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Production of biodiesel from yellow grease (waste cooking oil and waste animal fats) is fast emerging as a promising alternative to address the twin challenges before the biodiesel industry today-fluctuation in prices of vegetable oil and the food versus fuel debate. Yellow grease has a high percentage of free fatty acids (FFA) and proves to be an unsuitable feedstock for biodiesel production from commercially viable alkali-catalyzed production systems due to saponification problems.“Green” methodologies based on heterogeneous solid acid catalyzed reactions have the potential to simultaneously promote esterification and transesterification reactions of yellow grease to produce biodiesel without soap formation and offer easy catalyst separation without generation of toxic streams. This paper presents kinetic studies for the conversion of model yellow grease feeds to biodiesel using a heteropolyacid supported on alumina (HSiW/Al2O3) using a batch autoclave. Three model yellow grease feeds were prepared using canola oil with added FFA such as palmitic, oleic and linoleic acid. A pseudo homogeneous kinetic model for the parallel esterification and transesterification was developed. The rate constants and activation parameters for esterification and transesterification reactions for the model yellow grease feeds were determined. The rate constants for esterification are higher than the transesterification rate constants. The kinetic model was validated using the experimental biodiesel data obtained from processing a commercial yellow grease feed. The kinetic model could be used to design novel processes to convert various low-value waste oils, fats and non-food grade oils to sustainable biodiesel. Keywords: Yellow grease, Canola oil, Free fatty acids, Heteropolyacid, Kinetics for esterification and transesterification

Abstract In this study, crude cellulose derived from cornstalk, after bleaching, was used as raw material for the synthesis of sodium carboxymethyl cellulose (CMC) by reacting with the cellulose with NaOH and chloroacetic acid at 75 °C for 1.5 h. Effects of alkali dosage, concentration of chloroacetic acid on the physical and chemical properties of the CMC products were investigated. It was revealed that the reactants alkali reagent/chloroacetic acid/cellulose at the molar ratio of 4.6:2.8:1and 4:2.5:1, or at the molar ratio of NaOH/ClCH 2 COOH ≈1.6–1.64, resulted in CMC products of relatively high water solubility. The viscosity-average molecular weight M v of these two CMC products obtained at molar ratios of 4.0:2.5:1 and 4.6:2.8:1 is in the range of 1.94 × 10 4 –2.48 × 10 4 g mol −1 , and the average DS of the two products are 0.57 and 0.85, respectively. As the solute concentration is above 2 wt%, the viscosity of the CMC-water solution exhibits nonlinear (exponential) increasing with increasing the solute concentration (typical of non-Newton fluids).

It is crucial to reduce the energy penalties related to CO2 capture processes if CCS is to be implemented at industrial scale. In this context, gas-solid sorption has become a relevant technology. The absence of large amounts of water when using dry solid sorbents and their high heat capacity reduce the energy requirements in the gas-solid sorption CO2 capture process. Depending on the sorbent composition, the gas-solid sorption process carries out at high or low temperatures. High temperature sorbents allow the utilization of waste energy while energy requirements in low temperature processes will be less demanding. This study is focused on the assessment and comparison of the final energy penalty of low-temperature (amine impregnated alumina-based solid particles) and high-temperature solid sorbents capture process (calcium oxide).

A major achievement in research supported by the Kluane Lake Research Station was the recovery, in 2001 – 02, of a suite of cores from the icefields of the central St. Elias Mountains, Yukon, by teams of researchers from Canada, the United States, and Japan. This project led to the development of parallel, long (103 – 104 year) ice-core records of climate and atmospheric change over an altitudinal range of more than 2 km, from the Eclipse Icefield (3017 m) to the ice-covered plateau of Mt. Logan (5340 m). These efforts built on earlier work recovering single ice cores in this region. Comparison of these records has allowed for variations in climate and atmospheric composition to be linked with changes in the vertical structure and dynamics of the North Pacific atmosphere, providing a unique perspective on these changes over the Holocene. Owing to their privileged location, cores from the St. Elias Icefields also contain a remarkably detailed record of aerosols from various sources around or across the North Pacific. In this paper we review major scientific findings from the study of St. Elias Mountain ice cores, focusing on five main themes: (1) The record of stable water isotopes (δ18O, δD), which has unique characteristics that differ from those of Greenland, other Arctic ice cores, and even among sites in the St. Elias; (2) the snow accumulation history; (3) the record of pollen, biomass burning aerosol, and desert dust deposition; (4) the record of long-range air pollutant deposition (sulphate and lead); and (5) the record of paleo-volcanism. Our discussion draws on studies published since 2000, but based on older ice cores from the St. Elias Mountains obtained in 1980 and 1996.

Model projections show that production of high-value products from microalgae could be profitable nowadays and commodities will become profitable within 10 years.

The benefits of aluminum lamination in improving the physical and mechanical properties of wood-based composites is now well documented. This paper shows the contribution of life cycle assessment (LCA) as a tool to assess and compare the environmental footprint in the development of laminated panels. SimaPro 9.0 software, using Ecoinvent database was used to analyze the environmental impacts associated with the manufacturing of wood aluminum-laminated (WAL) panels and aluminum honeycomb panel (AHP). The impact 2002+ method was used to estimate environmental impacts. The LCA results show that the WAL panels manufacturing had a lower environmental impact than AHP manufacturing. In term of product, wood-based composites were the best choice as a core in laminated panel manufacturing. Wood-based composite manufacturing showed environmental advantages in all damage categories except in ecosystem quality. Aluminum alloy sheets manufacturing played an important role in the generation of environmental impacts for laminated panel development.