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Abstract Geological sequestration of CO 2 is an immediately available and technologically feasible means of reducing CO 2 emissions into the atmosphere, which is particularly suited to landlocked sedimentary basins. Geoscience, engineering, economic and public issues need addressing by governments and industry before proceeding with full scale implementation. Specific site selection should be based on a suitability analysis, a proper inventory of potential sites, an assessment of the fate of the injected CO 2 and a capacity determination, together with surface criteria such as CO 2 capture and transport. The suitability analysis, both at the basin and regional scales, is based on geological, geothermal, hydrodynamic, basin maturity, economic and societal criteria. The inventory of sequestration sites needs also identification of major CO 2 point sources and a cost benefit analysis. The potential for CO 2 escape and migration is a deciding factor in screening out unsafe sites. Site capacity should be determined based on in situ conditions and CO 2 properties and behavior. Transforming the geological space into the CO 2 space is an important step along the road map for selection of suitable CO 2 injection sites that allows the identification of safe large capacity sites. An example of application from the Alberta basin is presented.

In our continued efforts in the synthesis of ruthenium(II) polypyridine complexes as potential dyes for use in varied applications, such as the dye-sensitized solar cells (DSSCs), this work particularly describes the synthesis, absorption spectrum, redox behavior and luminescence properties of a new homoleptic ruthenium(II) complex bearing a simple trans-2-methyl-2-butenoic acid functionality as the anchoring ligand on terpyridine moiety. The functionalized terpyridine ligand: 4’-(trans-2-methyl-2-butenoic acid)-terpyridyl (L1) was synthesized by aryl bromide substitution on terpyridine in a basic reaction condition under palladium carbide catalysis. In particular, the photophysical and redox properties of the complex formulated as: bis-4’-(trans-2-methyl-2-butenoic acid)-terpyridyl ruthenium(II) bis-hexafluorophosphate [Ru(L1)2(PF6)2] are significantly better compared to those of [Ru(tpy)2]2+ and compare well with those of the best emitters of Ru(II) polypyridine family containing tridentate ligands. Reasons for the improved photophysical and redox properties of the complex may be attributed partly to the presence of a substituted α,β-unsaturated carboxylic acid moiety leading to increase in the length of π-conjugation bond thereby enhancing the MLCT-MC (Metal-to-ligand-charge transfer-metal centred) energy gap, and to the reduced difference between the minima of the excited and ground states potential energy surfaces.

Abstract Building energy prediction is a key factor to assess the energy performance of commercial buildings, identify operation issues and propose better operating strategies based on the forecast information. Different models have been used to forecast energy demand in buildings, including whole building energy simulation, regression analysis, and black-box models (e.g., artificial neural networks). This paper presents a different approach to predict the energy demand of commercial buildings using case-based reasoning (CBR). The proposed approach is evaluated using monitored data in a real office building located in Varennes, Quebec. The energy demand is predicted at every hour for the following 3 h using weather forecasts. The results show that during occupancy, 7:00–18:00, the coefficient of variance of the root-mean-square-error (CV-RMSE) is below 13.2%, the normalized mean bias error (NMBE) is below 5.8% and the root-mean-square-error (RMSE) is below 14 kW. When the statistical criteria are calculated for all hours of the day, the CV-RMSE is 12.1%, the NMBE is 1.0% and the RMSE is 11 kW. The case study demonstrates that CBR can be used for energy demand prediction and could be implemented in building operation systems.

Carbon capture, utilization, and storage (CCUS) is a gas injection technology that enables the storage of CO2 underground. The aims are twofold, on one hand to reduce the emissions of CO2 into the atmosphere and on the other hand to increase oil/gas/heat recovery. Different types of CCUS technologies and related engineering projects have a long history of research and operation in the USA. However, in China they have a short development period ca. 10 years. Unlike CO2 capture and CO2-EOR technologies that are already operating on a commercial scale in China, research into other CCUS technologies is still in its infancy or at the pilot-scale. This paper first reviews the status and development of the different types of CCUS technologies and related engineering projects worldwide. Then it focuses on their developments in China in the last decade. The main research projects, international cooperation, and pilot-scale engineering projects in China are summarized and compared. Finally, the paper examines the challenges and prospects to be experienced through the industrialization of CCUS engineering projects in China. It can be concluded that the CCUS technologies have still large potential in China. It can only be unlocked by overcoming the technical and social challenges.

Abstract Eradicating poverty and mitigating greenhouse gas (GHG) emissions are core issues of global sustainable development goals (SDGs), and China is struggling in realizing these targets. The poverty reduction that leads to popualtion structure and lifestyle changes would have an impact on GHG emission changes. However, few studies have assessed the historical and future impacts of the poverty allevation on China's emissions. Here by linking Chinese Multi-Regional Input Output (MRIO) database to the global MRIO database EXIOBASE, and using provincial household consumption data, we identified the distribution of Chinese household greenhouse gas footprints (HGFs) by income groups in 2015 at the national and provinical levels. Moreover, we focused on the historical impact of poverty alleviation on HGFs during 2010–2015, and developed four scenarios to project future HGFs changes due to poverty alleviation by 2030. We find that eradicating extreme poverty in the secanrio S2, i.e., bringing people to an income above $1.9 daily, does not cause a large emission impact with current technological level. However, lifting people from a higher poverty line of $5.5 per day in the sceanrio S4 results in a 1.6% increase in emissions compared with the scenario S1 without any poverty reduction goals. Furthermore, realizing a higher poverty reduction target will result in an increase of emissions contribution from internatioanl supply chains due to the differences in consumption patterns among different income groups. Our study highlights the conflict between the high poverty alleviaition goal and emission reduciton in China, and reminds us of the need to make more technological efforts for avoiding the large emissions embodied in international supply chains.

Abstract The kinetics of methane hydrate decomposition was studied using a semibatch stirred-tank reactor. The decomposition was accomplished by reducing the pressure on a hydrate slurry in water to a value below the three-phase equilibrium pressure at the reactor temperature. The data were obtained at temperatures from 274 to 283 K and pressures from 0.17 to 6.97 MPa. The stirring rates were high enough to eliminate mass-transfer effects. Analysis of the data indicated that the decomposition rate was proportional to the particle surface area and to the difference in the fugacity of methane at the equilibrium pressure and the decomposition pressure. The proportionality constant showed an Arrhenius temperature dependence. An estimate of the hydrate particle diameters in the experiments permitted the development of an intrinsic model for the kinetics of hydrate decomposition.

Abstract Hybrid TiO2/SiO2 thin films deposited by material printing technique on flexible substrates were prepared, characterized and tested for solar photocatalytic disinfection. Effect of surface hydrophilicity/hydrophobicity of printed coatings on photocatalytic disinfection was studied by means of (i) drinking water contaminated with natural consortia of fecal bacteria (gram-negative: Escherichia coli and total coliforms; gram-positive: Enterococci), and (ii) seawater containing pathogenic gram-negative bacteria (Vibrio owensii, Vibrio alfacsensis and Vibrio harveyi). Inactivation of gram-negative bacteria in drinking water with fecal contamination by solar photocatalysis was slightly more efficient than solar disinfection, while for gram-positive bacteria similar efficiency was observed. These results, in combination with observed release of titanium from coatings (detected by means of inductively coupled plasma atomic emission spectrometer), indicate that TiO2/SiO2 needs further improvements for solar photocatalytic disinfection of drinking water. Efficiency of seawater disinfection towards gram-negative Vibrio spp. (Vibrio owensii, Vibrio alfacsensis and Vibrio harveyi) was significantly enhanced when TiO2/SiO2 coatings were used under natural solar light. Moreover, hydrophobic thin films led to faster Vibrio spp. inactivation as compared to hydrophilic ones, which was attributed to higher bacteria adhesion on hydrophobic coatings. However, decrease of photocatalytic activity of hydrophobic TiO2/SiO2 coatings was observed after ten experimental cycles mainly due to deposition of salts on the surface of photocatalyst. Generally, results of this study suggest that autochthonous bacteria such as Vibrio spp. in seawater are significantly more resistant to solar disinfection in comparison with not autochthonous bacteria such as Escherichia coli, total coliforms and Enterococci in contaminated drinking water.

This paper describes anaerobic thermophilic sludge digestion (55 °C) in a continuously stirred tank reactor (CSTR) on a pilot-plant scale (150 L). The experimental protocol was defined to examine the effect of the increase in the organic loading rate on the efficiency of the digester and to report on its steady-state performance. The reactor was subjected to a programme of steady-state operation over a range of solids retention times (SRTs) of 75, 40, 27, 20 and 15 days and organic loading rates (OLR) in the range 0.4–2.2 kg VS/(m3 day). The digester was fed with raw sludge (containing approximately 35 kg/m3 volatile solids (VS)) once daily during the 75-day SRT period, twice daily during the 40-day SRT period and three times a day during the 27-, 20- and 15-day SRT periods. The reactor was initially operated with an organic loading rate of 0.4 kg VS/(m3 day) and an SRT of 75 days. The volatile solids removal efficiency in the reactor was found to be 73%, while the volumetric methane production rate produced in the digester reached 0.02 m3/(m3 day). Over a 338-day operating period, an OLR of 2.2 kg VS/(m3 day) was achieved with 49.1% VS removal efficiency in the pilot sludge digester, at which time the volumetric methane production rate content of biogas produced in the digester reached 0.4 m3/(m3 day). The chemical oxygen demand (COD) mass balance obtained indicated that COD used for methane generation increased when the SRT was decreased or when the influent organic loading rate was increased. This implies that the amount of COD used in the anabolism route decreased with SRT due the microbial population becoming adapted to new operational conditions and more COD being used to generate methane.