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Abstract The kinetics of methane hydrate decomposition was studied using a semibatch stirred-tank reactor. The decomposition was accomplished by reducing the pressure on a hydrate slurry in water to a value below the three-phase equilibrium pressure at the reactor temperature. The data were obtained at temperatures from 274 to 283 K and pressures from 0.17 to 6.97 MPa. The stirring rates were high enough to eliminate mass-transfer effects. Analysis of the data indicated that the decomposition rate was proportional to the particle surface area and to the difference in the fugacity of methane at the equilibrium pressure and the decomposition pressure. The proportionality constant showed an Arrhenius temperature dependence. An estimate of the hydrate particle diameters in the experiments permitted the development of an intrinsic model for the kinetics of hydrate decomposition.

Abstract Thermal energy storage (TES) systems are growing to a relevant role in solar cooling applications. Hence, high energy density is a desirable property of the TES system. Phase change materials (PCM) helps to increase this characteristic. A high temperature pilot plant able to test different types of TES systems and materials was designed and built at the University of Lleida (Spain). This pilot plant is composed mainly of three parts: heating system, cooling system, and different storage tanks. Two identical storage tanks based on the shell-and-tubes heat exchanger, one of them including 196 squared fins in the bundle of the tubes and the other without, were experimentally tested. Hydroquinone was selected as the storage material, having a latent heat of 205 kJ/kg and a phase change temperature between 168 and 173 °C. The aim of this paper is to test experimentally, and compare the average effectiveness of the TES systems analyzed using PCM for solar cooling and refrigeration applications. It was found out that for the same tank configurations (shell-and-tubes) even changing drastically the dimensions of the tank or the number and the diameter of the tubes, the average effectiveness curve proposed in the literature fits well with the results showed here.

The design and assessment of net-zero buildings commonly focus exclusively on the operational phase, ignoring the embodied environmental impacts over the building life cycle. An analysis is presented on the consequences of integrating embodied impacts into the assessment of the environmental advantageousness of net-zero concepts. Fundamental issues needing consideration in the design process - based on the evaluation of primary energy use and related greenhouse gas emissions - are examined by comparing three net-zero building design and assessment cases: (1) no embodied impacts included, net balance limited to the operation stage only; (2) embodied impacts included but evaluated separately from the operation stage; and (3) embodied impacts included with the operation stage in a life cycle approach. A review of recent developments in research, standardization activities and design practice and the presentation of a case study of a residential building in Norway highlight the critical importance of performance indicator definitions and system boundaries. A practical checklist is presented to guide the process of incorporating embodied impacts across the building life cycle phases in net-zero design. Its implications are considered on overall environmental impact assessment of buildings. Research and development challenges, as well as recommendations for designers and other stakeholders, are identified.

The building and construction sector is a large contributor to anthropogenic greenhouse gas emissions and consumes vast natural resources. Improvements in this sector are of fundamental importance for national and global targets to combat climate change. In this context, vertical greenery systems (VGS) in buildings have become popular in urban areas to restore green space in cities and be an adaptation strategy for challenges such as climate change. However, only a small amount of knowledge is available on the different VGS environmental impacts. This paper discusses a comparative life cycle assessment (LCA) between a building with green walls, a building with green facades and a reference building without any greenery system in the continental Mediterranean climate. This life cycle assessment is carried according to ISO 14040/44 using ReCiPe and GWP indicators. Moreover, this study fills this gap by thoroughly tracking and quantifying all impacts in all phases of the building life cycle related to the manufacturing and construction stage, maintenance, use stage (operational energy use experimentally tested), and final disposal. The adopted functional unit is the square meter of the facade. Results showed that the operational stage had the highest impact contributing by up to 90% of the total environmental impacts during its 50 years life cycle. Moreover, when considering VGS, there is an annual reduction of about 1% in the environmental burdens. However, in summer, the reduction is almost 50%. Finally, if the use stage is excluded, the manufacturing and the maintenance stage are the most significant contributors, especially in the green wall system.

Artículos en revistas Liberalization policies, the challenges of integrating distributed generation resources, and the recent flattening of electricity demand due to the economic crisis and technological change have led to lower returns for European electricity suppliers. Innovative and sustainable business models are needed to serve electricity customers while reflecting the operational needs of the system and maintaining supplier financial viability. This paper describes a novel model of Integrated Energy Services that encompasses distributed generation (DG) and demand response (DR) resources for industrial customers. We further reflect on some of the market opportunities and regulatory drivers for the development of similar schemes across Europe. info:eu-repo/semantics/publishedVersion

<div class="section abstract"><div class="htmlview paragraph">The introduction of new light-duty vehicle emission limits to comply under real driving conditions (RDE) is pushing the diesel engine manufacturers to identify and improve the technologies and strategies for further emission reduction. The latest technology advancements on the after-treatment systems have permitted to achieve very low emission conformity factors over the RDE, and therefore, the biggest challenge of the diesel engine development is maintaining its competitiveness in the trade-off “CO₂-system cost” in comparison to other propulsion systems. In this regard, diesel engines can continue to play an important role, in the short-medium term, to enable cost-effective compliance of CO₂-fleet emission targets, either in conventional or hybrid propulsion systems configuration. This is especially true for large-size cars, SUVs and light commercial vehicles.</div><div class="htmlview paragraph">In this framework, a comprehensive approach covering the whole powertrain is of primary importance in order to simultaneously meet the performance, efficiency, noise and emission targets, and therefore, further development of the combustion system design and injection system represent important levers for additional improvements. For this purpose, a dedicated 0.5 dm³ single-cylinder engine has been developed and equipped with, a state-of-the-art Euro 6 combustion system, and an advanced common rail fuel injection system (FIS) offering higher flexibility in terms of injection strategy and higher quantity accuracy. Three injector nozzles with different hydraulic flow rates (HF) have been selected and employed for the overall combustion process optimization.</div><div class="htmlview paragraph">The optimization has been performed by means of an extensive DoE-based test campaign in which the engine and FIS operating parameters have been parametrized with the aim to carry out a proper combination in terms of HF and injection strategy. The results at partial load conditions evidence significant advantages in applying an advanced injection pattern, while the HF reduction can significantly improve the smoke emission and combustion noise without fuel consumption penalties. Therefore, a proper combination and optimization of the HF and injection strategy can provide low noise and engine-out smoke while maintaining the rated power performance targets.</div></div>

A Life Cycle Assessment (LCA) with focus on carbon footprint, followed by Life Cycle Costing (LCC) of municipal solid waste (MSW) management were conducted in a residential area of a medium-sized European city of 80,000 inhabitants. The initial results showed high environmental impacts and lack of economic sustainability, due to the high amounts of waste landfilled, the low extent of separate collection, low performance of mechanical-biological treatment as well as absence from alternatives to landfilling of non-recyclable materials. Taking this result as a baseline scenario, three improvement.s were tested with the aim of turning the carbon footprint of the local MSW management system into a neutral value: (i) increased separate collection of recyclables, (ii) enhanced biogas production and (iii) refuse-derived fuel (RDF) production. Successively adding the improvements, three alternative improved scenarios were defined, until reaching a negative carbon footprint, meaning that an optimised system would avoid GHG emissions. The proposed changes were sufficient to achieve carbon neutrality, as well as reduce overall environmental impacts, but were not enough for achieving economic sustainability due to the great influence of collection costs, especially for separate collection. It was concluded that by using an adequate combination of several treatment options and increasing the separate collection of recyclable materials it is possible to turn MSW management into a carbon neutral activity as well as improve its economic balance.