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Microalgae have tremendous potential for producing liquid renewable fuel. Many methods for converting microalgae to biofuel have been proposed; however, an economical and energetically feasible route for algal fuel production is yet to be found. This paper presents a review on the comparison of the most promising conversion pathways of microalgae to liquid fuel: hydrothermal liquefaction (HTL), wet extraction and non-destructive extraction. The comparison is based on important assessment parameters of product quality and yield, nutrient recovery, GHG emissions, energy and the cost associated with the production of fuel from microalgae, in order to better understand the pros and cons of each method. It was found that the HTL pathway produces more oil than the wet extraction pathway; however, higher concentrations of unwanted components are present in the HTL oil produced. Less nutrients (N and P) can be recovered in HTL compared to wet extraction. HTL consumes more fossil energy and generates higher GHG emissions than wet extraction, while the production cost of fuel from HTL pathway is lower than wet extraction pathway. There is considerable uncertainty in the comparison of the energy consumption and economics of the HTL pathway and the wet extraction pathway due to different scenarios analysed in the assessment studies. To be able to appropriately compare methodologies, the conversion methods should be analysed from growth to upgradation of oil utilising sufficiently similar assumptions and scenarios. Based on the data in available literature, wet oil extraction is the more appropriate system for biofuel production than HTL. However, the potential of alternative extraction/conversion technologies, such as, non-destructive extraction, need to be further assessed.

It is now recognized that analytical chemistry must also be a target for green principles, in particular chromatographic methods which typically use relatively large volumes of hazardous organic solvents. More generally, high performance liquid chromatography (HPLC) is employed routinely for quality control of complex mixtures in various industries. Acetonitrile and methanol are the most commonly used organic solvents in HPLC, but they generate an impact on the environment and can have a negative effect on the health of analysts. Ethanol offers an exciting alternative as a less toxic, biodegradable solvent for HPLC. In this work we demonstrate that replacement of acetonitrile with ethanol as the organic modifier for HPLC can be achieved without significantly compromising analytical performance. This general approach is demonstrated through the specific example analysis of a complex plant extract. A benchmark method employing acetonitrile for the analysis of Bidens pilosa extract was statistically optimized using the Green Chromatographic Fingerprinting Response (GCFR) which includes factors relating to separation performance and environmental parameters. Methods employing ethanol at 30 and 80°C were developed and compared with the reference method regarding their performance of separation (GCFR) as well as by a new metric, Comprehensive Metric to Compare Liquid Chromatography Methods (CM). The fingerprint with ethanol at 80°C was similar to or better than that with MeCN according to GCFR and CM. This demonstrates that temperature may be used to replace harmful solvents with greener ones in HPLC, including for solvents with significantly different physiochemical properties and without loss in separation performance. This work offers a general approach for the chromatographic analysis of complex samples without compromising green analytical chemistry principles.

This study highlights how Chinese economic development detrimentally impacted water quality in recent decades and how this has been improved by enormous investment in environmental remediation funded by the Chinese government. To our knowledge, this study is the first to describe the variability of surface water quality in inland waters in China, the affecting drivers behind the changes, and how the government-financed conservation actions have impacted water quality. Water quality was found to be poorest in the North and the Northeast China Plain where there is greater coverage of developed land (cities + cropland), a higher gross domestic product (GDP), and higher population density. There are significant positive relationships between the concentration of the annual mean chemical oxygen demand (COD) and the percentage of developed land use (cities + cropland), GDP, and population density in the individual watersheds (p < 0.001). During the past decade, following Chinese government-financed investments in environmental restoration and reforestation, the water quality of Chinese inland waters has improved markedly, which is particularly evident from the significant and exponentially decreasing GDP-normalized COD and ammonium (NH4+-N) concentrations. It is evident that the increasing GDP in China over the past decade did not occur at the continued expense of its inland water ecosystems. This offers hope for the future, also for other industrializing countries, that with appropriate environmental investments a high GDP can be reached and maintained, while simultaneously preserving inland aquatic ecosystems, particularly through management of sewage discharge.

Abstract There are instances in remote areas where heat is being wasted, e.g., in internal combustion, engines, etc. Some of this heat can be recovered to produce distilled water in solar stills. The solar still replaces the cooling tower, ponds, or radiators normally used to control the engine temperature. The diesel cooling water in such a system remains separate from the saline water in the solar still. The advantages of using such a system compared with a conventional solar still are: 1. (a) water costs are very much reduced 2. (b) the area occupied is much less, i.e., about 1 5 th 3. (c) production has much less seasonal variation 4. (d) the efficiency of the solar still is improved due to the higher operating temperatures. From experiments conducted at Highett using a Mk VI solar still fitted with a simple heat exchanger and a separate electrically-heated source of hot water to simulate the waste heat, design data are not available for application to working systems. The information required to match a solar still to a diesel's cooling requirement is: 1. (a) engine efficiency 2. (b) hourly fuel consumption 3. (c) hourly solar radiation 4. (d) hourly ambient temperatures. A by-product of this work has been the production of a “solar water heater” which costs less than that of the cheapest conventional system. This “solar” hot water system uses a heat exchanger similar to what is used to transfer the waste heat to the saline water. It is envisaged to have hot water productions approximately the same as the distilled water productions. The influence of hot water production on the output of the waste heat solar still is discussed.

Electricity generation systems have traditionally been evaluated using only a limited number of economic or environmental indicators, for example capital investment, generation cost or carbon dioxide emissions. Moreover, the evaluations have generally been restricted to performance within the geographic boundary of the power station. This paper reports a sustainability assessment of power generation from Australian fossil fuels, notably black coal, brown coal and natural gas. A range of key sustainability indicators incorporating environmental, economic and social performance are included. The system boundary incorporates fuel extraction, fuel transport to the power station, generation of power, and transmission of electricity to the point of use. Most commonly employed existing technologies and some promising advanced technologies for power generation are considered. The cases of exporting Australian LNG and black coal to Japan for power generation in that country have also been considered. No one fuel or technology system was superior or inferior for every indicator. However the following generalizations can be made: Natural gas combined cycle systems have advantages for the majority of environmental and economic indicators, brown coal has an advantage in terms of value added, and black coal has relatively poor safety performance.

Abstract In recent years, modern appliances with high electricity demand have played a significant role in residential energy consumption. Despite the positive impact of these appliances on the quality of life, they suffer from major drawbacks, such as serious environmental concerns and high electricity bills. This paper introduces a consolidated framework of load management to alleviate those drawbacks. Initially, benefiting from a demonstrative analysis of home energy consumption data, controllable and responsive appliances in smart home are identified. Then, the energy consumption pattern is reduced and shifted using flexible load models and better utilization of existing energy storage systems. This can be achieved through data mining approaches, i.e., density-based spatial clustering of application with noise (DBSCAN) method. In this technique, no sensor for detection or measurement instruments will be required, whose deployment incur cost to the system or increase security risk for consumers. In the following, one scheduling of using controllable appliances, which is formulated by convex optimization, is considered for the demand response (DR) program, provided that this plan doesn't affect customers’ priority and convenience. In the last stage, the deployment of energy storage systems, such as plug-in hybrid electric vehicles (PHEVs) and battery energy storage systems (BESS), is introduced to lower the energy cost and improve the performance of the proposed DR model. Simulation results of this demand response are compared with conventional k-clustering methods to confirm the economic superiority of the DBSCAN clustering technique using the data of a residential unit during three different scenarios.

The design and assessment of net-zero buildings commonly focus exclusively on the operational phase, ignoring the embodied environmental impacts over the building life cycle. An analysis is presented on the consequences of integrating embodied impacts into the assessment of the environmental advantageousness of net-zero concepts. Fundamental issues needing consideration in the design process - based on the evaluation of primary energy use and related greenhouse gas emissions - are examined by comparing three net-zero building design and assessment cases: (1) no embodied impacts included, net balance limited to the operation stage only; (2) embodied impacts included but evaluated separately from the operation stage; and (3) embodied impacts included with the operation stage in a life cycle approach. A review of recent developments in research, standardization activities and design practice and the presentation of a case study of a residential building in Norway highlight the critical importance of performance indicator definitions and system boundaries. A practical checklist is presented to guide the process of incorporating embodied impacts across the building life cycle phases in net-zero design. Its implications are considered on overall environmental impact assessment of buildings. Research and development challenges, as well as recommendations for designers and other stakeholders, are identified.

The concept of resilience is a crucial part in crafting visions of desirable futures designed to withstand the widest variety of external shocks to the system. Backcasting scenarios are widely used to envision desirable futures with a discontinuous change from the present in mind. However, less effort has been devoted to developing theoretical frameworks and methods for building backcasting scenarios with a particular focus on resilience, although resilience has been explored in related sustainability fields. This paper proposes a method that helps design backcasting scenarios for resilient futures. A characteristic of the method is to delineate “collapse” futures, based upon which resilient futures are described to avoid the various collapsed states. In the process of designing backcasting scenarios, fault tree analysis (FTA) is used to support the generation of various risk factors and countermeasures to improve resilience. In order to test the effectiveness of the proposed method, we provide a case study to describe resilient energy systems for a Japanese community to 2030. Four expert workshops involving researchers from different disciplines were organized to generate diversified ideas on resilient energy systems. The results show that three scenarios of collapsed energy systems were described, in which policy options to be taken toward achieving resilient energy systems were derived.