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Abstract. The impact of multiphase reactions involving nitrogen dioxide (NO2) and aromatic compounds was simulated in this study. A mechanism (CAPRAM 2.4, MODAC Mechanism) was applied for the aqueous phase reactions, whereas RACM was applied for the gas phase chemistry. Liquid droplets were considered as monodispersed with a mean radius of 0.1 µm and a liquid content (LC) of 50 µg m-3. The multiphase mechanism has been further extended to the chemistry of aromatics, i.e. reactions involving benzene, toluene, xylene, phenol and cresol have been added. In addition, reaction of NO2 with dissociated hydroxyl substituted aromatic compounds has also been implemented. These reactions proceed through charge exchange leading to nitrite ions and therefore to nitrous acid formation. The strength of this source was explored under urban polluted conditions. It was shown that it may increase gas phase HONO levels under some conditions and that the extent of this effect is strongly pH dependent. Especially under moderate acidic conditions (i.e. pH above 4) this source may represent more than 75% of the total HONO/NO2 - production rate, but this contribution drops down close to zero in acidic droplets (as those often encountered in urban environments).

The variability of large scale wind power generation at high penetration levels has a significant impact on the secure and economic operation of onshore power systems. Grid bottlenecks, high gradients and wasting of wind energy can be avoided using local Energy Storage Systems (ESS) with dedicated power and capacity. The storage type considered in this study is an adiabatic compressed air energy storage (ACAES). This paper presents a comparison of different ESS applications aiming both to increase the profit of the power plant operator in selling the electricity into the electricity market and to support the intermittent electricity production of the wind park. This contribution presents the investigation methodology and discusses computation results for a region in Germany.

High reactivity coke is beneficial for achieving low carbon emission blast furnace ironmaking. Therefore, the preparation of highly reactive ferro-coke has aroused widespread attention. However, the effects of the particle size of iron ore on the pyrolysis behaviour of a coal-iron ore briquette are still unclear. In this study, the effect of three particle sizes (0.50–1.00 mm, 0.25–0.50 mm and <0.74 mm) of iron ore on the thermal and kinetic behaviours of coal-iron ore briquettes were investigated by non-isothermal kinetic analysis. The results showed that the synergistic effect of iron ore and coal during coking mainly occurred during the later reaction stage (850–1100 °C) and smaller particle sizes of iron ore have a stronger synergistic effect. The addition of iron ore had little effect on T0 (the initial temperature) and Tp (the temperature at the maximum conversion rate) of briquette pyrolysis, however itgreatly affected the conversion rate and Tf (the final temperature) of the briquettes. T0 decreased with the decrease of iron ore particle sizes, while Tp and Tf showed opposite trends. After adding iron ore into the coal briquette, the reaction kinetics at all stages of the coal-iron ore briquettes changed. The weighted apparent activation energy of the caking coal (JM) briquette was 35.532 kJ/mol, which is lower than that of the coal-iron ore briquettes (38.703–55.627 kJ/mol). In addition, the weighted apparent activation energy gradually increased with decreasing iron ore particle sizes.

Abstract: COVID-19, caused by the SARS-CoV-2 virus, has been expanding. SARS-CoV caused an outbreak in early 2000, while MERS-CoV had a similar expansion of illness in early 2010. Nanotechnology has been employed for nasal delivery of drugs to conquer a variety of challenges that emerge during mucosal administration. The role of nanotechnology is highly relevant to counter this “virus” nano enemy. This technique directs the safe and effective distribution of accessible therapeutic choices using tailored nanocarriers, as well as the interruption of virion assembly, by preventing the early contact of viral spike glycoprotein with host cell surface receptors. This study summarises what we know about earlier SARS-CoV and MERS-CoV illnesses, with the goal of better understanding the recently discovered SARS-CoV-2 virus. It also explains the progress made so far in creating COVID-19 vaccines/ treatments using existing methods. Furthermore, we studied nanotechnology- based vaccinations and therapeutic medications that are now undergoing clinical trials and other alternatives.

Abstract A comprehensive thermochemical analysis of the equilibrium gaseous product composition resulting from burning chromium, hydrocarbon, and chlorohydrocarbon polymers in air at 101 kPa is presented. Calculations have been made over the range φ = 0.25–2.50 at adiabatic flame temperatures from 600 to 2100 K. The main chromium-containing species formed are CrO 3 , CrO 2 , CrO 2 Cl, and CrO 2 (OH). The yield of Cr(6+) derivatives reaches a maximum of 77% at 1650 K and φ = 0.25, mainly in the form of CrO 3 (g). The yield of CrO, CrOCl, CrOCl 2 , CrO 2 Cl 2 , CrOOH, and CrO 2 (OH) 2 does not exceed 0.1% of the initial chromium content, and that of other chromium-containing species is less than 10 −2 mol%. A reaction scheme is constructed on the basis of the data obtained. It includes reactions of the secondary oxidants CO 2 , H 2 O, HCl, OH, and O, as well as the reducing agents CO, H 2 , and H.

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Abstract Wind power technology is one of the cleanest electricity generation technologies that are expected to have a substantial share in the future electricity mix. Nonetheless, the expected increase in the market share of wind technology has led to an increasing concern of the availability, production capacity and geographical concentration of the metals required for the technology, especially the rear earth elements (REE) neodymium (Nd) and the far less abundant dysprosium (Dy), and the impacts associated with their production. Moreover, Nd and Dy are coproduced with other rare earth metals mainly from iron, titanium, zirconium, and thorium deposits. Consequently, an increase in the demand for Nd and Dy in wind power technology and in their traditional applications may lead to an increase in the production of the host metals and other companion REE, with possible implications on their supply and demand. In this regard, we have used a dynamic material flow and stock model to study the impacts of the increasing demand for Nd and Dy on the supply and demand of the host metals and other companion REE. In one scenario, when the supply of Dy is covered by all current and expected producing deposits, the increase in the demand for Dy leads to an oversupply of 255 Gg of total REE and an oversupply of the coproduced REE Nd, La, Ce and Y. In the second and third scenarios, however, when the supply of Dy is covered by critical REE rich deposits or Dy rich deposits, the increase in Dy demand results in an oversupply of Ce and Y only, while the demand for Nd and La exceeds their supply. In the case of an oversupply of REEs, the environmental impacts associated with the REEs production should be allocated to Dy and consequently to the technologies that utilize the metal. The results also show that very large quantities of thorium will be co-produced as a result of the demand for Dy. The thorium would need to be carefully disposed of, or significant thorium applications would need to be found.