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Abstract The kinetics of methane hydrate decomposition was studied using a semibatch stirred-tank reactor. The decomposition was accomplished by reducing the pressure on a hydrate slurry in water to a value below the three-phase equilibrium pressure at the reactor temperature. The data were obtained at temperatures from 274 to 283 K and pressures from 0.17 to 6.97 MPa. The stirring rates were high enough to eliminate mass-transfer effects. Analysis of the data indicated that the decomposition rate was proportional to the particle surface area and to the difference in the fugacity of methane at the equilibrium pressure and the decomposition pressure. The proportionality constant showed an Arrhenius temperature dependence. An estimate of the hydrate particle diameters in the experiments permitted the development of an intrinsic model for the kinetics of hydrate decomposition.

Abstract Thermal energy storage (TES) systems are growing to a relevant role in solar cooling applications. Hence, high energy density is a desirable property of the TES system. Phase change materials (PCM) helps to increase this characteristic. A high temperature pilot plant able to test different types of TES systems and materials was designed and built at the University of Lleida (Spain). This pilot plant is composed mainly of three parts: heating system, cooling system, and different storage tanks. Two identical storage tanks based on the shell-and-tubes heat exchanger, one of them including 196 squared fins in the bundle of the tubes and the other without, were experimentally tested. Hydroquinone was selected as the storage material, having a latent heat of 205 kJ/kg and a phase change temperature between 168 and 173 °C. The aim of this paper is to test experimentally, and compare the average effectiveness of the TES systems analyzed using PCM for solar cooling and refrigeration applications. It was found out that for the same tank configurations (shell-and-tubes) even changing drastically the dimensions of the tank or the number and the diameter of the tubes, the average effectiveness curve proposed in the literature fits well with the results showed here.

The design and assessment of net-zero buildings commonly focus exclusively on the operational phase, ignoring the embodied environmental impacts over the building life cycle. An analysis is presented on the consequences of integrating embodied impacts into the assessment of the environmental advantageousness of net-zero concepts. Fundamental issues needing consideration in the design process - based on the evaluation of primary energy use and related greenhouse gas emissions - are examined by comparing three net-zero building design and assessment cases: (1) no embodied impacts included, net balance limited to the operation stage only; (2) embodied impacts included but evaluated separately from the operation stage; and (3) embodied impacts included with the operation stage in a life cycle approach. A review of recent developments in research, standardization activities and design practice and the presentation of a case study of a residential building in Norway highlight the critical importance of performance indicator definitions and system boundaries. A practical checklist is presented to guide the process of incorporating embodied impacts across the building life cycle phases in net-zero design. Its implications are considered on overall environmental impact assessment of buildings. Research and development challenges, as well as recommendations for designers and other stakeholders, are identified.

It is well known that the efficiency of PV modules decreases with increasing module temperatures. Many studies have paid attention to the development and validation of heuristic models to calculate the PV module temperature in higher latitudes, however only a few focus on the thermal behaviour of PV modules in tropical regions of the world, where constantly high temperatures prevail. Also, little is known about the effect of including wind speed in these thermal models. This study evaluates three of such models - one that excludes wind, and two others including the wind influence - using hourly data for two tropical locations. Results show that the average hourly wind speeds in Singapore and Jayapura (Indonesia) are low and therefore the influence of the wind on the PV module temperature is minor. The three evaluated models produce about the same results with RMSE between 1.5-3.8 °C during daytime, which corresponds to a deviation in power output in the range of 0.3-1.6 %, depending on the PV module technology.

<div class="section abstract"><div class="htmlview paragraph">The introduction of new light-duty vehicle emission limits to comply under real driving conditions (RDE) is pushing the diesel engine manufacturers to identify and improve the technologies and strategies for further emission reduction. The latest technology advancements on the after-treatment systems have permitted to achieve very low emission conformity factors over the RDE, and therefore, the biggest challenge of the diesel engine development is maintaining its competitiveness in the trade-off “CO₂-system cost” in comparison to other propulsion systems. In this regard, diesel engines can continue to play an important role, in the short-medium term, to enable cost-effective compliance of CO₂-fleet emission targets, either in conventional or hybrid propulsion systems configuration. This is especially true for large-size cars, SUVs and light commercial vehicles.</div><div class="htmlview paragraph">In this framework, a comprehensive approach covering the whole powertrain is of primary importance in order to simultaneously meet the performance, efficiency, noise and emission targets, and therefore, further development of the combustion system design and injection system represent important levers for additional improvements. For this purpose, a dedicated 0.5 dm³ single-cylinder engine has been developed and equipped with, a state-of-the-art Euro 6 combustion system, and an advanced common rail fuel injection system (FIS) offering higher flexibility in terms of injection strategy and higher quantity accuracy. Three injector nozzles with different hydraulic flow rates (HF) have been selected and employed for the overall combustion process optimization.</div><div class="htmlview paragraph">The optimization has been performed by means of an extensive DoE-based test campaign in which the engine and FIS operating parameters have been parametrized with the aim to carry out a proper combination in terms of HF and injection strategy. The results at partial load conditions evidence significant advantages in applying an advanced injection pattern, while the HF reduction can significantly improve the smoke emission and combustion noise without fuel consumption penalties. Therefore, a proper combination and optimization of the HF and injection strategy can provide low noise and engine-out smoke while maintaining the rated power performance targets.</div></div>

AbstractThe surface oxygen exchange on oxides with high oxygen ion mobility is modelled with a two step reaction with adsorbed mono-atomic oxygen species as intermediate. Interpretation of the Po2 dependence of the exchange rates, following from this model, indicates that these adsorbed oxygen atoms are singly charged.For the stabilized δ-Bi2O3 solid electrolyte a good agreement has been found between the isotope exchange model and the electrochemical study of the oxygen exchange using gold electrodes. For the mixed La-Sr cobaltite perovskite a change in the surface exchange reaction is observed going from room temperature to 600°C. Indications are that above 450°C the bulk exchange is rate limiting with a (Po2)−1 dependence while below this temperature it is assumed that the dissociative adsorption is rate limiting with a (Po2)1/2 dependence.

Artículos en revistas Numerical models of transmission-constrained electricity markets are used to inform regulatory decisions. How robust are their results? Three research groups used the same data set for the northwest Europe power market as input for their models. Under competitive conditions, the results coincide, but in the Cournot case, the predicted prices differed significantly. The Cournot equilibria are highly sensitive to assumptions about market design (whether timing of generation and transmission decisions is sequential or integrated) and expectations of generators regarding how their decisions affect transmission prices and fringe generation. These sensitivities are qualitatively similar to those predicted by a simple two-node model. info:eu-repo/semantics/publishedVersion