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Abstract Hydrogen is considered a potential game changer for world energy systems and a solution to climate change concerns, as it generates zero waste and it is suited for power generation and transportation. Despite its several advantages, there are significant technical challenges in deploying a stable hydrogen economy including improving its process efficiencies, lowering production costs, maintaining cost-effective transmission and distribution, and exploiting inexpensive and sustainable feedstocks. In this context, a detailed study was conducted to analyze the production sources, technologies, storage and transport systems, and global potential exportable feedstocks to produce hydrogen. A comprehensive analysis of current hydrogen production technologies with their energy efficiencies and hydrogen selling prices was reported in this study. Various hydrogen production technologies with their capital investments and CO2 emissions were also presented. Potential feedstocks for hydrogen production were identified and analyzed through a product space model, which characterizes a network of global exportable products based on their similarities and productive knowledge. It was established that the hydrogen production feedstocks and sources currently used are primarily available in six countries: the United States of America, France, Russia, Sweden, the Netherlands, and Spain. Broadly, the results revealed that the United States of America and Russia shared the highest hydrogen feedstock exports, indicating a higher probability of hydrogen production in these countries. Except for Russia, all the studied countries fell in the most desired quadrant, indicating that they can move in all product space directions to exploit unexplored hydrogen feedstocks for better sustainable economic growth.

Abstract This paper presents a conceptual study of a solar PV integrated refrigeration system for a cold storage facility based on the conventional vapor compression system for banana fruit. In the first stage, the conventional system has been thoroughly analyzed. Mathematical modelling has shown that the condenser is oversized, while the evaporator was undersized. Furthermore, the air-conditioning compressor was also found to be oversized by approximately 12 kW after an evaluation at no-load and full-load conditions. In the second stage, the optimized system with reduced consumption was integrated to a solar PV field. The solar field sizing, and performance optimization of the proposed PV hybrid refrigeration system was accomplished in PV*SOL tool. The simulations demonstrated that with a 170 m2 solar field, an optimized PV hybrid refrigeration system can achieve 58.1% solar fraction at a performance ratio of 59.2%, under given climatic conditions. With net metering, the hybrid system shows a high economic feasibility with the payback period of 5.2 years. The comprehensive methodology and all-inclusive results are valuable to generate explicit recommendations for repowering along with renewable integration of cold storage facilities operating in the region.

Abstract Hydrogen fuel cells are received increasingly wide attention in order to develop green ships and reduce greenhouse gas emissions in the field of waterway transportation. Metal hydrides (MHs) can be used to store hydrogen for green ships due to their high volumetric storage capacity and safety. Various measures should be considered in the design and manufacture process of the MH reactor to strengthen its performance of heat and mass transfer and obtain an acceptable hydrogen storage capacity. In this work, LaNi5 hydride is used as the hydrogen storage material and packed in the reactor. A basic axisymmetric numerical model for the hydrogen storage system without a heat exchanger has been developed and proved to be effective through the comparison between its simulation results and the published data during dehydriding. A hybrid heat exchanger, which is consisted of a phase change material (PCM) jacket and a coiled-tube, has been applied into the hydrogen storage system to relieve the thermal effect of MH in the dehydriding process on system performance. Effects of the heat transfer coefficient between the circulating heating water in the coil-tube and the MH bed, the temperature of circulating heating water and the pressure at the outlet on the dehydriding performance have been investigated. Based on parametric study, the relationships among the average dehydriding rate, the heat transfer coefficient, the heating water temperature and the outlet pressure have been found and fitted as simple equations. These fitted equations can be considered as a reference, which provides an important method to effectively control the dehydriding rate in order to satisfy the fuel requirement of the power unit and ensure the safe navigation of green ships in the future.

The synthesis of biodiesel from Jatropha curcas by transesterification is kinetically controlled. It depends on the molar ratio, reaction time, and temperature, as well as the catalyst nature and quantity. The aim of this study was to explore the transesterification of low-cost, inedible J. curcas seed oil utilizing both homogenous (potassium hydroxide; KOH) and heterogenous (calcium oxide; CaO) catalysis. In this effort, two steps were used. First, free fatty acids in J. curcas oil were reduced from 12.4 to less than 1 wt.% with sulfuric acid-catalyzed pretreatment. Transesterification subsequently converted the oil to biodiesel. The yield of fatty acid methyl esters was optimized by varying the reaction time, catalyst load, and methanol-to-oil molar ratio. A maximum yield of 96% was obtained from CaO nanoparticles at a reaction time of 5.5 h with 4 wt.% of the catalyst and an 18:1 methanol-to-oil molar ratio. The optimum conditions for KOH were a molar ratio of methanol to oil of 9:1, 5 wt.% of the catalyst, and a reaction time of 3.5 h, and this returned a yield of 92%. The fuel properties of the optimized biodiesel were within the limits specified in ASTM D6751, the American biodiesel standard. In addition, the 5% blends in petroleum diesel were within the ranges prescribed in ASTM D975, the American diesel fuel standard.

One of the most important concerns in the planning and operation of an electric power generation system is the effective scheduling of all power generation facilities to meet growing power demand. Economic load dispatch (ELD) is a phenomenon where an optimal combination of power generating units is selected in such a way as to minimize the total fuel cost while satisfying the load demand, subject to operational constraints. Different numerical and metaheuristic optimization techniques have gained prominent importance and are widely used to solve the nonlinear problem. Although metaheuristic techniques have a good convergence rate than numerical techniques, however, their implementation seems difficult in the presence of nonlinear and dynamic parameters. This work is devoted to solving the ELD problem with the integration of variable energy resources using a modified directional bat algorithm (dBA). Then the proposed technique is validated via different realistic test cases consisting of thermal and renewable energy sources (RESs). From simulation results, it is observed that dBA reduces the operational cost with less computational time and has better convergence characteristics than that of standard BA and other popular techniques like particle swarm optimization (PSO) and genetic algorithm (GA).

In our continued efforts in the synthesis of ruthenium(II) polypyridine complexes as potential dyes for use in varied applications, such as the dye-sensitized solar cells (DSSCs), this work particularly describes the synthesis, absorption spectrum, redox behavior and luminescence properties of a new homoleptic ruthenium(II) complex bearing a simple trans-2-methyl-2-butenoic acid functionality as the anchoring ligand on terpyridine moiety. The functionalized terpyridine ligand: 4’-(trans-2-methyl-2-butenoic acid)-terpyridyl (L1) was synthesized by aryl bromide substitution on terpyridine in a basic reaction condition under palladium carbide catalysis. In particular, the photophysical and redox properties of the complex formulated as: bis-4’-(trans-2-methyl-2-butenoic acid)-terpyridyl ruthenium(II) bis-hexafluorophosphate [Ru(L1)2(PF6)2] are significantly better compared to those of [Ru(tpy)2]2+ and compare well with those of the best emitters of Ru(II) polypyridine family containing tridentate ligands. Reasons for the improved photophysical and redox properties of the complex may be attributed partly to the presence of a substituted α,β-unsaturated carboxylic acid moiety leading to increase in the length of π-conjugation bond thereby enhancing the MLCT-MC (Metal-to-ligand-charge transfer-metal centred) energy gap, and to the reduced difference between the minima of the excited and ground states potential energy surfaces.

En los países del sur de Asia, incluidos Bangladesh, India y Pakistán, el escenario energético actual se considera no sostenible debido a diversas cuestiones, como las opciones económicas, ambientales, geopolíticas y tecnológicas para la explotación de la energía y el volumen insignificante del comercio regional de energía. Sin embargo, dentro de la región, India está liderando una fase de transición energética y transformación económica a través del desarrollo de energías renovables. Los países deben mostrar buenos resultados en el desarrollo de sus fuentes renovables siguiendo el rápido ritmo de las energías renovables en todo el mundo. Este artículo ofrece una visión general del escenario energético, el crecimiento de las energías renovables, la evolución y el enfoque de la política energética al resaltar los desafíos y barreras clave para la combinación energética ecológica de los países. Es importante destacar que el documento evalúa la combinación energética actual en el sur de Asia, destacando la anomalía de sus perspectivas futuras basadas en combustibles fósiles, sus ambiciones de avanzar hacia una menor contaminación ambiental y una combinación energética sostenible a través de un análisis FODA de herramientas estratégicas; fortalezas, debilidades, oportunidades y amenazas (FODA). En particular, este estudio examina las políticas gubernamentales para expandir la implementación de fuentes renovables con una visión de la estructura regulatoria existente del sector energético. Los hallazgos de la investigación presentada sugieren que para lograr el ambicioso objetivo de reducir la descarga de emisiones hasta en un 30% para el año 2030 en el marco de las Contribuciones Previstas Determinadas a Nivel Nacional (INDC), los gobiernos de los tres países deben tomar medidas preventivas. Incluye la reducción gradual de los subsidios a los combustibles fósiles, la integración del mercado dentro de la región y la rápida realización de las iniciativas existentes a través de una fuerte voluntad política, una buena gobernanza, la adopción de las últimas tecnologías y un plan de acción pragmático, y la cooperación energética en toda la región. Dans les pays d'Asie du Sud, y compris le Bangladesh, l'Inde et le Pakistan, le scénario énergétique actuel est considéré comme non durable en raison de divers problèmes tels que les options économiques, environnementales, géopolitiques et technologiques pour l'exploitation de l'énergie et le volume négligeable du commerce régional de l'énergie. Bien que, dans la région, l'Inde mène une phase de transition énergétique et de transformation économique grâce au développement des énergies renouvelables. Les pays doivent bien montrer dans le développement de leurs sources renouvelables à la suite du rythme rapide des énergies renouvelables dans le monde entier. Cet article offre un aperçu du scénario énergétique, de la croissance des énergies renouvelables, de l'évolution et de l'approche de la politique énergétique en soulignant les principaux défis et obstacles pour le mix énergétique écologique des pays. Il est important de noter que le document évalue le bouquet énergétique actuel en Asie du Sud, en soulignant l'anomalie de ses perspectives d'avenir basées sur les combustibles fossiles, ses ambitions de réduire la pollution environnementale et son bouquet énergétique durable grâce à une analyse SWOT d'outil stratégique ; forces, faiblesses, opportunités et menaces (SWOT). En particulier, cette étude examine les politiques gouvernementales visant à étendre la mise en œuvre des sources renouvelables avec un aperçu de la structure réglementaire existante du secteur de l'énergie. Les résultats de recherche présentés suggèrent que pour atteindre l'objectif ambitieux de réduire les rejets d'émissions jusqu'à 30 % d'ici 2030 dans le cadre des contributions prévues déterminées au niveau national (CPDN), les gouvernements des trois pays doivent prendre des mesures préventives. Il comprend la réduction progressive des subventions sur les combustibles fossiles, l'intégration du marché dans la région et la réalisation rapide des initiatives existantes grâce à une forte volonté politique, à une bonne gouvernance, à l'adoption des dernières technologies, à un plan d'action pragmatique et à une coopération énergétique dans toute la région. In the South Asian countries, including Bangladesh, India, and Pakistan, the current energy scenario is considered non-sustainable due to diverse issues such as economic, environmental, geopolitical, technological options for energy exploitation, and negligible volume of regional energy trade. Though, within the region, India is leading a phase of energy transition and economic transformation through renewable energy development. The countries need to exhibit well in the development of their renewable sources following the rapid pace of renewable energies worldwide. This article offers an overview of the energy scenario, growth of renewable energies, evolution, and approach for energy policy by highlighting key challenges and barriers for the ecological energy mix of the countries. Importantly, the paper assesses the current energy mix in South Asia, highlighting the anomaly of its fossil fuel-based future outlook, its ambitions to move towards less environmental pollution, and sustainable energy mix through a strategic tool SWOT analysis; strengths, weaknesses, opportunities, and threats (SWOT). In particular, this study examines the government policies to expand the implementation of renewable sources with an insight into the existing regulatory structure of the energy sector. The presented research findings suggest that to achieve the ambitious target to reduce emission discharge by up to 30% by the year 2030 under Intended Nationally Determined Contributions (INDCs), the Governments of the three countries must take preemptive measures. It includes the stage-wise reduction of subsidies on fossil fuels, market integration within the region, and swift realization of the existing initiatives through strong political will, good governance, adoption of the latest technologies, and a pragmatic action plan, and energy cooperation across the region. في بلدان جنوب آسيا، بما في ذلك بنغلاديش والهند وباكستان، يعتبر سيناريو الطاقة الحالي غير مستدام بسبب قضايا متنوعة مثل الخيارات الاقتصادية والبيئية والجيوسياسية والتكنولوجية لاستغلال الطاقة، وحجم ضئيل من تجارة الطاقة الإقليمية. على الرغم من أن الهند، داخل المنطقة، تقود مرحلة انتقال الطاقة والتحول الاقتصادي من خلال تطوير الطاقة المتجددة. تحتاج البلدان إلى أن تظهر أداءً جيدًا في تطوير مصادرها المتجددة بعد الوتيرة السريعة للطاقات المتجددة في جميع أنحاء العالم. تقدم هذه المقالة لمحة عامة عن سيناريو الطاقة، ونمو الطاقات المتجددة، والتطور، ونهج سياسة الطاقة من خلال تسليط الضوء على التحديات والحواجز الرئيسية لمزيج الطاقة البيئية للبلدان. والأهم من ذلك، تقوم الورقة بتقييم مزيج الطاقة الحالي في جنوب آسيا، مع تسليط الضوء على الشذوذ في توقعاتها المستقبلية القائمة على الوقود الأحفوري، وطموحاتها للتحرك نحو تلوث بيئي أقل، ومزيج الطاقة المستدامة من خلال تحليل SWOT الاستراتيجي للأداة ؛ نقاط القوة والضعف والفرص والتهديدات (SWOT). على وجه الخصوص، تبحث هذه الدراسة في السياسات الحكومية لتوسيع تنفيذ مصادر الطاقة المتجددة مع نظرة ثاقبة على الهيكل التنظيمي الحالي لقطاع الطاقة. تشير نتائج البحث المقدمة إلى أنه لتحقيق الهدف الطموح المتمثل في الحد من تصريف الانبعاثات بنسبة تصل إلى 30 ٪ بحلول عام 2030 بموجب المساهمات المقررة المحددة وطنيًا (INDCs)، يجب على حكومات البلدان الثلاثة اتخاذ تدابير وقائية. ويشمل ذلك التخفيض التدريجي للإعانات على الوقود الأحفوري، وتكامل الأسواق داخل المنطقة، والإدراك السريع للمبادرات القائمة من خلال الإرادة السياسية القوية، والحكم الرشيد، واعتماد أحدث التقنيات، وخطة عمل عملية، والتعاون في مجال الطاقة في جميع أنحاء المنطقة.

Abstract Building energy prediction is a key factor to assess the energy performance of commercial buildings, identify operation issues and propose better operating strategies based on the forecast information. Different models have been used to forecast energy demand in buildings, including whole building energy simulation, regression analysis, and black-box models (e.g., artificial neural networks). This paper presents a different approach to predict the energy demand of commercial buildings using case-based reasoning (CBR). The proposed approach is evaluated using monitored data in a real office building located in Varennes, Quebec. The energy demand is predicted at every hour for the following 3 h using weather forecasts. The results show that during occupancy, 7:00–18:00, the coefficient of variance of the root-mean-square-error (CV-RMSE) is below 13.2%, the normalized mean bias error (NMBE) is below 5.8% and the root-mean-square-error (RMSE) is below 14 kW. When the statistical criteria are calculated for all hours of the day, the CV-RMSE is 12.1%, the NMBE is 1.0% and the RMSE is 11 kW. The case study demonstrates that CBR can be used for energy demand prediction and could be implemented in building operation systems.