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Abstract This paper uses research-quality, ground measurements of irradiance and temperature that are accurate to ±2% to estimate the electric energy yield of fixed solar modules for utility-scale solar power plants at 18 sites in Saudi Arabia. The calculation is performed for a range of tilt and azimuth angles and the orientation that gives the optimum annual energy yield is determined. A detailed analysis is presented for Riyadh including the impact of non-optimal tilt and azimuth angles on annual energy yield. It is also found that energy yield in March and October are higher than in April and September, due to milder operating temperatures of the modules. A similar optimization of tilt and azimuth is performed each month separately. Adjusting the orientation each month increases energy yield by 4.01% compared to the annual optimum, but requires considerable labour cost. Further analysis shows that an increase in energy yield of 3.63% can be obtained by adjusting the orientation at five selected times during the year, thus significantly reducing the labour requirement. The optimal orientation and corresponding energy yield for all 18 sites is combined with a site suitability analysis taking into account climate, topography and proximity to roads, transmission lines and protected areas. Six sites are selected as having high suitability and high energy yield: Albaha, Arar, Hail, Riyadh, Tabuk and Taif. For these cities the optimal tilt is only slightly higher than the latitude, however the optimum azimuth is from 20° to 53° west of south due to an asymmetrical daily irradiance profile.

Abstract In the present study, Loblolly pine biomass residue was converted to bio-oil in a two-step process, consisting of 1) fast pyrolysis in the presence of zeolite ZSM-5 as a catalyst to produce pyrolysis oil, 2) hydrogenation of pyrolysis oil using formic acid as the hydrogen source in presence of Ru/activated carbon catalyst. Pyrolysis oils were analyzed by 13C, 31P and HSQC-NMR and the results revealed that the zeolite-induced catalytic fast pyrolysis process led to effective demethoxylation, producing more catechol and p-hydroxy-phenyl hydroxyl groups in the bio-oils, resulting in a decrease in the methoxyl group content by about 85 % and rich aromatic structures in the pyrolysis oils. The properties of pyrolysis oil with and without zeolite were in the bio-oil range. Hydrogenated pyrolysis oil showed that 79 % of the aromatic protons are eliminated and 87 % of protons are aliphatic in nature, with no oxygen attached to the α-carbon.

The ‘4 per mille Soils for Food Security and Climate’ was launched at the COP21 with an aspiration to increase global soil organic matter stocks by 4 per 1000 (or 0.4 %) per year as a compensation for the global emissions of greenhouse gases by anthropogenic sources. This paper surveyed the soil organic carbon (SOC) stock estimates and sequestration potentials from 20 regions in the world (New Zealand, Chile, South Africa, Australia, Tanzania, Indonesia, Kenya, Nigeria, India, China Taiwan, South Korea, China Mainland, United States of America, France, Canada, Belgium, England & Wales, Ireland, Scotland, and Russia). We asked whether the 4 per mille initiative is feasible for the region. The outcomes highlight region specific efforts and scopes for soil carbon sequestration. Reported soil C sequestration rates globally show that under best management practices, 4 per mille or even higher sequestration rates can be accomplished. High C sequestration rates (up to 10 per mille) can be achieved for soils with low initial SOC stock (topsoil less than 30 t C ha− 1), and at the first twenty years after implementation of best management practices. In addition, areas which have reached equilibrium will not be able to further increase their sequestration. We found that most studies on SOC sequestration only consider topsoil (up to 0.3 m depth), as it is considered to be most affected by management techniques. The 4 per mille number was based on a blanket calculation of the whole global soil profile C stock, however the potential to increase SOC is mostly on managed agricultural lands. If we consider 4 per mille in the top 1m of global agricultural soils, SOC sequestration is between 2-3 Gt C year− 1, which effectively offset 20–35% of global anthropogenic greenhouse gas emissions. As a strategy for climate change mitigation, soil carbon sequestration buys time over the next ten to twenty years while other effective sequestration and low carbon technologies become viable. The challenge for cropping farmers is to find disruptive technologies that will further improve soil condition and deliver increased soil carbon. Progress in 4 per mille requires collaboration and communication between scientists, farmers, policy makers, and marketeers.

In our continued efforts in the synthesis of ruthenium(II) polypyridine complexes as potential dyes for use in varied applications, such as the dye-sensitized solar cells (DSSCs), this work particularly describes the synthesis, absorption spectrum, redox behavior and luminescence properties of a new homoleptic ruthenium(II) complex bearing a simple trans-2-methyl-2-butenoic acid functionality as the anchoring ligand on terpyridine moiety. The functionalized terpyridine ligand: 4’-(trans-2-methyl-2-butenoic acid)-terpyridyl (L1) was synthesized by aryl bromide substitution on terpyridine in a basic reaction condition under palladium carbide catalysis. In particular, the photophysical and redox properties of the complex formulated as: bis-4’-(trans-2-methyl-2-butenoic acid)-terpyridyl ruthenium(II) bis-hexafluorophosphate [Ru(L1)2(PF6)2] are significantly better compared to those of [Ru(tpy)2]2+ and compare well with those of the best emitters of Ru(II) polypyridine family containing tridentate ligands. Reasons for the improved photophysical and redox properties of the complex may be attributed partly to the presence of a substituted α,β-unsaturated carboxylic acid moiety leading to increase in the length of π-conjugation bond thereby enhancing the MLCT-MC (Metal-to-ligand-charge transfer-metal centred) energy gap, and to the reduced difference between the minima of the excited and ground states potential energy surfaces.

Carbon capture, utilization, and storage (CCUS) is a gas injection technology that enables the storage of CO2 underground. The aims are twofold, on one hand to reduce the emissions of CO2 into the atmosphere and on the other hand to increase oil/gas/heat recovery. Different types of CCUS technologies and related engineering projects have a long history of research and operation in the USA. However, in China they have a short development period ca. 10 years. Unlike CO2 capture and CO2-EOR technologies that are already operating on a commercial scale in China, research into other CCUS technologies is still in its infancy or at the pilot-scale. This paper first reviews the status and development of the different types of CCUS technologies and related engineering projects worldwide. Then it focuses on their developments in China in the last decade. The main research projects, international cooperation, and pilot-scale engineering projects in China are summarized and compared. Finally, the paper examines the challenges and prospects to be experienced through the industrialization of CCUS engineering projects in China. It can be concluded that the CCUS technologies have still large potential in China. It can only be unlocked by overcoming the technical and social challenges.