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The drought prone North-West Bangladesh is vulnerable to the impacts of climate change, particularly because of less water availability in the dry period and high water requirement for crop production. Improved understanding of recent changes in crop water demand in the dry season is important for the water resources management in the region. A study was carried out to determine the potential impacts of recent climate change during last three decades on trends of water requirements of Boro rice. The reference crop evapotranspiration (ETo), potential crop water requirement (∑ETC), effective rainfall during the crop growing period (ER), potential irrigation requirement for crop evapotranspiration (∑ETC − ER) and net irrigation requirement of Boro rice were estimated using observed daily climate data in the CropWat model for the period of 1980 to 2013 for four North-West districts. Significant decreasing trends of ETo were observed in most of the dry months due to increasing relative humidity and decreasing wind-speed and sun-shine hours. The results showed decreasing trends of potential crop water requirement, i.e. the total crop evapotranspiration (∑ETC), of Boro rice due to decreasing reference crop evapotranspiration and shorter crop growing periods. The variations in trends of potential irrigation requirement for crop evapotranspiration (∑ETC − ER) found among different districts, are mainly linked to variations in trends of changes in effective rainfall. The net irrigation requirement of Boro rice has decreased, by 11% during the last three decades at an average rate of −4.4 mm year−1, instead of decreasing effective rainfall, mainly because of high rate of decrease of crop evapotranspiration (−5.9 mm year−1). Results indicate that a warming climate does not always result in higher agricultural water use and that climate change can also result in reduced water demands because of changes in humidity, wind-speed and sun-shine hours.

Forest biomass is one of the main contributors to the EU's renewable energy target of 20% gross final energy consumption in 2020 (Renewable Energy Directive). Following the RED, new sustainability principles are launched by the European energy sector, such as the Initiative Wood Pellet Buyers (IWPB or SBP). The aim of our study is the investigation of the quantitative impacts from IWPB's principles for forest biomass for energy only. We deploy a bottom up method that quantifies the supplies and the costs from log harvest until forest chip delivery at a domestic consumer. We have a reference situation with existing national (forest) legislation and voluntary certification schemes (scenario 1) and a future situation with additional criteria based on the IWPB principles (scenario 2). Two country studies were selected for our (2008) survey: one in Finland with nearly 100% certification and one in Leningrad province with a minor areal share of certification in scenario 1. The sustainable potential of forest resources for energy is about 54 Mm3 (385 PJ) in Finland and about 13.5 Mm3 (95 PJ) in Leningrad in scenario 1 without extra criteria. The potential volumes reduce considerably by maximum 43% respectively 39% after new criteria from the IWPB, like a minimum use of sawlogs, stumps and slash for energy, and by an increased area of protected forests (scenario 2A Maximum extra restrictions). In case sawlogs can be used, but instead ash recycling is applied after a maximum stump and slash recovery (scenario 2B Minimum extra restrictions), the potential supply is less reduced: 5% in Finland and 22% in Leningrad region. The estimated reference costs for forest chips are between €18 and €45 solid m-3 in Finland and between €7 and €33 solid m-3 in the Leningrad region. In scenario 2A, the costs will mainly increase by €7 m-3 for delimbing full trees (Finland), and maximum €0.3 m-3 for suggested improved forest management (Leningrad region). In scenario 2B, when ash recycling is applied, costs increase by about €0.3 to €1.6 m-3, depending on the rate of soil contamination. This is an increase of 2%, on top of the costs in scenario 2A.

The Carpathian mountain region is one of the most significant natural refuges on the European continent. It is home to Europe’s most extensive tracts of montane forest, the largest remaining virgin forest and natural mountain beech-fir forest ecosystems. Adding to the biodiversity are semi-natural habitats such as hay meadows, which are the result of centuries of traditional land management. Like other mountain regions areas, the Carpathian mountain region provides important ecosystem goods and services such as water provision, food products, forest products and tourism. But these ecosystem services are feared to be under threat from climate change.This chapter reports on climate trends, impacts and adaptation options. Analysis of climate trends show an increase in annual mean temperature of 1.1–2.0 °C over the last 50 years (1961–2010), further increasing by 3.5–4.0 °C towards the end of the century. Precipitation changes are dispersed with an increase of 300–400 mm in the north and decrease of 100–150 mm in the south regions. Summer precipitation is projected to reduce by 20 %, whereas winter precipitation is projected to increase in most areas by 5–20 % by the year 2100. Both future scenarios and observations show high spatial variability and uncertainty. The same holds for the impacts on the investigated sectors water resources, forests, wetlands, grasslands, agriculture and tourism.The review of climate trends and adaptation options, inspired a strategic agenda on adaptation to be implemented under the regional Carpathian Convention. Planning for climate change adaptation benefits from transnational cooperation because many impacts relate to seasonal and geographical shifts across borders. This is true for the natural system (e.g. shifts in species distribution and snow cover) as well as for socio-economic activities like agriculture, forestry and tourism (e.g. shifting opportunities for growing crops and changes in the tourist season). Examples of adaptation exist, yet need to be communicated for wider adoption. Essential components of adaptation will be capacity building and information sharing, climate-proofing of infrastructure and investments, promotion of eco-system based adaptation measures and making biodiversity management more dynamic.

Mitigation of carbon dioxide emissions has become an utmost important global agenda, keeping into consideration the associated environmental hardships. As a result, it is important to unearth the factors which can neutralize carbon emissions to transform the world economy into a low-carbon one. Against this backdrop, this study explores the carbon dioxide neutralizing effects of economic growth, international tourism, clean energy promotion, and technological innovation in the context of five European Union (EU-5) nations during the 1990-2015 period. This study's main contribution is in terms of its approach to test the interaction effect between foreign direct investment (FDI) inflows and energy innovation on carbon dioxide emissions. The econometric analysis chronologically involves the employment of unit root, cointegration, causality, and regression methods. Overall, the findings support the inverted-U-shaped economic growth-carbon dioxide emissions nexus to verify the Environmental Kuznets Curve (EKC) hypothesis. Besides, the Pollution Haven Hypothesis in the context of the selected panel is also verified as higher FDI inflows are seen to boost the carbon dioxide emission levels. The results also confirm that energy innovation moderates the harmful effect of air transport (a proxy for international tourism) on carbon dioxide emissions during the developing stage of the tourism industry. On the other hand, renewable energy promotion is found to curb carbon dioxide emissions. These findings suggest that the European governments need to enhance investments in their respective renewable energy sectors and simultaneously ensure the development of clean industries, which can collectively help these nations become carbon-neutral in the future.

One of the most fascinating characteristics of perovskite solar cells (PSCs) is the retrieved obtainment of outstanding photovoltaic (PV) performances withstanding important device configuration variations. Here we have analyzed CH3NH3PbI3-xClx in planar or in mesostructured (MS) configurations, employing both titania and alumina scaffolds, fully infiltrated with perovskite material or presenting an overstanding layer. The use of the MS scaffold induces to the perovskite different structural properties, in terms of grain size, preferential orientation, and unit cell volume, in comparison to the ones of the material grown with no constraints, as we have found out by X-ray diffraction analyses. We have studied the effect of the PSC configuration on photoinduced absorption and time-resolved photoluminescence, complementary techniques that allow studying charge photogeneration and recombination. We have estimated electron diffusion length in the considered configurations observing a decrease when the material is confined in the MS scaffold with respect to a planar architecture. However, the presence of perovskite overlayer allows an overall recovering of long diffusion lengths explaining the record PV performances obtained with a device configuration bearing both the mesostructure and a perovskite overlayer. Our results suggest that performance in devices with perovskite overlayer is mainly ruled by the overlayer, whereas the mesoporous layer influences the contact properties.

With concerns of energy shortages, China, like the United States, European Union, and other countries, is promoting the development of biofuels. However, China also faces high future demand for food and feed, and so its bioenergy program must try to strike a balance between food and fuel. The goals of this paper are to provide an overview of China's current bioethanol program, identify the potential for using marginal lands for feedstock production, and measure the likely impacts of China's bioethanol development on the nation's future food self-sufficiency. Our results indicate that the potential to use marginal land for bioethanol feedstock production is limited. Applying a modeling approach based on highly disaggregated data by region, our analysis shows that the target of 10 million t of bioethanol by 2020 seems to be a prudent target, causing no major disturbances in China's food security. But the expansion of bioethanol may increase environmental pressures due to the higher levels of fertilizer use. This study shows also that if China were able to cultivate 45% of its required bioethanol feedstock on new marginal land, it would further limit negative effects of the bioethanol program on the domestic and international economy, but at the expense of having to apply another 750 thousand t of fertilizer.

Abstract We have analyzed time series of solar data together with the atmospheric and ionospheric measurements for solar cycles 19 till 23 according to particular data availability. For the analyses we have used long term data with 1-day sampling. By mean of Continuous Wavelet Transform (CWT) we have found common spectral domains within solar and atmospheric and ionospheric time series. Further we have identified terms when particular pairs of signals show high coherence applying Wavelet Transform Coherence (WTC). Despite wide oscillation ranges detected in particular time series CWT spectra we found only limited domains with high coherence by mean of WTC. Wavelet Transform Coherence reveals significant high power domains with stable phase difference for periods 1 month, 2 months, 6 months, 1 year, 2 years and 3–4 years between pairs of solar data and atmospheric and ionospheric data. The occurence of the detected domains vary significantly during particular solar cycle (SC) and from cycle to the following one. It indicates the changing solar forcing and/or atmospheric sensitivity with time.

A new series of transparent gel polymer electrolytes are prepared by adding various weight percent of thiourea coupled with poly(ethylene oxide) for the application of dye-sensitized solar cells. Coupling of thiourea in the presence of iodine undergoes dimerization reaction to produce formamidine disulfide. Fourier Transform Infrared spectroscopy shows that the interactions of thiourea and formamidine disulfide with electronegative ether linkage of poly(ethylene oxide) results in conformational changes of gel polymer electrolytes. Electrochemical impedance spectroscopy and linear sweep voltammetry experiments reveal an increment in ionic conductivity and tri-iodide diffusion coefficient, for thiourea modified gel polymer electrolytes. Finally, the prepared electrolytes are used as a redox mediator in dye-sensitized solar cells and the photovoltaic properties were studied. Apart from transparency, the gel polymer electrolytes with thiorurea show higher photovoltaic properties compared to bare gel polymer electrolyte and a maximum photocurrent efficiency of 7.17% is achieved for gel polymer electrolyte containing 1 wt% of thiourea with a short circuit current of 11.79 mA cm-2 and open circuit voltage of 834 mV. Finally, under rear illumination, almost 90% efficiency is retained upon compared to front illumination.