• Energy Research
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Production of biodiesel from yellow grease (waste cooking oil and waste animal fats) is fast emerging as a promising alternative to address the twin challenges before the biodiesel industry today-fluctuation in prices of vegetable oil and the food versus fuel debate. Yellow grease has a high percentage of free fatty acids (FFA) and proves to be an unsuitable feedstock for biodiesel production from commercially viable alkali-catalyzed production systems due to saponification problems.“Green” methodologies based on heterogeneous solid acid catalyzed reactions have the potential to simultaneously promote esterification and transesterification reactions of yellow grease to produce biodiesel without soap formation and offer easy catalyst separation without generation of toxic streams. This paper presents kinetic studies for the conversion of model yellow grease feeds to biodiesel using a heteropolyacid supported on alumina (HSiW/Al2O3) using a batch autoclave. Three model yellow grease feeds were prepared using canola oil with added FFA such as palmitic, oleic and linoleic acid. A pseudo homogeneous kinetic model for the parallel esterification and transesterification was developed. The rate constants and activation parameters for esterification and transesterification reactions for the model yellow grease feeds were determined. The rate constants for esterification are higher than the transesterification rate constants. The kinetic model was validated using the experimental biodiesel data obtained from processing a commercial yellow grease feed. The kinetic model could be used to design novel processes to convert various low-value waste oils, fats and non-food grade oils to sustainable biodiesel. Keywords: Yellow grease, Canola oil, Free fatty acids, Heteropolyacid, Kinetics for esterification and transesterification

Upwelling processes bring nutrient-rich waters from the deep ocean to the surface. Areas of upwelling are often associated with high productivity, offering great economic value in terms of fisheries. The sensitivity of spring/summer-time coastal upwelling systems to climate change has recently received a lot of attention. Several studies have suggested that their intensity may increase in the future while other authors have shown decreasing intensity in their equatorward portions. Yet, recent observations do not show robust evidence of this intensification. The Senegalo-Mauritanian upwelling system (SMUS) located at the southern edge of the north Atlantic system (12°N–20°N) and most active in winter/spring has been largely excluded from these studies. Here, the seasonal cycle of the SMUS and its response to climate change is investigated in the database of the Coupled Models Inter comparison Project Phase 5 (CMIP5). Upwelling magnitude and surface signature are characterized by several sea surface temperature and wind stress indices. We highlight the ability of the climate models to reproduce the system, as well as their biases. The simulations suggest that the intensity of the SMUS winter/spring upwelling will moderately decrease in the future, primarily because of a reduction of the wind forcing linked to a northward shift of Azores anticyclone and a more regional modulation of the low pressures found over Northwest Africa. The implications of such an upwelling reduction on the ecosystems and local communities exploiting them remains very uncertain.

Abstract This paper investigates the optimal choice of building energy efficiency (BEE) standard in the context of centralised urban district heating system in northern China. By employing a techno-economic analysis approach, we demonstrate that the current BEE standard implemented in the Chinese cities should be tightened further in order to achieve a socially optimal level. Without considering the externality costs associated with carbon dioxide (CO2) emissions, current BEE standards need to be upgraded to the equivalent level of French RT2005 standard coupled with a properly designed district coal-fired Combined Heat and Power (CHP). In contrast, the equivalent efficiency standard of Swedish building code is preferably to be implemented in the case of explicit carbon emission restriction as long as the marginal cost of carbon emission (carbon price) is sufficiently high. The fuel-switching policy (from coal to natural gas) in the urban district heating system would result in significant increase in overall costs if the BEE upgrade is not taken into account simultaneously. It is also found that BEE improvements in northern Chinese cities are more cost-effective than investing in low-carbon technologies such as wind power or Carbon Capture and storage in the EU and US with regard to CO2 emissions mitigation.

AbstractThe presented synthesis of the title compounds (II), (IV), (VI) and (VIII) is extremely simple and highly efficient without the use of any chromatographic purification.

This paper presents an experimental study of indoor thermal environment near a full-scale glass facade with different types of shading devices under varying climatic conditions in winter. Interior glazing and shading temperature, operative temperature and radiant temperature asymmetry were measured for facade sections with roller shades and venetian blinds at different positions. Interior glass surface temperatures can be high during sunny days with low outdoor temperature. Shading systems significantly improved operative temperature and radiant temperature asymmetry during cold sunny days, depending on their properties and tilt angle. During cloudy days the impact was smaller, however the shading layers could still decrease the amount of heat loss through the facade. A transient building thermal model, which also calculates indoor environmental indices under the presence of solar radiation, was developed and compared with the experimental measurements. Part II of this paper uses this validated model with a transient, two-node thermal comfort model (including transmitted solar radiation) for assessment of indoor environmental conditions with different building envelope and shading properties, facade location and orientation.

Abstract Recharging infrastructure (RI) deployment plays a vital role in improving the public recharging availability for transport electrification. Decarbonizing transportation using low-emission electricity requires massive RI network. Even though the consumers are reluctant to purchase electric vehicles (EVs) until RIs are sufficiently placed, the investors are not willing to invest in RIs due to recharging demand uncertainties. Therefore, a scientific planning framework is needed to ensure the sustainable deployment of EV-RIs in complex networks. In this study, a lifecycle thinking-based multi-period infrastructure-planning framework is proposed to develop sustainable public EV-RIs in an urban context. This framework consists of a temporal model to find the dynamic EV-RI demands, a stochastic model to obtain travel distances, and a multi-objective optimization model to select the best desirable capacities and locations for potential EV-RIs. A case study of a typical medium-scale municipality in Canada was assessed using the proposed framework and validated using conventional infrastructure planning scenarios. The geo-processing data, regional travel behaviors, and recharging characteristics were used as model inputs. The results of the case study showed that the proposed framework can be used to estimate multi-period public recharging demands, minimize lifecycle costs, maximize service coverage and infrastructure utilization, and ensure reasonable paybacks compared to conventional planning approaches. Moreover, this framework can be used to compare different investment assistances, which are required in the early stages of the RI deployment process to encourage investors. Furthermore, government and private institutions can use this framework to identify recharging demands, permitting, and developing RIs in the long-run.

Abstract The residential sector accounts for most of energy-consumption in developing countries in the form of traditional energy. The use of commercial energy is nominal and confined mostly to urban areas where fuelwood is already monetized. A model, based on an end-use/process analysis approach, is developed on a spreadsheet, which is capable of simulating scenarios to address issues of increasing traditional energy-demand caused by population growth, sustainable supply capacity of the existing energy resources, potential for development of new and renewable energy resources, technology. This paper is divided into two parts: general energy issues and the modelling approach, and the application of this approach to Nepal in the context of fuelwood-supply sustainability.

An analysis of streamflow characteristics (i.e. mean annual and seasonal flows and extreme high and low flows) in current and future climates for 21 watersheds of north-east Canada covering mainly the province of Quebec is presented in this article. For the analysis, streamflows are derived from a 10-member ensemble of Canadian Regional Climate Model (CRCM) simulations, driven by the Canadian Global Climate Model simulations, of which five correspond to current 1970–1999 period, while the other five correspond to future 2041–2070 period. For developing projected changes of streamflow characteristics from current to future periods, two different approaches are used: one based on the concept of ensemble averaging while the other approach is based on merged samples of current and similarly future simulations following multiple comparison tests. Verification of the CRCM simulated streamflow characteristics for the 1970–1999 period suggests that the model simulated mean hydrographs and high flow characteristics compare well with those observed, while the model tends to underestimate low flow extremes. Results of projected changes to mean annual streamflow suggest statistically significant increases nearly all over the study domain, while those for seasonal streamflow show increases/decreases depending on the season. Two- and 5-year return levels of 15-day low flows are projected to increase significantly over most part of the study domain, though the changes are small in absolute terms. Based on the ensemble averaging approach, changes to 10- and 30-year return levels of high flows are not generally found significant. However, when a similar analysis is performed using longer samples, significant increases to high flow return levels are found mainly for northernmost watersheds. This study highlights the need for longer samples, particularly for extreme events in the development of robust projections.