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Microalgae have tremendous potential for producing liquid renewable fuel. Many methods for converting microalgae to biofuel have been proposed; however, an economical and energetically feasible route for algal fuel production is yet to be found. This paper presents a review on the comparison of the most promising conversion pathways of microalgae to liquid fuel: hydrothermal liquefaction (HTL), wet extraction and non-destructive extraction. The comparison is based on important assessment parameters of product quality and yield, nutrient recovery, GHG emissions, energy and the cost associated with the production of fuel from microalgae, in order to better understand the pros and cons of each method. It was found that the HTL pathway produces more oil than the wet extraction pathway; however, higher concentrations of unwanted components are present in the HTL oil produced. Less nutrients (N and P) can be recovered in HTL compared to wet extraction. HTL consumes more fossil energy and generates higher GHG emissions than wet extraction, while the production cost of fuel from HTL pathway is lower than wet extraction pathway. There is considerable uncertainty in the comparison of the energy consumption and economics of the HTL pathway and the wet extraction pathway due to different scenarios analysed in the assessment studies. To be able to appropriately compare methodologies, the conversion methods should be analysed from growth to upgradation of oil utilising sufficiently similar assumptions and scenarios. Based on the data in available literature, wet oil extraction is the more appropriate system for biofuel production than HTL. However, the potential of alternative extraction/conversion technologies, such as, non-destructive extraction, need to be further assessed.

Low-salinity water injection emerges to be a cost-effective and environmentally friendly enhanced oil recovery technique. Furthermore, additives, such as the surfactant and nanoparticles in combina...

Abstract In this paper, we investigate distributed thermal-electrochemical modeling of a Lithium-Ion battery cell to include the effect of temperature distribution across the thickness of the cell as a first step to study the module level temperature distribution at high charging rates. Most recent works have focused on lumped thermal models for a Li-Ion cell which ignore any temperature differential across cell thickness. However, even a small temperature differential across cell thickness at the cell level can contribute to significant temperature differential in the thickness direction of stacked-up Li-Ion cells at the module level. Such temperature differential can potentially impact the battery charging control system, especially at high charging rates. Here, the thermal-electrochemical partial differential and algebraic equations for a Li-ion cell are solved via a spatial finite difference method. Simulation results show that the temperature differentials over the cell thickness at the cell level are not insignificant, particularly at high charging rates.

Abstract This paper presents a numerical study of the particle cluster behavior in a riser/downer reactor by means of combined computational fluid dynamics (CFD) and discrete element method (DEM), in which the motion of discrete particles is obtained by solving Newton's equations of motion and the flow of continuum gas by the Navier–Stokes equations. It is shown that the existence of particle clusters, unique to the solid flow behavior in such a reactor, can be predicted from this first principle approach. The results demonstrate that there are two types of clusters in a riser and downer: one is in the near wall region where the velocities of particles are low; the other is in the center region where the velocities of particles are high. While the extent of particle aggregation appears to be similar, the duration time for the first type in a downer is shorter than in a riser. Furthermore, it is demonstrated that the formation of clusters is affected by a range of variables related to operational conditions, particle properties, and bed properties and geometry. The increase of solid volume fraction, sliding and rolling friction between particles or between particles and wall, or damping coefficient can enhance the formation of clusters. The use of multi-sized particles can also promote the formation of clusters. But the increase of gas velocity or use of a wider bed can suppress the formation of clusters. The van der Waals force may enhance the formation of clusters when solid concentration is high but suppress the formation of clusters near the wall region when solid concentration is low.

In this paper, a comparison of power system frequency response is conducted for a simple modelled power system with primary frequency control being provided either by synchronous generators or by inverter-based Battery Energy Storage (BES) systems. Mathematical models of conventional governor and turbine are developed, representing conventional synchronous generator frequency control, and are used to illustrate system frequency response for a range of typical conventional generating units. A mathematical model of a power-electronics interfaced Li-ion BES system is developed and used to represent a non-synchronous inverter-based generator with primary frequency control capabilities. MATLAB/Simulink is used to build a model of a small power system, and simulations are carried out with at a range of typical conventional synchronous generating units with a nonsynchronous generating unit in the power system. The simulation results demonstrate that the BES can be used for primary frequency control providing a faster and better response. BES is also capable of almost eliminating frequency overshoot and reducing 70% of settling time while providing primary frequency control in power system with various types of conventional synchronous generating units and a nonsynchronous generating unit.

Abstract To improve the conversion efficiency of thermophotovoltaic devices, we designed a thermophotovoltaic system based on an InAs/InGaAsSb/GaSb three-junction tandem cell. The tandem cell can recover photons in the wavelength range of 200–3650 nm and therefore enhance the output power of the system. To further improve system performance, we designed a multilayer circular truncated cone metamaterial emitter matching the tandem cell. Existing TPV systems based on multi-junction tandem PV cells can achieve conversion efficiencies of 33.3%–41%, while the thermophotovoltaic system coupled with the multilayer circular truncated cone metamaterial can recover more photons of 1.44 mol/(m2·s) and achieve a higher conversion efficiency of 52.8% at 1773 K. The thermophotovoltaic system designed here demonstrates an extremely high energy conversion efficiency and has good application prospects.

Abstract The use of organic additives in zinc electroplating is reviewed with particular emphasis on the types of compounds used, the bath type for which they are most suited, and their function with respect to brightening and levelling action. Fundamental studies of the mode of action of these additives are also reviewed and comparisons are made with similar studies of nickel and copper electrodeposition. It is concluded that much more fundamental studies are required to fully explain the effects of additives. Further, the effect of codeposition of organic impurities on the corrosion resistance of electrodeposited zinc requires urgent study.

Abstract This study evaluates the performance of 75 clear-sky global irradiance models against 75 ground stations worldwide covering five major Koppen-Geiger climate classifications and overall global performance. After quality control, clear-sky detection and data-availability criteria, there are 4.36 million 1-min valid global horizontal irradiance (GHI) data points for evaluation. This study represents the most encompassing evaluation of its kind in terms of number of models assessed, number of ground stations used, most consistent selection of input variables in terms of temporal and spatial resolution, also using the most rigorous and fair performance assessment criteria and suitable ranking system. A statistically rigorous Principal Component Analysis (PCA) ranking procedure is proposed to replace the conventional ordering method based on single and simple statistics. In particular, it is demonstrated that all 13 error metrics contribute to the variance of GHI estimation and thus must all be accounted for in the ranking procedure. The best performing models in each climate zone of equatorial, arid, temperate, cold and polar are REST2v9.1, REST2v9.1, MAC2, REST2v5 and CLS, respectively. Globally, the top three performing models are MAC2, REST2v5, and REST2v9.1. Many models appear to suffer from over-fitting empirical relationships to training data, resulting in inconsistent worldwide performance. Furthermore, six different formulations of the Linke Turbidity factor (TL) are evaluated through its application to five clear-sky models that require it as an input. The best globally performing TL formulations are either by Ineichen or Gueymard when combined with four of the five Linke-dependent clear-sky models, whilst the Grenier formulation performs best with the Ineichen & Perez model. Significant performance variation is observed depending on the TL formulation selected, hence, careful selection is required for an optimal application. The model codes are available in R [1].

Abstract There are instances in remote areas where heat is being wasted, e.g., in internal combustion, engines, etc. Some of this heat can be recovered to produce distilled water in solar stills. The solar still replaces the cooling tower, ponds, or radiators normally used to control the engine temperature. The diesel cooling water in such a system remains separate from the saline water in the solar still. The advantages of using such a system compared with a conventional solar still are: 1. (a) water costs are very much reduced 2. (b) the area occupied is much less, i.e., about 1 5 th 3. (c) production has much less seasonal variation 4. (d) the efficiency of the solar still is improved due to the higher operating temperatures. From experiments conducted at Highett using a Mk VI solar still fitted with a simple heat exchanger and a separate electrically-heated source of hot water to simulate the waste heat, design data are not available for application to working systems. The information required to match a solar still to a diesel's cooling requirement is: 1. (a) engine efficiency 2. (b) hourly fuel consumption 3. (c) hourly solar radiation 4. (d) hourly ambient temperatures. A by-product of this work has been the production of a “solar water heater” which costs less than that of the cheapest conventional system. This “solar” hot water system uses a heat exchanger similar to what is used to transfer the waste heat to the saline water. It is envisaged to have hot water productions approximately the same as the distilled water productions. The influence of hot water production on the output of the waste heat solar still is discussed.