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Comprehensive and reliable information on anthropogenic sources of greenhouse gas emissions is required to track progress towards keeping warming well below 2°C as agreed upon in the Paris Agreement. Here we provide a dataset on anthropogenic GHG emissions 1970-2019 with a broad country and sector coverage. We build the dataset from recent releases from the “Emissions Database for Global Atmospheric Research” (EDGAR) for CO2 emissions from fossil fuel combustion and industry (FFI), CH4 emissions, N2O emissions, and fluorinated gases and use a well-established fast-track method to extend this dataset from 2018 to 2019. We complement this with information on net CO2 emissions from land use, land-use change and forestry (LULUCF) from three available bookkeeping models.

Production of biodiesel from yellow grease (waste cooking oil and waste animal fats) is fast emerging as a promising alternative to address the twin challenges before the biodiesel industry today-fluctuation in prices of vegetable oil and the food versus fuel debate. Yellow grease has a high percentage of free fatty acids (FFA) and proves to be an unsuitable feedstock for biodiesel production from commercially viable alkali-catalyzed production systems due to saponification problems.“Green” methodologies based on heterogeneous solid acid catalyzed reactions have the potential to simultaneously promote esterification and transesterification reactions of yellow grease to produce biodiesel without soap formation and offer easy catalyst separation without generation of toxic streams. This paper presents kinetic studies for the conversion of model yellow grease feeds to biodiesel using a heteropolyacid supported on alumina (HSiW/Al2O3) using a batch autoclave. Three model yellow grease feeds were prepared using canola oil with added FFA such as palmitic, oleic and linoleic acid. A pseudo homogeneous kinetic model for the parallel esterification and transesterification was developed. The rate constants and activation parameters for esterification and transesterification reactions for the model yellow grease feeds were determined. The rate constants for esterification are higher than the transesterification rate constants. The kinetic model was validated using the experimental biodiesel data obtained from processing a commercial yellow grease feed. The kinetic model could be used to design novel processes to convert various low-value waste oils, fats and non-food grade oils to sustainable biodiesel. Keywords: Yellow grease, Canola oil, Free fatty acids, Heteropolyacid, Kinetics for esterification and transesterification

The benefits of aluminum lamination in improving the physical and mechanical properties of wood-based composites is now well documented. This paper shows the contribution of life cycle assessment (LCA) as a tool to assess and compare the environmental footprint in the development of laminated panels. SimaPro 9.0 software, using Ecoinvent database was used to analyze the environmental impacts associated with the manufacturing of wood aluminum-laminated (WAL) panels and aluminum honeycomb panel (AHP). The impact 2002+ method was used to estimate environmental impacts. The LCA results show that the WAL panels manufacturing had a lower environmental impact than AHP manufacturing. In term of product, wood-based composites were the best choice as a core in laminated panel manufacturing. Wood-based composite manufacturing showed environmental advantages in all damage categories except in ecosystem quality. Aluminum alloy sheets manufacturing played an important role in the generation of environmental impacts for laminated panel development.

Abstract. Reliable quantification of the sources and sinks of greenhouse gases, together with trends and uncertainties, is essential to monitoring the progress in mitigating anthropogenic emissions under the Paris Agreement. This study provides a consolidated synthesis of CH4 and N2O emissions with consistently derived state-of-the-art bottom-up (BU) and top-down (TD) data sources for the European Union and UK (EU27+UK). We integrate recent emission inventory data, ecosystem process-based model results, and inverse modelling estimates over the period 1990–2018. BU and TD products are compared with European National GHG Inventories (NGHGI) reported to the UN climate convention secretariat UNFCCC in 2019. For uncertainties, we used for NGHGI the standard deviation obtained by varying parameters of inventory calculations, reported by the Member States following the IPCC guidelines recommendations. For atmospheric inversion models (TD) or other inventory datasets (BU), we defined uncertainties from the spread between different model estimates or model specific uncertainties when reported. In comparing NGHGI with other approaches, a key source of bias is the activities included, e.g. anthropogenic versus anthropogenic plus natural fluxes. In inversions, the separation between anthropogenic and natural emissions is sensitive to the geospatial prior distribution of emissions. Over the 2011–2015 period, which is the common denominator of data availability between all sources, the anthropogenic BU approaches are directly comparable, reporting mean emissions of 20.8 Tg CH4 yr−1 (EDGAR v5.0) and 19.0 Tg CH4 yr−1 (GAINS), consistent with the NGHGI estimates of 18.9 ± 1.7 Tg CH4 yr−1. TD total inversions estimates give higher emission estimates, as they also include natural emissions. Over the same period regional TD inversions with higher resolution atmospheric transport models give a mean emission of 28.8 Tg CH4 yr−1. Coarser resolution global TD inversions are consistent with regional TD inversions, for global inversions with GOSAT satellite data (23.3 Tg CH4yr−1) and surface network (24.4 Tg CH4 yr−1). The magnitude of natural peatland emissions from the JSBACH-HIMMELI model, natural rivers and lakes emissions and geological sources together account for the gap between NGHGI and inversions and account for 5.2 Tg CH4 yr−1. For N2O emissions, over the 2011–2015 period, both BU approaches (EDGAR v5.0 and GAINS) give a mean value of anthropogenic emissions of 0.8 and 0.9 Tg N2O yr−1 respectively, agreeing with the NGHGI data (0.9 ± 0.6 Tg N2O yr−1). Over the same period, the average of the three total TD global and regional inversions was 1.3 ± 0.4 and 1.3 ± 0.1 Tg N2O yr−1 respectively, compared to 0.9 Tg N2O yr−1 from the BU data. The TU and BU comparison method defined in this study can be operationalized for future yearly updates for the calculation of CH4 and N2O budgets both at EU+UK scale and at national scale. The referenced datasets related to figures are visualized at https://doi.org/10.5281/zenodo.4288969 (Petrescu et al., 2020).

Abstract This work aims to predict the general performances of a pilot parabolic trough collector during transient periods. To do so, a one-dimensional thermal model has been developed. It has been validated with experimental results from two different experimental setups, in steady-state conditions, with a transmitted power maximum error of 3.4%. Since the model only predicts the collector's thermal behavior, the parabolic trough collector has been first optically qualified. Then, optical efficiencies were used as input for the model. Experimental results were obtained in steady-state conditions and compared to the model. Then, experimental and numerical results were compared during two period of time with varying inlet conditions (i.e. dynamic condition tests): the first one with stable conditions, and the other one with harsh conditions. The developed model showed a good capability of predicting the thermal behavior of the parabolic trough collector with unstable environment (DNI, mass flow, inlet temperature), with a 9.6% relative standard error in the worst case. As a conclusion, while previous studies only focused on steady-state conditions, it has been showed that this kind of model can be used to precisely predict the dynamic behavior of large power plants.

Abstract This paper investigates the optimal choice of building energy efficiency (BEE) standard in the context of centralised urban district heating system in northern China. By employing a techno-economic analysis approach, we demonstrate that the current BEE standard implemented in the Chinese cities should be tightened further in order to achieve a socially optimal level. Without considering the externality costs associated with carbon dioxide (CO2) emissions, current BEE standards need to be upgraded to the equivalent level of French RT2005 standard coupled with a properly designed district coal-fired Combined Heat and Power (CHP). In contrast, the equivalent efficiency standard of Swedish building code is preferably to be implemented in the case of explicit carbon emission restriction as long as the marginal cost of carbon emission (carbon price) is sufficiently high. The fuel-switching policy (from coal to natural gas) in the urban district heating system would result in significant increase in overall costs if the BEE upgrade is not taken into account simultaneously. It is also found that BEE improvements in northern Chinese cities are more cost-effective than investing in low-carbon technologies such as wind power or Carbon Capture and storage in the EU and US with regard to CO2 emissions mitigation.

Abstract Thermal performance of three naturally ventilated public buildings in which the wind tower is an important architectural freature is studied. One of the three builidings as well as it's wind tower is instrumented for temperature, relative humidity and airflow velocity measurements, and the other two are instrumented for temperature measurement. The results have led to a discussion concerning the degree of wind tower effectiveness in achieving thermal comfort.

Abstract Building-based active envelopes play an important role to reduce active heating supplies. Several techniques are developed to enhance the energy performances of active building envelopes; meanwhile, numerous numerical and mathematical models are also developed to conduct the performance analysis of these techniques. In this paper, we propose a state-space model for solar active wall-based Phase Change Materials (PCM). The advantage of this method remains in its simplicity to provide details of internal nodes and input/output parameters. The low-cost calculation is a supplementary advantage versus a heavy numerical method. The proposed numerical model is applied for a multi-layer wall with PCM Wallboards (PCMW) embedded between indoor and outdoor environments. The results show the ability of the state-space model to estimate the thermal behavior of the system, as well as the thermal characteristics of embedding PCM in the internal face of the wall. It significantly contributes to stabilize the indoor temperature and to ensure the thermal comfort.