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Interfacial resistance at electrode‐high Li+ conductive solid electrolytes must be reduced well to develop high‐power all‐solid‐state batteries using oxide‐based solid electrolytes (Ox‐SSBs). Herein, crystalline electrode films of LiCoO2 (LCO) are formed on a high Li+ conductive crystalline‐glass solid electrolyte sheet, Li1.3Al0.3Ti2(PO4)3 (LATP) (σ25 °C = 1 × 10−4 S cm−1), at room temperature by aerosol deposition (AD), and the effects of the annealing temperature on the interfacial resistivities (Rint) at the LCO/LATP are investigated. The Rint visibly increases by annealing over 500 °C with the growth of Co3O4 as a reactant. In contrast, Rint is reduced to ≈100 Ω cm2 by low‐temperature annealing at 250–350 °C due to superior contact through the structural rearrangement of an artificial metastable interface formed by the AD. These results are applied to bulk‐type Ox‐SSB, Li/Li7La3Zr2O12(LLZ)/LCO–LATP, and our best Ox‐SSB delivers a discharge capacity of 100 mA cm−2 at 100 °C.

Abstractπ‐Conjugated polyelectrolytes (CPEs) have been studied as interlayers on top of a separate hole transport layer (HTL) to improve the wetting, interfacial defect passivation, and crystal growth of perovskites. However, very few CPE‐based HTLs have been reported without rational molecular design as ideal HTLs for perovskite solar cells (PeSCs). In this study, the authors synthesize a triphenylamine‐based anionic CPE (TPAFS‐TMA) as an HTL for p‐i‐n‐type PeSCs. TPAFS‐TMA has appropriate frontier molecular orbital (FMO) levels similar to those of the commonly used poly(bis(4‐phenyl)‐2,4,6‐trimethylphenylamine) (PTAA) HTL. The ionic and semiconducting TPAFS‐TMA shows high compatibility, high transmittance, appropriate FMO energy levels for hole extraction and electron blocking, as well as defect passivating properties, which are confirmed using various optical and electrical analyses. Thus, the PeSC with the TPAFS‐TMA HTL exhibits the best power conversion efficiency (PCE) of 20.86%, which is better than that of the PTAA‐based device (PCE of 19.97%). In addition, it exhibits negligible device‐to‐device variations in its photovoltaic performance, contrary to the device with PTAA. Finally, a large‐area PeSC (1 cm2) and mini‐module (3 cm2), showing PCEs of 19.46% and 18.41%, respectively, are successfully fabricated. The newly synthesized TPAFS‐TMA may suggest its great potential as an HTL for large‐area PeSCs.

Abstract Background Parabolic Trough Solar Collector (PTSC) is one of the most popular and an effective device that converts solar radiation into a heat or useful energy. However, it suffers from high temperature gradient and low thermal efficiency. The solution for this problem is to use new advanced coolants (hybrid nanofluids) in order to enhance PTSC's thermal efficiency. Methods A numerical analysis on the thermo-hydraulic performance of a PTSC receiver's tube equipped with conical turbulators is presented. The Navier-Stokes equations are solved using Finite Volume Method (FVM) coupled with Monte Carlo Ray Tracing (MCRT) method. The flow and thermal characteristics as well as entropy generation of the PTSC's receiver tube are investigated for three hybrid nanofluids (Ag-SWCNT, Ag-MWCNT, and Ag-MgO) having a mixing ratio of (50:50) dispersed in Syltherm oil 800, Reynolds number (5000 to 100,000) and fluid inlet temperatures (400 to 650 K). Significant findings The conical turbulators effectively augmented the thermal performance by 233.4% utilising Ag-SWCNT/Syltherm oil instead of pure Syltherm oil. The performance evaluation criterion is found to be in the range of 0.9–1.82. The thermal and exergetic efficiencies increased by 11.5% and 18.2%, respectively. The maximum decrement in the entropy generation rate and entropy generation ratio are 42.7% and 33.7%.

Abstract A new conical-cylindrical top-discharge blow tank is designed, by introducing the pulsed gas to facilitate discharging, for stable transportation for kaolin powders. A series of experimental studies on pulsed gas characteristic parameters like pulsed gas flow rate Qpulsed (5 m3/h ≤ Qpulsed ≤ 25 m3/h), pulsed interval tpulsed (1 s ≤ tpulsed ≤ 5 s) and pulsed width τpulsed (50 ms ≤ τpulsed ≤ 250 ms) are conducted with the fluidized gas flow rate of 12 m3/h. The experiments mainly test the powder mass flow rate and solid-gas ratio in the conveying process. The results indicate that the mass flow rate and solid-gas ratio range 12.6–278.04 kg/h and 0.9–19.56 kg/m3, respectively. With the increase of the pulsed gas flow rate, the mass flow rate and solid gas ratio first increase and then decrease. When the ratio of fluidized gas flow rate to pulsed gas flow rate is within 0.8–1.2, its conveying capacity reaches the maximum. Meanwhile, the increase in the pulsed interval leads to the decrease of the mass flow rate and solid-gas ratio. Moreover, the increase in the pulsed width leads to the initial increase and then the stabilization of the mass flow rate and solid gas ratio. When the pulsed width is 50 ms, the improvement of discharge would small. Conversely, increasing the pulsed width can increase the discharge, and stabilize subsequently until over 200 ms. Besides, moisture content is one of the important factors affecting kaolin powders discharge. When the moisture content is 0.83%, the pulsed gas does not improve the discharge significantly. Meanwhile, pressure distribution at different locations in the tank is also measured. The results reveal that the introduction of pulsed gas changes the pressure distribution in the tank. A pressure zone is formed on the upper part of the tank, which promotes the powder discharge.

Much of New South Wales and southern Queensland suffered from extreme drought from 2017 to 2019. This study models drought and bushfires impacts using VU‐TERM, a multi‐regional, dynamic CGE model. Prolonged drought pushed national real GDP to 0.7 per cent or more below base in 2018–2019 and 2019–2020. NSW’s real GDP fell relative to forecast by 1.1 per cent or $6.9 billion in 2018–2019 and 1.6 per cent or $10.2 billion in 2019–2020. These impacts reflect a severe diminution of farm output, given that agriculture accounts for around 1.6 per cent of NSW’s income. Bushfires exacerbated 2019–2020 losses. We assume that there is a full recovery in seasonal conditions in 2020. However, prolonged drought and bushfire destruction deplete farm capital through depressed investment and diminished herd numbers. Consequently, the income earning capacity of farms in recovery remains below that of a no drought base. The net present value of the national welfare loss is $63 billion, split between $53 billion in losses from drought and $10 billion from bushfires. The latter excludes any valuation of human lives lost, flora, fauna or forestry destruction. In the longer term, adaptation and policy responses will need to reflect the expectation of increased frequency of adverse climatic events.

Abstract It is demonstrated that the fuel deposit has a significant influence on the NOx and particular matter (PM) emissions, especially with the consideration of the more and more strict emission regulations issued by the governments, which results in that the near-nozzle spray has been received the increased attention, recently. In this study, the near-nozzle spray characteristics at the initial and end stages were investigated by a high-resolution camera with a laser as the light source. At the initial stage, microscopic behaviors of the near-nozzle spray were observed at upstream, midstream and downstream, respectively. Moreover, the injection frequency was changed to check the effect on the near-nozzle spray morphology. Next, the micro spray length, width and angle were obtained from the processed images. While, at the end stage, the near-nozzle spray evolutions were observed and characterized at 0.5, 0.3, 0.2 and 0.1 ms before the end of injection (BEOI), the end of injection (EOI), 0.05, 0.1, 0.15 and 0.2 ms after the end of injection (AEOI), respectively. Furthermore, the droplet area, spray area without droplets, droplet number and averaged diameter were calculated. Results show that three structures of the near-nozzle spray at the initial stage can be classified as mushroom, steeple and cylinder shapes. And the injection frequency has an influence on their formations owing to the residual fuel and sucked air AEOI. Moreover, although more droplets can be identified at the end stage with time, it does not indicate the better atomization. On the contrary, these droplets AEOI are responsible for the injector deposit in the real engine.