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In the present work the influence of accelerated mineral carbonation on the leaching behaviour of basic oxygen furnace steel slag was investigated. The environmental behaviour of the material as evaluated through the release of major elements and toxic metals under varying pH conditions was the main focus of the study. Geochemical modelling of the eluates was used to derive a theoretical description of the underlying leaching phenomena for the carbonated material as compared to the original slag. Among the investigated elements, Ca and Si were most appreciably affected by carbonation. A very clear effect of carbonation on leaching was observed for silicate phases, and lower-Ca/Si-ratio minerals were found to control leaching in carbonated slag eluates as compared to the corresponding untreated slag sample as a result of Ca depletion from the residual slag particles. Clear evidence was also gained of solubility control for Ca, Mg and Mn by a number of carbonate minerals, indicating a significant involvement of the original slag constituents in the carbonation process. The release of toxic metals (Zn, V, Cr, Mo) was found to be variously affected by carbonation, owing to different mechanisms including pH changes, dissolution/precipitation of carbonates as well as sorption onto reactive mineral surfaces. The leaching test results were used to derive further considerations on the expected metal release levels on the basis of specific assumptions on the relevant pH domains for the untreated and carbonated slag.

Abstract The kinetics of methane hydrate decomposition was studied using a semibatch stirred-tank reactor. The decomposition was accomplished by reducing the pressure on a hydrate slurry in water to a value below the three-phase equilibrium pressure at the reactor temperature. The data were obtained at temperatures from 274 to 283 K and pressures from 0.17 to 6.97 MPa. The stirring rates were high enough to eliminate mass-transfer effects. Analysis of the data indicated that the decomposition rate was proportional to the particle surface area and to the difference in the fugacity of methane at the equilibrium pressure and the decomposition pressure. The proportionality constant showed an Arrhenius temperature dependence. An estimate of the hydrate particle diameters in the experiments permitted the development of an intrinsic model for the kinetics of hydrate decomposition.

The safeguard of power equipments is assuming a major role in the deregulated electricity market, where a malfunctioning power system could be responsible for serious damages to a large number of system operators having access to the shared energy resource. In this context thermal monitoring of power cables represents a key issue in evaluating the risks associated with a given load management policy especially during emergency conditions. In particular this demands for reliable assessment models that should be able to predict the transient thermal behaviour when the load exceeds the nameplate value. In this connection the application of both simplified and detailed power cable thermal models is often complicated by the presence of uncertainties affecting the tolerances of the input data. The effect of these uncertainties could influence the final solution to a considerable extent. A comprehensive tolerance analysis is therefore required in order to incorporate the effect of data uncertainties into the thermal modelling process. To address this problem, in the paper the employment of interval mathematic is proposed. Several numerical results are presented and discussed in order to assess the effectiveness of the proposed methodology which offer a rough qualitative insight of the solution in a very short time, comparable to the time required for a deterministic numerical simulation.

In recent years, the portable technology is receiving a great interest and significant improvement due to the progresses in electronic technology development and energy storage solutions. The decrease in power requirements for working energy systems, due to the increased efficiency and to the reduction in components size, opens the access to new solutions for power supplying. In particular, alternative backup systems for battery charging or replacement could be designed taking advantage of unconventional technologies. It is the case of small photovoltaic portable panels or fuel cells technology: in these solutions different sources are used to produce limited electrical powers required to keep devices on. In this paper, a thermoelectric solution for the power generation has been considered: the generator has been designed and assembled starting from a catalytic combustor. Catalytic combustion allows safe control of the processes, and the choice of a hydrocarbon fuel ensures the power availability and a fast recharge. The size of the system is set to fit a volume close to the one of AA batteries. The electrical power output obtained is close to 1 W with a cold side temperature below 40 °C. The limited values of these physical parameters allow obtaining a portable and safe device. The generator has been fully characterized in different ranges of fuel flow rates and the performances have been thoroughly analysed for processes optimization and efficiency improvement.

The design and assessment of net-zero buildings commonly focus exclusively on the operational phase, ignoring the embodied environmental impacts over the building life cycle. An analysis is presented on the consequences of integrating embodied impacts into the assessment of the environmental advantageousness of net-zero concepts. Fundamental issues needing consideration in the design process - based on the evaluation of primary energy use and related greenhouse gas emissions - are examined by comparing three net-zero building design and assessment cases: (1) no embodied impacts included, net balance limited to the operation stage only; (2) embodied impacts included but evaluated separately from the operation stage; and (3) embodied impacts included with the operation stage in a life cycle approach. A review of recent developments in research, standardization activities and design practice and the presentation of a case study of a residential building in Norway highlight the critical importance of performance indicator definitions and system boundaries. A practical checklist is presented to guide the process of incorporating embodied impacts across the building life cycle phases in net-zero design. Its implications are considered on overall environmental impact assessment of buildings. Research and development challenges, as well as recommendations for designers and other stakeholders, are identified.

The building and construction sector is a large contributor to anthropogenic greenhouse gas emissions and consumes vast natural resources. Improvements in this sector are of fundamental importance for national and global targets to combat climate change. In this context, vertical greenery systems (VGS) in buildings have become popular in urban areas to restore green space in cities and be an adaptation strategy for challenges such as climate change. However, only a small amount of knowledge is available on the different VGS environmental impacts. This paper discusses a comparative life cycle assessment (LCA) between a building with green walls, a building with green facades and a reference building without any greenery system in the continental Mediterranean climate. This life cycle assessment is carried according to ISO 14040/44 using ReCiPe and GWP indicators. Moreover, this study fills this gap by thoroughly tracking and quantifying all impacts in all phases of the building life cycle related to the manufacturing and construction stage, maintenance, use stage (operational energy use experimentally tested), and final disposal. The adopted functional unit is the square meter of the facade. Results showed that the operational stage had the highest impact contributing by up to 90% of the total environmental impacts during its 50 years life cycle. Moreover, when considering VGS, there is an annual reduction of about 1% in the environmental burdens. However, in summer, the reduction is almost 50%. Finally, if the use stage is excluded, the manufacturing and the maintenance stage are the most significant contributors, especially in the green wall system.

The electrodissolution of p-Ge in aqueous NaOH solutions (pH 12-13) has been investigated with steady-state and impedance techniques. In the potential region where the process is under kinetic control, the impedance patterns are characterised by a high frequency capacitive loop, associated with the space charge, largely merged with another due to charge transfer resistance and double layer capacitance, and two low frequency loops changing from inductive to capacitive upon increasing the potential. At larger potential, under mixed control, the same high frequency features are observed, while a convection diffusion impedance dominates the low frequency response. The data relevant to pure kinetic control are interpreted with a simplified kinetic model, based on the classical scheme of Beck and Gerischer [Z. Electrochem., Ber. Bunsenges. Physik. Chem. 63 (1959) 500], neglecting transport effects and assuming only three electrochemical steps: (i) oxidation, involving water molecules, of Ge(0) to dihydroxylated Ge(II) by two holes; (ii) oxidation by one hole of Ge(II)-Ge(III) in a step requiring OH-; (iii) oxidative dissolution of Ge(III) proceeding either by hole capture or electron injection, leaving behind a surface Ge(0) species. Diagrams calculated for the limiting cases of pure depletion layer control reproduce the essential features of the experimental ones.

Artículos en revistas Liberalization policies, the challenges of integrating distributed generation resources, and the recent flattening of electricity demand due to the economic crisis and technological change have led to lower returns for European electricity suppliers. Innovative and sustainable business models are needed to serve electricity customers while reflecting the operational needs of the system and maintaining supplier financial viability. This paper describes a novel model of Integrated Energy Services that encompasses distributed generation (DG) and demand response (DR) resources for industrial customers. We further reflect on some of the market opportunities and regulatory drivers for the development of similar schemes across Europe. info:eu-repo/semantics/publishedVersion