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The atmosphere concentration of CO2 is steadily increasing and causing climate change. To achieve the Paris 1.5 or 2 oC target, negative emissions technologies must be deployed in addition to reducing carbon emissions. The ocean is a large carbon sink but the potential of marine primary producers to contribute to carbon neutrality remains unclear. Here we review the alterations to carbon capture and sequestration of marine primary producers (including traditional ‘blue carbon’ plants, microalgae, and macroalgae) in the Anthropocene, and, for the first time, assess and compare the potential of various marine primary producers to carbon neutrality and climate change mitigation via biogeoengineering approaches. The contributions of marine primary producers to carbon sequestration have been decreasing in the Anthropocene due to the decrease in biomass driven by direct anthropogenic activities and climate change. The potential of blue carbon plants (mangroves, saltmarshes, and seagrasses) is limited by the available areas for their revegetation. Microalgae appear to have a large potential due to their ubiquity but how to enhance their carbon sequestration efficiency is very complex and uncertain. On the other hand, macroalgae can play an essential role in mitigating climate change through extensive offshore cultivation due to higher carbon sequestration capacity and substantial available areas. This approach seems both technically and economically feasible due to the development of offshore aquaculture and a well-established market for macroalgal products. Synthesis and applications: This paper provides new insights and suggests promising directions for utilizing marine primary producers to achieve the Paris temperature target. We propose that macroalgae cultivation can play an essential role in attaining carbon neutrality and climate change mitigation, although its ecological impacts need to be assessed further. To calculate the parameters presented in Table 1, the relevant keywords "mangroves, salt marshes, macroalgae, microalgae, global area, net primary productivity, CO2 sequestration" were searched through the ISI Web of Science and Google Scholar in July 2021. Recent data published after 2010 were collected and used since area and productivity of plants change with decade. For data with limited availability, such as net primary productivity (NPP) of seagrasses and global area and NPP of wild macroalgae, data collection was extended back to 1980. Total NPP and CO2 sequestration for mangroves, salt marshes, seagrasses and wild macroalgae were obtained by the multiplication of area and NPP/CO2 sequestration density and subjected to error propagation analysis. Data were expressed as means ± standard error.

Figure 1-4 data for "Anaconda-shaped Spiral Multi-layered Triboelectric Nanogenerators with Ultra-High Space Efficiency for Wave Energy Harvesting" Figure 1-4 data for "Anaconda-shaped Spiral Multi-layered Triboelectric Nanogenerators with Ultra-High Space Efficiency for Wave Energy Harvesting"

By using a liquid desiccant ventilation system for dehumidification and an air-handling unit for cooling, the liquid desiccant cooling system (LDCS) system became a promising alternative for traditional technology. Solar thermal energy is suitable to deal with the heat requirement of LDCS in buildings, especially in the areas with abundant solar radiation. The energy saving of solar-assisted liquid desiccant air-conditioning system is significantly affected by various operation conditions, and multi-parameter optimization was necessary to improve the system applicability. In this paper, we investigated the impact of five main parameters on the system performance via self-developed system modelling, including the solution mass flow rate, concentration, cooling tower flow rate, and solar water flow rate and installation area of solar collector. A typical commercial building in Hong Kong was selected as a case study, which air-conditioning load was obtained by Energy-plus. The results indicated that the installation area of solar collector showed the greatest impact, and the effect of heating water flow rate was also important. The effect of desiccant flow rate was significant, but the influence of solution concentration was slight. Then, the multi-parameter optimization was conducted for obtaining a maximum annual electricity saving rate based on the Multi-Population Genetic Algorithm. The optimized installation area of solar collector was 72 m2, and the heating water flow rate was 0.66 kg/s. The optimized solution flow rate was 0.17 kg/s. The required cooling water flow rate was around 0.8 kg/s.

Large-scale reforestation can potentially bring both benefits and risks to the water cycle, which needs to be better quantified under future climates to inform reforestation decisions. We identified 477 water-insecure basins worldwide accounting for 44.6% (380.2 Mha) of the global reforestation potential. As many of these basins are in the Asia-Pacific, we used regional coupled land-climate modelling for the period 2041–2070 to reveal that reforestation increases evapotranspiration and precipitation for most water-insecure regions over the Asia-Pacific. This resulted in a statistically significant increase in water yield (p < 0.05) for the Loess Plateau-North China Plain, Yangtze Plain, Southeast China and Irrawaddy regions. Precipitation feedback was influenced by the degree of initial moisture limitation affecting soil moisture response and thus evapotranspiration, as well as precipitation advection from other reforested regions and moisture transport away from the local region. Reforestation also reduces the probability of extremely dry months in most of the water-insecure regions. However, some regions experience non-significant declines in net water yield due to heightened evapotranspiration outstripping increases in precipitation, or declines in soil moisture and advected precipitation. This dataset contains raw data outputs for Teo et al. (2022), Global Change Biology. Please see the published paper for further details on methods. For enquiries, please contact the corresponding authors: hcteo [at] u.nus.edu or lianpinkoh [at] nus.edu.sg.  Shapefiles can be opened with any GIS program such as ArcMap or QGIS. CSV files can be opened with any spreadsheet program such as Microsoft Excel or OpenOffice.

Owing to the storage and transportation problems of hydrogen fuel, exploring new methods of the realtime hydrogen production from ammonia becomes attractive. In this paper, non-thermal arc plasma (NTAP) combining with NiO/Al2O3 catalyst is developed to produce hydrogen from ammonia with high efficiency and large scale. The effects of ammonia gas flow rate and discharge power on the gas temperature, electron density, the hydrogen production rate, and energy efficiency were investigated. Experimental results show that the optical emission spectrum of NTAP working with pure ammonia medium was dominated by the atom spectrum of Hα, Hβ, and molecular spectrum of NH component. Under the optimum experimental condition of plasma discharge, the highest energy efficiency of hydrogen production reached 783.4 L/kW·h at NH3 gas flow rate of 30 SLM. When the catalyst was added, and heated by the NTAP simultaneously, the energy efficiency further increased to 1080.0 L/kW·h. Owing to the storage and transportation problems of hydrogen fuel, exploring new methods of the realtime hydrogen production from ammonia becomes attractive. In this paper, non-thermal arc plasma (NTAP) combining with NiO/Al2O3 catalyst is developed to produce hydrogen from ammonia with high efficiency and large scale. The effects of ammonia gas flow rate and discharge power on the gas temperature, electron density, the hydrogen production rate, and energy efficiency were investigated. Experimental results show that the optical emission spectrum of NTAP working with pure ammonia medium was dominated by the atom spectrum of Hα, Hβ, and molecular spectrum of NH component. Under the optimum experimental condition of plasma discharge, the highest energy efficiency of hydrogen production reached 783.4 L/kW·h at NH3 gas flow rate of 30 SLM. When the catalyst was added, and heated by the NTAP simultaneously, the energy efficiency further increased to 1080.0 L/kW·h.

Positive forced aeration is widely used in industrial composting plants to supply sufficient oxygen, accelerating compost maturity. However, this technology results in significant gaseous emission, especially NH3 and GHGs emissions. To reduce gaseous emissions and investigate aeration efficiency, negative pressure aeration was used during cattle manure þ corn stalk composting in 50 L-scale reactors. Composting with negative pressure aeration at three different flow rates (0.25, 0.50 and 0.75 L/min/kg dry weight, named Negative-L, Negative-M and Negative-H treatments) were conducted. Treatment with positive pressure aeration was set as a control (Positive-M, with flow rate at 0.50 L/min/kg dry weight). The results showed that negative pressure aeration changed the temporal distribution of oxygen and temperature. With the same flow rate, the Negative-M treatment maintained a longer thermophilic period, accelerating organic matter degradation (47.6% in treatment Negative-M and 41.4% in Positive-M) and the maturity of feedstock (germination index was 105.9% in Negative-M and 58.5% in Positive-M). Ammonia emissions were significantly reduced by composting with negative pressure aeration. During composting, 36.7%, 15.8%, 16.8% and 16.0% of the initial total nitrogen was lost via NH3 volatilizations in the Positive-M, Negative-L, Negative-M and Negative-H treatments, respectively, indicating NH3 emissions were reduced by ~55% compared to the positive pressure aeration treatment. Even though both CH4 and N2O emission were greater from the negative pressure aeration treatments, the global warming potential was significantly reduced in treatments with negative pressure aeration because of the lower NH3 emission (an indirect N2O source). This indicates the benefit of NH3 emission mitigation was larger than the increase in CH4 and N2O emissions. Positive forced aeration is widely used in industrial composting plants to supply sufficient oxygen, accelerating compost maturity. However, this technology results in significant gaseous emission, especially NH3 and GHGs emissions. To reduce gaseous emissions and investigate aeration efficiency, negative pressure aeration was used during cattle manure þ corn stalk composting in 50 L-scale reactors. Composting with negative pressure aeration at three different flow rates (0.25, 0.50 and 0.75 L/min/kg dry weight, named Negative-L, Negative-M and Negative-H treatments) were conducted. Treatment with positive pressure aeration was set as a control (Positive-M, with flow rate at 0.50 L/min/kg dry weight). The results showed that negative pressure aeration changed the temporal distribution of oxygen and temperature. With the same flow rate, the Negative-M treatment maintained a longer thermophilic period, accelerating organic matter degradation (47.6% in treatment Negative-M and 41.4% in Positive-M) and the maturity of feedstock (germination index was 105.9% in Negative-M and 58.5% in Positive-M). Ammonia emissions were significantly reduced by composting with negative pressure aeration. During composting, 36.7%, 15.8%, 16.8% and 16.0% of the initial total nitrogen was lost via NH3 volatilizations in the Positive-M, Negative-L, Negative-M and Negative-H treatments, respectively, indicating NH3 emissions were reduced by ~55% compared to the positive pressure aeration treatment. Even though both CH4 and N2O emission were greater from the negative pressure aeration treatments, the global warming potential was significantly reduced in treatments with negative pressure aeration because of the lower NH3 emission (an indirect N2O source). This indicates the benefit of NH3 emission mitigation was larger than the increase in CH4 and N2O emissions.

Supplementary material for the publication " Agricultural biogas plants as a hub to foster circular economy and bioenergy: An assessment using material substance and energy flow analysis" Burg, V., b, Rolli, C., Schnorf, V., Scharfy, D., Anspach, V., Bowman, G. Today's agro-food system is typically based on linear fluxes (e.g. mineral fertilizers importation), when a circular approach should be privileged. The production of biogas as a renewable energy source and digestate, used as an organic fertilizer, is essential for the circular economy in the agricultural sector. This study investigates the current utilization of wet biomass in agricultural anaerobic digestion plants in Switzerland in terms of mass, nutrients, and energy flows, to see how biomass use contributes to circular economy and climate change mitigation through the substitution effect of mineral fertilizers and fossil fuels. We quantify the system and its benefits in details and examine future developments of agricultural biogas plants using different scenarios. Our results demonstrate that agricultural anaerobic digestion could be largely increased, as it could provide ten times more biogas by 2050, while saving significant amounts of mineral fertilizer and GHG emissions.

The dataset "RoRCC" consists of simulation-based results on climate change impacts on Alpine RoR power production; it is based on 21 Swiss RoR power plants, with a total production of 5.9 TWh a-1. The dataset contains the following information: 1) metadata on the RoR power plants under consideration, 2) annual and seasonal production potential scenarios under into three emission scenarios (RCP2.6, RCP4.5, RCP8.5) and three future periods (T1: 2020–2049, T2: 2045–2074, T3: 2070–2099), 3) annual and seasonal streamflow scenarios, 4) annual and seasonal production loss due to environmental flow requirements, 5) annual and seasonal the technical increase potential (via design discharge optimisation) and 6) annual and seasonal changes in the hydrological cycle.

- EddyPro v6 and v7 for flux calculations [https://www.licor.com/env/products/eddy_covariance/eddypro] - bico for the conversion of binary raw data files to ASCII (2013-2016, 2020-2022) [https://gitlab.ethz.ch/flux/bico] - fluxrun for the flux calculation using EddyPro (2013-2016, 2020-2022) [https://gitlab.ethz.ch/flux/fluxrun] - Various versions of FCT (flux calculation using EddyPro) were used for years 1997-2004 and 2017-2019 [https://gitlab.ethz.ch/holukas/fct-flux-calculation-tool] - scop v0.1 (self-heating correction for open-path IRGAs) for the self-heating correction of IRGA75 fluxes [https://gitlab.ethz.ch/holukas/scop] - diive v0.21.0 (legacy version) for file merging, quality control, storage correction, outlier removal [https://gitlab.ethz.ch/diive/diive-legacy/-/tree/v0.21.0] - ReddyProc v1.2.2 for application of the constant ustar threshold, MDS gap-filliing and partitioning, in R Studio v1.3.959 [https://cran.r-project.org/web/packages/REddyProc/index.html]

Structural, optoelectronic, photovoltaic, and supplementary characterization data for “Benzylammonium-Mediated Formamidinium Lead Iodide Perovskite Phase Stabilization for Photovoltaics”, DOI:10.1002/adfm.202101163. Figure_2_XRD.zip: Data described in Figure 2 (XRD patterns) as Origin (.opj) software file. Figure_3_NMR_data.zip: Data described in Figure 3 (NMR spectra) in the file structure of the TopSpin software, which is available from Bruker. Figure_4_spectra.zip: Data described in Figure 4 (UV-vis absorption, PL and IPCE spectra) as Origin (.opj) software files. Figure_5_PV.zip: Data described in Figure 5 (photovoltaic characterization) as Origin (.opj) software files. Figure_6_spectra.zip: Data described in Figure 6 (PLQY and TRPL) as Origin (.opj) and *.csv files. Figure_7_stability.zip: Data described in Figure 7 (stability analysis) as Origin (.opj) software files. Figure_SI.zip: Data described in the Supporting Information Figures S1, S2, S3, S5, and S6 (XRD data, reciprocal space maps, radial profiles of q-maps, UV-vis absorption spectra, PL spectra, and additional photovoltaic characterization) as Origin (.opj), text (.txt), and image (.tiff) files.