5) and RCP8.5 climate scenarios, respectively. Furthermore, our analysis revealed that wheat-flowering-date stability is likely to be further strengthened under projected climate scenarios due to early flowering trends. Ultimately, we demonstrate that the combination of Vrn and Ppd genes, rather than individual Vrn or Ppd genes, plays a critical role in wheat-flowering-date stability. Our results suggest that the combination of Ppd-D1a with winter genotypes carrying the vrn-D1 allele significantly contributes to flowering date stability under current and projected climate scenarios. These findings provide valuable insights for wheat breeders and producers under future climatic conditions.

Revolutionary catalyst protection by single layer graphene capping, tremendous catalyst lifetime longevity and activity enhancement towards oxygen reduction reaction.

National net zero emission targets could, if fully implemented, reduce best estimates of projected global average temperature increase to 2.0–2.4 °C by 2100, bringing the Paris Agreement temperature goal within reach. A total of 131 countries are discussing, have announced or have adopted net zero targets, covering 72% of global emissions. These targets could substantially lower projected warming as compared to currently implemented policies (2.9–3.2 °C) or pledges submitted to the Paris Agreement (2.4–2.9 °C). Current pledges for emissions cuts are insufficient to meet the Paris Agreement temperature goal. The wave of net zero targets being discussed and adopted could make the Paris goal possible if further countries follow suit.