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Abstract The purpose of this paper is to investigate the influence of blending methods on the co-gasification of petroleum coke and lignite with CO 2 using a thermogravimetric system at 0.1 MPa. The weight loss curves, XRD analysis, SEM images, BET specific surface area, were investigated. It was observed that petroleum coke shows a low reactivity because of the graphitic carbon structure, low catalyst content and small specific surface area. Blending with lignite can get a high reactivity. The co-gasification reactivity was significantly influenced by blending methods. Wet grinding is much effective than dry grinding. Long grinding time made lignite show greater BET specific area. And the sample in long grinding time has more association chances between petroleum coke and AAEM species. The co-gasification reactivity increases linearly with a rise of BET specific area.

The effect of the combined application of nano-hydroxyapatite (NHAP) or nano-carbon black (NCB) on the phytoextraction of Pb by ryegrass was investigated as an enhanced remediation technique for soils by field-scale experiment. After the addition of 0.2% NHAP or NCB to the soil, temporal variation of the uptake of Pb in aboveground parts and roots were observed. Ryegrass shoot concentrations of Pb were lower with nano-materials application than without nano-materials for the first month. However, the shoot concentrations of Pb were significantly increased with nano-materials application, in particular NHAP groups. The ryegrass root concentrations of Pb were lower with nano-materials application for the first month. These results indicated that nano-materials had significant effects on stabilization of lead, especially at the beginning of the experiment. Along with the experimental proceeding, phytotoxicity was alleviated after the incorporation of nano-materials. The ryegrass biomass was significantly higher with nano-materials application. Consequently, the Pb phytoextraction potential of ryegrass significantly increased with nano-materials application compared to the gounps without nano-materials application. The total removal rates of soil Pb were higher after combined application of NHAP than NCB. NHAP is more suitable than NCB for in-situ remediation of Pb-contaminated soils. The ryegrass translocation factor exhibited a marked increase with time. It was thought that the major role of NHP and NBA might be to alleviate the Pb phytotoxicity and increase biomass of plants.

Schisandra Sphenanthera polysaccharides fractions (SSPs), namely SSP40, SSP60, and SSP80, were obtained by gradient precipitation with 40 %, 60 %, and 80 % (v/v) ethanol, respectively. It was found that gradient ethanol precipitation (GEP) significantly affected the physicochemical and structural characteristics of SSPs, including molecular weight, monosaccharide composition, and surface morphology. Compared to fractions SSP40 and SSP60, SSP80 was observed to have a lower molecular weight (22.58 kDa) and certain specific monosaccharide composition, such as lower glucose content and higher galactose, arabinose, rhamnose, and galacturonic acid content. Furthermore, the apparent porosity of the SSPs increased with increasing ethanol concentration in GEP. After fermentation at 37 °C for 48 h, fraction SSP80 prominently promoted the production of more short-chain fatty acids (SCFAs), increasing from an initial 1.39 ± 0.08 to 26.75 ± 0.54 mmol/L. The SSP fraction types extracted by GEP greatly affected the modulation of the intestinal microflora at different levels. The SSP80 fraction with excellent structure demonstrated the best ability to modulate the intestinal microflora by increasing the relative abundance of Bacteroides, Faecalibacterium and Dialister and decreasing the relative abundance of Escherichia-Shigella. The remarkable differences in modulating the intestinal microflora confirmed the importance of carefully selecting GEP to fraction SSPs that promote health.

Poria cocos (Schw.) Wolf, an important medicinal and food fungus, is well known in East Asia. Due to growing market demand, long cultivation period, and consumption of pine trunk during cultivation, developing alternative methods for producing P. cocos and/or its active components is of interest. In the present study, the effects of different culture methods on biomass and accumulation of four triterpenoids were investigated. The ethanol extract of fermented mycelium (EFM) was orally administered to rats. Urine output and concentrations of electrolytes (Na+, K+, and Cl-) were measured. Our results showed that mycelia grew better under continuous shaking culture condition (7.5 g DW·L-1), and higher triterpenoid levels were accumulated in two-stage culture (112 mg·L-1, 2.03%). The optimal starting time of static culture for triterpenoid yield was 4th d after shaking culture. Single administration of middle and high dose of EFM significantly increased urine output, Na+ and Cl- excretion, and Na+/K+ ratio. These results suggested that ethanol extract of cultured mycelia showed significant diuretic activity in rats and two-stage culture of P. cocos could be an alternative way to produce mycelia and triterpenoids.

Abstract Fresh green asparagus is prone to lignify after harvest due to its high respiration rate and secretion of secondary metabolites regulated by enzymes generated during storage. In this work, a dense hemicellulose-based coating containing hemicellulose, cellulose nanofibers, and montmorillonite (MMT) was prepared and used as a coating to reduce the respiration rate of green asparagus, with which the shelf life of green asparagus was prolonged from 5 days to 7 days. Alkyl ketene dimer (AKD) was used as a hydrophobizer and a crosslinking agent to reduce humidity sensitivity by introducing hydrophobic fatty acid chains to nanoparticles for increased structural stability and respiratory barrier property hemicellulose-based film in high humidity conditions. Our study proved that AKD modified coating with nature-derived nanomaterials could effectively increase respiratory barrier property, slow down the secretion of lignification-involved enzymes, and regulating the conversion of phenolic compounds to the lignin monomers.

Abstract This paper summarises studies undertaken towards the development of a laminated composite aluminium/hexadecane phase change material (PCM) drywall based on previous analytical work. The study also covered the selection and testing of various types of adhesive materials and identified Polyvinyl acetate (PVA) material as a suitable bonding material. For the purpose of comparison pure hexadecane and composite aluminium/hexadecane samples were developed and tested. The test results revealed faster thermal response by the aluminium/hexadecane sample regarding the rate of heat flux and also achieved about 10% and 15% heat transfer enhancements during the charging and discharging periods respectively. Its measured effective thermal conductivity also increased remarkably to 1.25 W/mK as compared with 0.15 W/mK for pure hexadecane. However there was about 5% less total cumulative thermal energy discharged at the end of the test which indicates that its effective thermal capacity was reduced by the presence of the aluminium particles. The study has shown that some of the scientific and technical barriers associated with the development of laminated composite PCM drywall systems can be overcome but further investigations of effects of adhesive materials are needed.

Abstract Egg yolk-derived P and N dual doped nano carbon capsules (PNCCs) have been synthesized and used as lithium ion battery anodes. The application of egg yolk as the carbon source is a new and environmental-friendly approach for biomass recycling. The reversible capacity of half cells made of PNCCs is as high as ~770 mA h g−1 at a current density of 0.5 A g−1 with considerable rate capacity and cycling stability. PNCCs show a capsule-like structure, which provide extra edges and active sites for lithium intercalation. The heteroatom doping also introduce defects and disorder, which increases the electrochemical activity and creates more active sites for lithium insertion.

This study aims to introduce, conceptualize, and design a novel biomass/gasification-driven hybrid energy configuration. The proposed hybrid configuration has four subsystems: reformer solid oxide fuel cell (RSOFC), biomass/gasification, homogeneous charge compression ignition engine (HCCIE) plus waste heat recovery system (WHRS). RSOFC and HCCIE systems are embedded to generate electric energy. The syngas required for these two subsystems is captured from the biomass/gasification subsystem. In addition to generating electrical energy, fuel cell is responsible for providing combustible fuel to the HCCIE subsystem. The embedded engine in the system can improve the proposed configuration efficiency by increasing the rate of electrical energy production. In addition, the dissipated heat of fuel cell and engine subsystems is recovered by WHRS. The proposed energy configuration is evaluated and discussed from energetically, exergetically and exergoeconomic and environmental aspects to obtain a comprehensive feasibility study of the plant. The offered hybrid design has new component's structure and relationships that have not been reported in the publications. The analysis indicated that the proposed hybrid configuration is capable of generating approximately 1100 kW and 366.3 W of electric and thermal power, respectively, with the overall energetic and exergetic efficiencies of 69.4% and 52.1%. Exergoeconomic analysis results revealed that the specific fuel cost of the total proposed configuration was approximately 1.96 USD per GJ. In addition, compared to a coal and petroleum oil-based power generation plants, the proposed hybrid configuration can have approximately 2.75-fold and 97.7% lower CO2 emissions, sequentially. Besides, the proposed system can rival other similar biomass-driven designs.