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Microalgae have tremendous potential for producing liquid renewable fuel. Many methods for converting microalgae to biofuel have been proposed; however, an economical and energetically feasible route for algal fuel production is yet to be found. This paper presents a review on the comparison of the most promising conversion pathways of microalgae to liquid fuel: hydrothermal liquefaction (HTL), wet extraction and non-destructive extraction. The comparison is based on important assessment parameters of product quality and yield, nutrient recovery, GHG emissions, energy and the cost associated with the production of fuel from microalgae, in order to better understand the pros and cons of each method. It was found that the HTL pathway produces more oil than the wet extraction pathway; however, higher concentrations of unwanted components are present in the HTL oil produced. Less nutrients (N and P) can be recovered in HTL compared to wet extraction. HTL consumes more fossil energy and generates higher GHG emissions than wet extraction, while the production cost of fuel from HTL pathway is lower than wet extraction pathway. There is considerable uncertainty in the comparison of the energy consumption and economics of the HTL pathway and the wet extraction pathway due to different scenarios analysed in the assessment studies. To be able to appropriately compare methodologies, the conversion methods should be analysed from growth to upgradation of oil utilising sufficiently similar assumptions and scenarios. Based on the data in available literature, wet oil extraction is the more appropriate system for biofuel production than HTL. However, the potential of alternative extraction/conversion technologies, such as, non-destructive extraction, need to be further assessed.

It is now recognized that analytical chemistry must also be a target for green principles, in particular chromatographic methods which typically use relatively large volumes of hazardous organic solvents. More generally, high performance liquid chromatography (HPLC) is employed routinely for quality control of complex mixtures in various industries. Acetonitrile and methanol are the most commonly used organic solvents in HPLC, but they generate an impact on the environment and can have a negative effect on the health of analysts. Ethanol offers an exciting alternative as a less toxic, biodegradable solvent for HPLC. In this work we demonstrate that replacement of acetonitrile with ethanol as the organic modifier for HPLC can be achieved without significantly compromising analytical performance. This general approach is demonstrated through the specific example analysis of a complex plant extract. A benchmark method employing acetonitrile for the analysis of Bidens pilosa extract was statistically optimized using the Green Chromatographic Fingerprinting Response (GCFR) which includes factors relating to separation performance and environmental parameters. Methods employing ethanol at 30 and 80°C were developed and compared with the reference method regarding their performance of separation (GCFR) as well as by a new metric, Comprehensive Metric to Compare Liquid Chromatography Methods (CM). The fingerprint with ethanol at 80°C was similar to or better than that with MeCN according to GCFR and CM. This demonstrates that temperature may be used to replace harmful solvents with greener ones in HPLC, including for solvents with significantly different physiochemical properties and without loss in separation performance. This work offers a general approach for the chromatographic analysis of complex samples without compromising green analytical chemistry principles.

This study highlights how Chinese economic development detrimentally impacted water quality in recent decades and how this has been improved by enormous investment in environmental remediation funded by the Chinese government. To our knowledge, this study is the first to describe the variability of surface water quality in inland waters in China, the affecting drivers behind the changes, and how the government-financed conservation actions have impacted water quality. Water quality was found to be poorest in the North and the Northeast China Plain where there is greater coverage of developed land (cities + cropland), a higher gross domestic product (GDP), and higher population density. There are significant positive relationships between the concentration of the annual mean chemical oxygen demand (COD) and the percentage of developed land use (cities + cropland), GDP, and population density in the individual watersheds (p < 0.001). During the past decade, following Chinese government-financed investments in environmental restoration and reforestation, the water quality of Chinese inland waters has improved markedly, which is particularly evident from the significant and exponentially decreasing GDP-normalized COD and ammonium (NH4+-N) concentrations. It is evident that the increasing GDP in China over the past decade did not occur at the continued expense of its inland water ecosystems. This offers hope for the future, also for other industrializing countries, that with appropriate environmental investments a high GDP can be reached and maintained, while simultaneously preserving inland aquatic ecosystems, particularly through management of sewage discharge.

Abstract The housing growth programme could offer an opportunity for accelerating the deployment of decentralised renewable energy systems (DRES) in the UK. The Government hopes to leverage private sector investment into DRES as part of new housing projects. The aim of this paper is to assess whether current regulatory and funding frameworks are sufficient to achieve this. The question is explored by drawing on the experience of developers, local authorities, energy utilities and service companies operating in the largest housing growth region in the UK–Thames Gateway. Their experience suggests that the current low intervention approach will be insufficient to generate the shift required in both industries. In order to be more successful economic and regulatory instruments should focus on producers (house-builders and energy providers) rather than consumers (households). Tighter regulation is needed to ensure that producers have a responsibility to install DRES as part of new developments, to enable connection to the grid, to ensure a sustained financial return from investment and revenue is spent on the expansion of new renewable energy infrastructure. This regulatory framework must be under-pinned by substantial funds focused on producers. Greater intervention is needed if DRES is to be included in new housing development.

Abstract There are instances in remote areas where heat is being wasted, e.g., in internal combustion, engines, etc. Some of this heat can be recovered to produce distilled water in solar stills. The solar still replaces the cooling tower, ponds, or radiators normally used to control the engine temperature. The diesel cooling water in such a system remains separate from the saline water in the solar still. The advantages of using such a system compared with a conventional solar still are: 1. (a) water costs are very much reduced 2. (b) the area occupied is much less, i.e., about 1 5 th 3. (c) production has much less seasonal variation 4. (d) the efficiency of the solar still is improved due to the higher operating temperatures. From experiments conducted at Highett using a Mk VI solar still fitted with a simple heat exchanger and a separate electrically-heated source of hot water to simulate the waste heat, design data are not available for application to working systems. The information required to match a solar still to a diesel's cooling requirement is: 1. (a) engine efficiency 2. (b) hourly fuel consumption 3. (c) hourly solar radiation 4. (d) hourly ambient temperatures. A by-product of this work has been the production of a “solar water heater” which costs less than that of the cheapest conventional system. This “solar” hot water system uses a heat exchanger similar to what is used to transfer the waste heat to the saline water. It is envisaged to have hot water productions approximately the same as the distilled water productions. The influence of hot water production on the output of the waste heat solar still is discussed.

This paper describes anaerobic thermophilic sludge digestion (55 °C) in a continuously stirred tank reactor (CSTR) on a pilot-plant scale (150 L). The experimental protocol was defined to examine the effect of the increase in the organic loading rate on the efficiency of the digester and to report on its steady-state performance. The reactor was subjected to a programme of steady-state operation over a range of solids retention times (SRTs) of 75, 40, 27, 20 and 15 days and organic loading rates (OLR) in the range 0.4–2.2 kg VS/(m3 day). The digester was fed with raw sludge (containing approximately 35 kg/m3 volatile solids (VS)) once daily during the 75-day SRT period, twice daily during the 40-day SRT period and three times a day during the 27-, 20- and 15-day SRT periods. The reactor was initially operated with an organic loading rate of 0.4 kg VS/(m3 day) and an SRT of 75 days. The volatile solids removal efficiency in the reactor was found to be 73%, while the volumetric methane production rate produced in the digester reached 0.02 m3/(m3 day). Over a 338-day operating period, an OLR of 2.2 kg VS/(m3 day) was achieved with 49.1% VS removal efficiency in the pilot sludge digester, at which time the volumetric methane production rate content of biogas produced in the digester reached 0.4 m3/(m3 day). The chemical oxygen demand (COD) mass balance obtained indicated that COD used for methane generation increased when the SRT was decreased or when the influent organic loading rate was increased. This implies that the amount of COD used in the anabolism route decreased with SRT due the microbial population becoming adapted to new operational conditions and more COD being used to generate methane.

Abstract Decentralised energy in the UK is rare. Cities in the north of England however lead the UK in terms of sustainable, low-carbon, local/district heating, through the implementation of combined-heat-and-power (CHP) facilities; substantial schemes are installed in several cities, including Barnsley and Sheffield. This paper presents the results from extensive experimental and theoretical feasibility studies, in which the merits of these were explored. Barnsley has a number of biomass-fuelled community energy generators, where pollutant monitoring and mathematical modelling were conducted to assess combustion characteristics and overall system performance. Measured pollutant levels were within the relative emission limits, though emission concentrations (CO, CO2, NO and particles) in the flue gas from the coal boiler were higher than the wood pellet boiler. Sheffield already has a citywide district energy network, centred around a sustainably-sourced waste-to-energy facility; an expansion of this scheme was investigated here. This focuses mainly on the link to a 30 MW wood-fired CHP plant, which could be a significant provider of additional thermal capacity (low-grade heat) to an expanded network. Through identifying heat sources and sinks – potential suppliers and end-users – key areas were identified where a connection to the heat network would be feasible.

As presented in the first companion paper, distributed mixed-integer fuzzy hierarchical programming (DMIFHP) was developed for municipal solid waste management (MSWM) under complexities of heterogeneities, hierarchy, discreteness, and interactions. Beijing was selected as a representative case. This paper focuses on presenting the obtained schemes and the revealed mechanisms of the Beijing MSWM system. The optimal MSWM schemes for Beijing under various solid waste treatment policies and their differences are deliberated. The impacts of facility expansion, hierarchy, and spatial heterogeneities and potential extensions of DMIFHP are also discussed. A few of findings are revealed from the results and a series of comparisons and analyses. For instance, DMIFHP is capable of robustly reflecting these complexities in MSWM systems, especially for Beijing. The optimal MSWM schemes are of fragmented patterns due to the dominant role of the proximity principle in allocating solid waste treatment resources, and they are closely related to regulated ratios of landfilling, incineration, and composting. Communities without significant differences among distances to different types of treatment facilities are more sensitive to these ratios than others. The complexities of hierarchy and heterogeneities pose significant impacts on MSWM practices. Spatial dislocation of MSW generation rates and facility capacities caused by unreasonable planning in the past may result in insufficient utilization of treatment capacities under substantial influences of transportation costs. The problems of unreasonable MSWM planning, e.g., severe imbalance among different technologies and complete vacancy of ten facilities, should be gained deliberation of the public and the municipal or local governments in Beijing. These findings are helpful for gaining insights into MSWM systems under these complexities, mitigating key challenges in the planning of these systems, improving the related management practices, and eliminating potential socio-economic and eco-environmental issues resulting from unreasonable management.

Abstract Algae have been considered as a promising biodiesel feedstock. One of the major factors affecting large-scale algae technology application is poor wintering cultivation performance. In this study, an integrated approach is investigated combining freshwater microalgae Chlorella zofingiensis wintering cultivation in pilot-scale photobioreactors with artificial wastewater treatment. Mixotrophic culture with the addition of acetic acid (pH-regulation group) and autotrophic culture (control group) were designed, and the characteristics of algal growth, lipid and biodiesel production, and nitrogen and phosphate removal were examined. The results showed that, by using acetic acid three times per day to regulate pH at between 6.8 and 7.2, the total nitrogen (TN) and total phosphate (TP) removal could be increased from 45.2% to 73.5% and from 92.2% to 100%, respectively. Higher biomass productivity of 66.94 mg L−1 day−1 with specific growth rate of 0.260 day−1 was achieved in the pH-regulation group. The lipid content was much higher when using acetic acid to regulate pH, and the relative lipid productivity reached 37.48 mg L−1 day−1. The biodiesel yield in the pH-regulated group was 19.44% of dry weight, with 16–18 carbons as the most abundant composition for fatty acid methyl esters. The findings of the study prove that pH adjustment using acetic acid is efficient in cultivating C. zofingiensis in wastewater in winter for biodiesel production and nutrient reduction.