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AbstractThe fluid flow characteristics in shale fractures are of great significance for shale gas reservoir evaluation and exploitation. In this study, artificial tension fractures in shale were used to simulate the hydraulic fractures formed by fracturing, and a gas flow test under different pressure gradients was conducted. The nonlinear gas flow and stress‐dependent permeability characteristics were analyzed. The experimental results show the following: (a) CO2 flow in shale fractures exhibits strong nonlinearity. Forchheimer's law, which considers gas compressibility, satisfactorily describes the nonlinear relationship between the flow rate and the pressure gradients in shale fractures. (b) The permeability sensitivity of shale fractures under stress is very strong, and the exponential relationship better describes the pressure dependency of the permeability for the tested shale samples. The permeability of the shale fractures is similar when measured parallel or perpendicular to bedding. Furthermore, the pressure dependence of fractures in shale obeys the Walsh permeability model. (c) As the effective stress increases, the nonlinear flow behavior appears earlier. Based on the Reynolds number and the nonlinear coefficient, a friction factor model is proposed. (d) The normalized transmissivity exhibits a strong correlation with the Reynolds number. CO2 flow through shale fractures is generally dominated by transitional flow. The critical Reynolds number ranges from 1.8 to 102.88 and decreases with increasing effective stress.

Background: Fish entrainment through turbine intakes is one of the major issues for operators of hydropower facilities because it causes injury and/or mortality and adversely affects population abundance. Entrainment reduction strategies have been developed based on the behavior of downstream migrating fishes, particularly diadromous species. However, knowledge of the behavior of migratory fishes has very limited application for reducing the entrainment of resident fishes, including several species that represent important recreational and aboriginal fishery resources in reservoirs. In this study, we used fine-scale acoustic telemetry and state-space modeling to investigate behavioral attributes associated with entrainment risk of resident adult bull trout (Salvelinus confluentus) in a large hydropower reservoir in British Columbia, Canada. Results: We found that adult bull trout resided longer in the vicinity of the powerhouse and moved closer to the turbine intakes in the fall and particularly in the winter. Bull trout were more likely to engage in exploratory behavior (characteristic of foraging or reduced activity) during periods when their body temperature was lower or higher than 6°C. We also detected diel changes in behavioral attributes, with bull trout distance to intakes and probability of exploratory behavior slightly increasing at night. Conclusions: We hypothesize that the exploratory behavior in the forebay is associated with foraging for kokanee (nonanadromous form of Oncorhynchus nerka), which have been shown to congregate near the dams of hydropower reservoirs in the winter. Our study findings should be applicable to bull trout populations residing in other reservoirs and indicate that entrainment mitigation (for example, use of deterrent devices) should be focused on the fall and winter. This work also provides a framework for combining acoustic telemetry and state-space models to understand and categorize movement behavior of fish in reservoirs and, more generally, in any environment with fluctuating water levels.

Pool boiling in porous media has been applied in various thermal management systems by using latent heat and increasing the heat transfer area and thermal conduction path to improve the heat transfer performance. In mechanical equipment, vibration is an inevitable problem due to reasons such as engine operation and high-speed relative motion between transmission system components, which causes the system components to be affected by vibration forces or vibration accelerations. This study focuses on a review of published articles about the effects of mechanical vibration on the characteristics of boiling process in porous media by two aspects: heat transfer performance and bubble dynamics. Heat transfer coefficient (HTC) and critical heat flux are two main parameters used to measure the boiling heat transfer characteristics of porous media. For bubble dynamics investigations, properties such as migration, fragment, coalescence, departure diameter and frequency are the focus of research attention. Different mechanical vibration parameters, i.e., direction, frequency, and amplitude, will have different effects on the above characteristics. It is worth mentioning that the greatest influence occurs under resonance conditions, and this has been verified through experimental and simulation calculations. This review highlights the importance of considering mechanical vibrations in the design and optimization of porous media systems for efficient heat transfer applications. Further research is warranted to explore the detailed mechanisms and optimize the vibration parameters for enhanced heat transfer performance in thermal management systems using porous media.

Many aquatic species with stylar polymorphisms have the capacity for clonal and sexual reproduction and are sensitive to the balance of the two reproductive modes when there are a limited number of mating morphs within a population. This study asked how the clonal and sexual reproductive modes perform in populations that contain only a single morph and where fitness gain through sexual reproduction is rare. In clonal aquatic Nymphoides montana, polymorphic populations normally contain two mating morphs in equal frequencies. Populations are sexually fertile and appear to be maintained by pollen transfer between the two partners. However, in a monomorphic population of N. montana where mating opportunities are unavailable, female and male function is impaired and clonality maintains the population. Here, the consequences of intraspecific variation in sexuality were explored between monomorphic and polymorphic N. montana populations in eastern Australia.Comparative measurements of male and female fertility, total dry mass and genotypic diversity using ISSR markers were made between populations with variable sexuality.Very few seeds were produced in the monomorphic population under natural and glasshouse conditions due to dysfunctional pollen and ovules. Stigma-anther separation was minimal in the monomorphic population, which may be a consequence of the relaxed selective pressures that regulate the maintenance of sexual function. However, clonal reproduction was favoured at the expense of sexual reproduction in the monomorphic population; this may facilitate the establishment of sterility throughout the population via resource reallocation or pleiotropic effects. The ISSR results showed that the monomorphic population was one large, single genotype, unlike the multi-genotypic fertile polymorphic populations. Evolutionary loss of sex in a clonal population in which a mating morph is absent was evident; under these conditions clonal growth may assure reproduction and expand the population via spreading stolons.

To mitigate the temperature increase in urban environments and reduce its impact on energy consumption and the quality of the environment, urban retrofitting technologies have been developed and applied worldwide. High albedo in urban surfaces and additional vegetation are the most efficient strategies to accomplish these goals. The objective of this study is to estimate the weight of these strategies, both individually and integrated, on the cooling potential of two Latin American cities. To do this, 36 low and high urban density scenarios were simulated with the ENVI-Met software. The simulation models were calibrated using air temperature curves which were monitored during the summer periods from 2010 to 2013. A Principal Components Analysis was carried out to establish possible associations between the proposed mitigation strategies and then the weight of anthropogenic heat was evaluated according to the configuration. The results show that the integrated mitigation strategies in urban areas -i. e. increase vegetation and albedo on horizontal surfaces- has a great potential to mitigate urban warming, showing a more significant impact on low-density urban configuration. The contribution of anthropogenic heat mainly produced by motorized transport and air conditioning systems, is a crucial input data for the urban microclimate simulations. Its impact on the urban densification processes may cancel out the benefits derived by the application of the mitigation strategies considered.

AbstractThe ethylene glycol oxidation reaction on nickel and ruthenium modified palladium nanocatalysts was investigated with electrochemical, spectroelectrochemical, and chromatographic methods. These carbon‐supported materials, prepared by a revisited polyol approach, exhibited high activity towards the ethylene glycol electrooxidation in alkaline medium. Electrolysis coupled with high performance liquid chromatography/mass spectrometry (HPLC‐MS) and in situ Fourier transform infrared spectroscopy (FTIRS) measurements allowed us to determine the different compounds electrogenerated in the oxidative conversion of this two‐carbon molecule. High value‐added products such as oxalate, glyoxylate, and glycolate were identified in all electrolytic solutions, whereas glyoxylate was selectively formed at the Ru45@Pd55/C electrode surface. In situ FTIRS results also showed a decrease in the pH value in the thin layer near the electrode as a consequence of OH− consumption during the spectroelectrochemical experiments.

ABSTRACTPlant heme oxygenases (HOs) regulate biosynthesis of phytochrome which accounts for photo‐acceptance and ‐morphogenesis. Recent studies have demonstrated that plant HOs also regulate many other physiological processes including response to environmental stimuli. To elucidate the mechanism by which HOs regulate plant adaptation to heavy metal exposure, three novel HOs genes were isolated from rapeseed (Brassica napus) and their expression patterns were analysed. Alignment of deduced protein sequences revealed that the three BnHOs share high identity with their corresponding orthologos (AtHO1‐3) from Arabidopsis. To investigate whether the BnHO regulates plant tolerance to Hg toxicity, we constructed B. napus transgenic plants overexpressing BnHO‐1. Under Hg stress, the transgenic plants had 1.41–1.59 folds higher biomass than the untransformants. However, overexpression of BnHO‐1 resulted in less accumulation of Hg in some lines of transformants than in untransformants. The transgenic plants show lower abundance of reactive oxygen species and attenuated oxidative injury compared with the untransgenic plants. We cloned the promoter sequences of BnHO‐1 from B. napus. Analysis revealed that the 1119 bp fragment contains a conserved Cd responsive element (CdRE) and others responding to multiple environmental stimuli. Transient expression in tobacco leaves showed differential responses to heavy metals (Zn, Cu, Pb, Hg and Cd).

A range of optical fibre-based sensors for the measurement of ethanol, primarily in aqueous solution, have been developed and are reviewed here. The sensing approaches can be classified into four groups according to the measurement techniques used, namely absorption (or absorbance), external interferometric, internal fibre grating and plasmonic sensing. The sensors within these groupings can be compared in terms of their characteristic performance indicators, which include sensitivity, resolution and measurement range. Here, particular attention is paid to the potential application areas of these sensors as ethanol production is globally viewed as an important industrial activity. Potential industrial applications are highlighted in the context of the emergence of the internet of things (IoT), which is driving widespread utilization of these sensors in the commercially significant industrial and medical sectors. The review concludes with a summary of the current status and future prospects of optical fibre ethanol sensors for industrial use.