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Abstract The influence of the solid-phase wall boundary condition was investigated in Eulerian–Eulerian numerical simulations of a bubbling fluidized bed. Parametric studies of the particle–wall restitution coefficient and specularity coefficient were performed to evaluate their impact on the predicted flow hydrodynamics in terms of bed expansion, local voidage, and solid velocity. Both two- and three-dimensional simulations were conducted and compared with available experimental data on solid velocity and bubble properties. It is found that the wall effect plays an important role in CFD models. Such factors as the voidage at the bubble boundary, averaging method, and minimum bubble size also influence the mean bubble diameter.

Abstract Recharging infrastructure (RI) deployment plays a vital role in improving the public recharging availability for transport electrification. Decarbonizing transportation using low-emission electricity requires massive RI network. Even though the consumers are reluctant to purchase electric vehicles (EVs) until RIs are sufficiently placed, the investors are not willing to invest in RIs due to recharging demand uncertainties. Therefore, a scientific planning framework is needed to ensure the sustainable deployment of EV-RIs in complex networks. In this study, a lifecycle thinking-based multi-period infrastructure-planning framework is proposed to develop sustainable public EV-RIs in an urban context. This framework consists of a temporal model to find the dynamic EV-RI demands, a stochastic model to obtain travel distances, and a multi-objective optimization model to select the best desirable capacities and locations for potential EV-RIs. A case study of a typical medium-scale municipality in Canada was assessed using the proposed framework and validated using conventional infrastructure planning scenarios. The geo-processing data, regional travel behaviors, and recharging characteristics were used as model inputs. The results of the case study showed that the proposed framework can be used to estimate multi-period public recharging demands, minimize lifecycle costs, maximize service coverage and infrastructure utilization, and ensure reasonable paybacks compared to conventional planning approaches. Moreover, this framework can be used to compare different investment assistances, which are required in the early stages of the RI deployment process to encourage investors. Furthermore, government and private institutions can use this framework to identify recharging demands, permitting, and developing RIs in the long-run.

AbstractCellulose and lignin nanoparticles are high‐value‐added products obtained from lignocellulosic biomasses through several steps of cellulose purification and lignin extraction. These steps drastically reduce the potential feedstock revenue when carried out as stand‐alone methodologies. To increase biomass yields, we describe here a strategy to design a biorefinery focused on producing cellulose and lignin nanoparticles as main products, but also aim to recover and benefit from other biomass components using only water‐based processes. Sequential pressurized liquid extractions and diluted acid and alkaline treatments were carried out to fractionate elephant grass biomass, yielding (for every 100 g of biomass): 30 g of cellulose pulp (converted to 9 g of cellulose nanocrystals and 9 g of cellulose nanofibers); 10 g of lignin (used to produce 8.5 g of stable colloidal lignin nanoparticles by probe‐sonication in water); 7.5 g of extractives (e.g. sterols and phenolics) and 23 g of xylose (converted to 4.1 g of furfural). Alternatively, to allow for the flexible use of the cellulose fraction in the proposed biorefinery, 22 g of glucose could be produced by enzymatic hydrolysis. The results demonstrate that water‐based processes are suitable for a holistic use of biomass, providing a comprehensive set of high‐value‐added co‐products that are renewable and cost‐effective chemical, cosmetic, food, polymer and pharmaceutical solutions.

Abstract Conjugate heat transfer of liquid-gas fin and tube heat exchangers is widely used in industry. However, heat transfer characteristics of such system is difficult to predict as the limiting heat rate can be from either side. This paper aims to quantify the conjugate heat transfer performance of fin and tube heat exchangers via mathematical modeling. Three-dimensional conjugate fluid flow and heat transfer model is developed and validated against the state-of-the-art experimental data and existing analytical correlations. Turbulent k-e model has been employed for the fluid flow and heat transfer modeling. Statistical method, i.e. data reduction and multivariate nonlinear regression techniques, is implemented to analyse the results and to quantify the interaction between parameters. Wide range of parametric studies and simulations is further carried out to evaluate the significance of design, geometrical and operating parameters. According to the results of the study, larger fin length factor and fin pitch and the smaller tube diameter are in favor of fin and tube heat exchangers within the Reynolds number range of 3000–12,000. Finally, a novel conjugate heat transfer correlation for liquid-gas finned tube heat exchangers is proposed to assist engineers for practical designs and applications. The results suggest that our new correlation gives rise to a more accurate conjugate heat transfer prediction as compared to that of traditional non-conjugate counterpart.

Summary Separating edaphic impacts on tree distributions from those of climate and geography is notoriously difficult. Aboveground and belowground factors play important roles, and determining their relative contribution to tree success will greatly assist in refining predictive models and forestry strategies in a changing climate. In a common glasshouse, seedlings of interior Douglas‐fir (Pseudotsuga menziesii var. glauca) from multiple populations were grown in multiple forest soils. Fungicide was applied to half of the seedlings to separate soil fungal and nonfungal impacts on seedling performance. Soils of varying geographic and climatic distance from seed origin were compared, using a transfer function approach. Seedling height and biomass were optimized following seed transfer into drier soils, whereas survival was optimized when elevation transfer was minimised. Fungicide application reduced ectomycorrhizal root colonization by c. 50%, with treated seedlings exhibiting greater survival but reduced biomass. Local adaptation of Douglas‐fir populations to soils was mediated by soil fungi to some extent in 56% of soil origin by response variable combinations. Mediation by edaphic factors in general occurred in 81% of combinations. Soil biota, hitherto unaccounted for in climate models, interacts with biogeography to influence plant ranges in a changing climate.

AbstractThe state of California could play an important role in emerging markets for biochar, due in part to the availability of low‐value biomass resources and their potential for use in agriculture sector. In this study, we assess the scale of production and use, and comment on potential markets for biochar in California. We explore various sectors for the application of biochar produced from local biomass using surveys and a market‐sizing approach. A market‐oriented approach for biochar innovation and the ecosystem around a biochar producer is also discussed. Next, we identify barriers to biochar market success in the present and the near future based on a survey of local producers. Among the barriers analyzed, access to capital investment for scale‐up is the biggest barrier experienced by a majority of producers, followed by market and demand. When grouped under different categories, the extent of barriers decreased in the order: market > scale‐up > technical > socio‐political > environmental. Most producers anticipate that revenues from carbon offset credits would help them scale up their facilities and expand the biochar market. In the near future, soil‐based applications of biochar could be the most likely market for biochar, followed by filtration, livestock feed, and manure management. As the industry evolves, rewarding carbon credits, increasing awareness and improving production processes are expected to help commercialize biochar. Finally, we offer recommendations to promote the growth of biochar in California. © 2021 Society of Chemical Industry and John Wiley & Sons, Ltd

Abstract This paper provides a comprehensive overview of developments and recent trends in H2 separation technology that uses dense proton–electron conducting ceramic materials and their associated membranes. Various proton–electron conducting materials and their associated membranes are summarized and classified into several important categories, such as Ni-composite proton-conducting materials, as well as tungstate-based, BaPrO3-based, LaGaO3-based, and niobate/tantalite composite metal oxide-based ceramic materials/membranes. Various membrane designs, including asymmetric ceramic membranes (supported and self-supported) and surface-modified membranes, are also reviewed. Several important properties of ceramic materials and membranes, such as proton and electron conductivity and performance (i.e., H2 transport flux and lifetime stability), are also discussed. To highlight the technical progress in this area, all possible ceramic materials and associated membranes are summarized, along with their properties and performance, to help readers quickly locate the information they are looking for. Based on this review, several challenges hindering the maturation of this technology are analyzed in depth, and possible research directions for overcoming these challenges are suggested.

Abstract This study simulated the effect of time on bioenergy production from dairy manure and associated variation in energy demand and GHG emission in Ohio and Hawaii. Increasing the residence-time (RT) decreases the bioenergy-production in a nonlinear-fashion, for both the states (Ohio and Hawaii). Using the main scenario in Hawaii, the highest bioenergy production for 30 days RT was 11.2 × 104 GJ. Life-cycle-assessment of produced bioenergy showed that energy requirement and GHG emission of the produced-bioenergy (GJ) varied from 0.65 to 0.67 and 28–35 kg CO2/GJ bioenergy respectively. Year-round bioenergy production through main scenario was more advantageous with respect to bioenergy production and GHG emission. Decreasing nitrogen concentration for algal biomass production increased the bioenergy production significantly with a reduced energy demand and marginally increased GHG emission. Hence, the LCA model predicted that running a biorefinery for short residence time, and using diluted waste, could provide bioenergy with reduced energy requirement and GHG-emission.

The uncertainties in renewable generators and load demand make it a challenge for system operators to execute the security-constrained unit commitment (SCUC) program in an ac-dc grid. The SCUC is a nonlinear mixed-integer optimization problem due to the power flow equations, constraints imposed by the ac-dc converters, and the binary variables associated with the generators’ on/off state. In this paper, we study the SCUC problem in ac-dc grids with generation and load uncertainty. We introduce the concept of conditional value-at-risk to limit the risk of deviations in the load demand and renewable generation. We relax the binary variables and introduce a $l_1$ -norm regularization term to the objective function, and then use convex relaxation techniques to transform the problem into a semidefinite program (SDP). We develop an algorithm based on the iterative reweighted $l_1$ -norm approximation that involves solving a sequence of SDPs. Simulations are performed on an IEEE 30-bus test system. Results show that the proposed algorithm returns a solution within 2% gap from the global optimal solution for the underlying test system. When compared with the multi-stage algorithm in the literature, our algorithm has a lower running time and returns a solution with a smaller gap from the global optimal solution.