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Abstract The use of thermal energy storage (TES) systems for solar heating and cooling applications has received considerable attention in recent decades because it has a high potential in energy savings. Phase change materials (PCMs) can store large amount of energy per mass unit compared with other TES materials. Nevertheless, the selection of the suitable PCM for each application is a key issue in any TES system design. The most important properties to take into account to select a PCM are the melting and solidification temperature, the phase change enthalpy and the stability after several thermal cycles. In this paper, d -mannitol was a candidate material to be tested as PCM in a solar cooling application due to its melting point (167 °C) and a relatively high enthalpy (316.0 kJ/kg). The experiments performed by DSC have shown that the d -mannitol presents polymorphic structural changes and, therefore, its thermal properties are not always the same. Depending on the polymorphic phase obtained, d -mannitol has different melting temperature. This behaviour was corroborated in a storage tank, where it may be seen that the cooling rate of the d -mannitol is a key parameter in the formation of the different polymorphic phases.

Abstract The use of thermal energy storage (TES) systems for solar heating and cooling applications has received considerable attention in recent decades because it has a high potential in energy savings. Phase change materials (PCMs) can store large amount of energy per mass unit compared with other TES materials. Nevertheless, the selection of the suitable PCM for each application is a key issue in any TES system design. The most important properties to take into account to select a PCM are the melting and solidification temperature, the phase change enthalpy and the stability after several thermal cycles. In this paper, d -mannitol was a candidate material to be tested as PCM in a solar cooling application due to its melting point (167 °C) and a relatively high enthalpy (316.0 kJ/kg). The experiments performed by DSC have shown that the d -mannitol presents polymorphic structural changes and, therefore, its thermal properties are not always the same. Depending on the polymorphic phase obtained, d -mannitol has different melting temperature. This behaviour was corroborated in a storage tank, where it may be seen that the cooling rate of the d -mannitol is a key parameter in the formation of the different polymorphic phases.

Abstract Thermal energy storage systems for both heat and cold are necessary for many industrial processes. High energy density and high power capacity are desirable properties of the storage. The use of latent heat increases the energy density of the storage tank with high temperature control close to the melting point. Tube in PCM tank is a very promising system that provides high packing factor. This work presents an experimental study of a PCM tank for cold storage applications. Two different configurations and different flow rates of the heat transfer fluid were studied. The effectiveness of the PCM storage system was defined as that of a heat exchanger. The results showed that the heat exchange effectiveness of the system did not vary with time, decreased with increasing flow rate and increased with increasing heat transfer area. The effectiveness was experimentally determined to only be a function of the ratio m ˙ /A. This equation was found to be adequately be used to design a PCM storage system, and a case study is presented. It was shown that the tube in tank design together with a low temperature PCM is suitable as a thermal storage facility for cold storage.

Abstract Thermal energy storage systems for both heat and cold are necessary for many industrial processes. High energy density and high power capacity are desirable properties of the storage. The use of latent heat increases the energy density of the storage tank with high temperature control close to the melting point. Tube in PCM tank is a very promising system that provides high packing factor. This work presents an experimental study of a PCM tank for cold storage applications. Two different configurations and different flow rates of the heat transfer fluid were studied. The effectiveness of the PCM storage system was defined as that of a heat exchanger. The results showed that the heat exchange effectiveness of the system did not vary with time, decreased with increasing flow rate and increased with increasing heat transfer area. The effectiveness was experimentally determined to only be a function of the ratio m ˙ /A. This equation was found to be adequately be used to design a PCM storage system, and a case study is presented. It was shown that the tube in tank design together with a low temperature PCM is suitable as a thermal storage facility for cold storage.

Because of their numerous advantages, lithium-ion (Li-ion) batteries have recently become a focus of research interest for vehicle applications. Li-ion batteries are suitable for electric vehicles (EVs) and hybrid electric vehicles (HEVs) because of advantages such as their high specific energy, high energy density, and low self-discharge rate in comparison with other secondary batteries. Nevertheless, the commercial availability of Li-ion batteries for vehicle applications has been hindered by issues of safety, cost, charging time, and recycling. One principal limitation of this technology resides in its poor low-temperature performance. Indeed, the effects of low temperature reduce the battery’s available energy and increase its internal impedance. In addition, performance-hampering cell degradation also occurs at low temperatures and throughout the entire life of a Li-ion battery. All of these issues pose major difficulties for cold-climate countries. This paper reviews the effects of cold temperatures on the capacity/power fade of Li-ion battery technology. Extensive attention is paid to the aging mechanisms of Li-ion batteries at cold temperatures. This paper also reviews several battery models found in the literature. Finally, thermal strategies are detailed, along with a discussion of the ideal approach to cold-temperature operation.

Because of their numerous advantages, lithium-ion (Li-ion) batteries have recently become a focus of research interest for vehicle applications. Li-ion batteries are suitable for electric vehicles (EVs) and hybrid electric vehicles (HEVs) because of advantages such as their high specific energy, high energy density, and low self-discharge rate in comparison with other secondary batteries. Nevertheless, the commercial availability of Li-ion batteries for vehicle applications has been hindered by issues of safety, cost, charging time, and recycling. One principal limitation of this technology resides in its poor low-temperature performance. Indeed, the effects of low temperature reduce the battery’s available energy and increase its internal impedance. In addition, performance-hampering cell degradation also occurs at low temperatures and throughout the entire life of a Li-ion battery. All of these issues pose major difficulties for cold-climate countries. This paper reviews the effects of cold temperatures on the capacity/power fade of Li-ion battery technology. Extensive attention is paid to the aging mechanisms of Li-ion batteries at cold temperatures. This paper also reviews several battery models found in the literature. Finally, thermal strategies are detailed, along with a discussion of the ideal approach to cold-temperature operation.

Abstract Life Cycle Assessment (LCA) has been conducted for seven experimental cubicles located in Puigverd de Lleida (Spain). The objective of this experimental set-up is to test different constructive solutions in order to point out the most sustainable solution with lower energy demand during the operational phase. Therefore, different building, insulation and Phase Change Materials (PCMs) have been tested under controlled temperature conditions to examine the thermal performance of the whole system. Although some of these materials are able to reduce the energy demand and consequently the environmental impact during the operational phase, they still have high embodied energy that can cause high environmental impact during the manufacturing phase. Therefore the LCA study in this paper focuses on assessing the impact of the embodied energy needed during the manufacturing and disposal phase by highlighting and comparing the effect of using different building materials, insulating materials, and phase change materials.

Abstract Life Cycle Assessment (LCA) has been conducted for seven experimental cubicles located in Puigverd de Lleida (Spain). The objective of this experimental set-up is to test different constructive solutions in order to point out the most sustainable solution with lower energy demand during the operational phase. Therefore, different building, insulation and Phase Change Materials (PCMs) have been tested under controlled temperature conditions to examine the thermal performance of the whole system. Although some of these materials are able to reduce the energy demand and consequently the environmental impact during the operational phase, they still have high embodied energy that can cause high environmental impact during the manufacturing phase. Therefore the LCA study in this paper focuses on assessing the impact of the embodied energy needed during the manufacturing and disposal phase by highlighting and comparing the effect of using different building materials, insulating materials, and phase change materials.