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Abstract Hydrothermal treatment (HT) is one of the efficient approaches for upgrading municipal solid waste (MSW). In the present study, emission characteristics of polycyclic aromatic hydrocarbons (PAHs) from hydrothermally treated municipal solid waste (H-MSW) combustion alone and H-MSW/coal co-combustion were investigated at different temperatures. The results showed that for all fuel combustion, the majority of PAHs were 3- or 4-ring PAHs. In addition, flue gas had the highest yields of PAHs followed by fly ash and bottom ash, while the ring number of dominated PAHs in fly ash was higher than those in flue gas and bottom ash. Compared to MSW, H-MSW combustion generated less PAHs at the value of 1131.95–7649.24 μg/g. The blending of H-MSW and coal reduced total PAH emissions and positive interactions were observed between H-MSW and coal during co-combustion. The toxicity equivalent quantity (TEQ) values of the PAHs from combustion were in the order MSW > H-MSW > H-MSW/coal, which was consistent with the total PAH emissions. The present study illustrated that significant reduction of PAH emissions and toxicity from combustion could be achieved by HT and the blending of H-MSW and coal.

China’s steel industry is an energy-intensive sector. Synergistic reduction of emissions of CO2 and air pollutants (SO2, NOx, and PM2.5) in the steel industry has an important practical significance for climate change and air pollution control. According to the CO2 emission reduction intensity targets (CERO) and air pollutant emission targets (PERO) for 2020 and 2030, 28 types of energy-saving and emission reduction technologies (20 types of carbon reduction technology and eight types of air pollution end-of-pipe technology) were selected for examination, and a two-stage dynamic optimization model with collaborative implementation of PERO and CERO was built to assess the near future (2015–2020) and long-term (2020–2030) implementation plans for synergistic emissions reduction of CO2 and air pollutants. The results show that in the near future, the implementation of PERO will have a greater synergistic effect on CO2 emission reduction. CO2 emission reduction under PERO in 2020 will be 97 million tons (Mt) higher than that of CERO, an increase of nearly 26%. However, the effects of implementing CERO are better in the long run. Under CERO, the emission reductions of SO2, NOx, and PM2.5 in 2030 are 2.44 Mt, 1.47 Mt, and 0.86 Mt, respectively, and 7%, 4%, and 5% higher than the implementation of PERO. As far as marginal abatement cost is concerned, in the near future, the marginal abatement costs of CO2 and air pollutant equivalents are 1.06 yuan/kgCO2 and 133 yuan/kg pollution equivalent (pe) under PERO, which are 23% and 11% lower than that of CERO, while in the long run, the marginal abatement costs of CO2 and pollutant equivalents under CERO are 0.025 yuan/kgCO2 and 2.73 yuan/kgpe, about 96% and 95% lower than that of PERO.

In today’s increasingly competitive coffee industry, the point of running a good coffee shop is no longer to run a coffee and beverage shop simply, but to focus on the quality of service and the value that customers feel as a result. Previous studies have mainly discussed the customer satisfaction and behavioral intention of restaurants, while few studies have explored the influencing factors of customer satisfaction and behavioral intention of chain coffee shops. Given that the perceived service quality theory and DINESERV model can effectively predict customer satisfaction and behavioral intention, this study took 385 consumers in the first Starbucks Reserve flagship store in China as survey objects. SmartPLS 3.0 software was used to explore the relationship among respondents’ perceived service quality, customer perceived value, satisfaction, and behavioral intention. The results show that service quality has a partially significant positive effect on perceived value. Perceived service quality and customers’ perceived value both have significant positive effects on satisfaction. Customers’ satisfaction has a significant positive effect on their behavioral intention. These results indicate that enterprises should strengthen the emotional bond between consumers and enterprises and improve the reliability, assurance, and empathy of perceived service quality to create a better emotional resonance between consumers and the Starbucks brand to improve customer satisfaction. At the same time, it should also promote the symbolic perceived value of Chinese consumers to Starbucks to realize the sustainable development of coffee-shop operation and consumer repurchase. This study expands the research on the service quality, perceived value, and behavioral intention of coffee chain enterprises in the context of non-habitual coffee-drinking countries. Moreover, it provides case support for the operation and research of regional cultural consumption habits of international catering chain enterprises.

“Low expectation of success” is proposed as a factor in relation to problem behavior in the comprehensive theoretical model of problem behavior (CTMPB). Based on the framework of CTMPB, this study aimed to further examine the association between confidence in the future (including parental confidence in the adolescent future and adolescent self-confidence in the future in this study) and problem behavior. A nationwide representative sample data from the China Education Panel Survey (CEPS) were used in this study. A total of 8328 middle school students and their parents were included. Among the students, 4081 (49.0%) were boys, the mean age was 14.53 years (SD = 0.70); among the parents, 3908 (46.9%) were male, the mean age was 41.15 years (SD = 5.14). The results reveal that parental confidence in adolescent future (PCAF) can play a role in adolescent problem behavior through adolescent perceived parental confidence in adolescent future (APPCAF) and adolescent self-confidence in the future (ASF). Low levels of both PCAF and ASF are vulnerability risk factors in adolescent problem behavior. Lowering PCAF and ASF might increase the likelihood of engaging in problem behavior. However, this study was based on cross-sectional data only and is required to be supported by further experimental or longitudinal studies.

Carbon capture and utilization (CCU) is a field of key emerging technologies. CCU can support the economy to decrease the dependency on fossil carbon raw materials, to stabilize electricity grids and markets with respect to a growing share of fluctuating renewable energy. Furthermore, it can contribute to mitigate anthropogenic CO2 emissions. The German Federal Ministry of Education and Research has provided substantial financial support for research and development projects, stimulating research, development, and innovations in the field of CO2 utilization. This review provides an overview over the most relevant funding measures in this field. Examples of successful projects demonstrate that CCU technologies are already economically viable or technologically ready for industrial application. CCU technologies as elements of a future "green economy" can contribute to reach the ambitious German sustainability targets with regard to climate protection as well as raw material productivity.

Robust mitigation options will play significant role in achieving the target of limiting global change to below 1.5 °C above pre-industrial levels by 2100. To support cooperation for mitigation development, we establish a real options-based model to evaluate the rational decisions of exercising the abandon option for carbon capture and storage-enhanced oil recovery (CCS-EOR) projects under oil market and geological uncertainties. Three possible cooperative mechanisms (fixed carbon dioxide (CO2) price, oil-indexed CO2 price, and joint venture contracts) among CO2-EOR stakeholders are evaluated. The results show that the conflicts in profit maximization targets for different stakeholders in cooperative mitigation are to a great extent unable to be avoided. A joint venture business model is preferred in cooperative mitigation as it can effectively weaken such conflicts. And it is more reasonable to provide incentives to the downstream of the CO2-EOR chain than compensating the adoption cost of carbon capture technologies in the upstream. From a global perspective, the inefficient cooperation can be a main barrier that hinders the development of deep-cutting options. Global mitigation strategies should not only focus on promoting technology progress but also the design of innovative business models to balance the benefits among stakeholders. A joint venture business model is recommended in both the developed and developing countries for seizing the early mitigation opportunities.

Abstract Liquid fuels are likely to remain the main energy source in long-range transportation and aviation for several decades. To reduce our dependence on fossil fuels, liquid biofuels can be blended to fossil fuels – or used purely. In this paper, coconut methyl ester, standard diesel fuel (EN590:2017), and their blends were investigated in 25 V/V% steps. A novel turbulent combustion chamber was developed to facilitate combustion in a large volume that leads to ultra-low emissions. The combustion power of the swirl burner was 13.3 kW, and the air-to-fuel equivalence ratio was 1.25. Two parameters, combustion air preheating temperature and atomizing air pressure were adjusted in the range of 150–350 °C and 0.3–0.9 bar, respectively. Both straight and lifted flames were observed. The closed, atmospheric combustion chamber resulted in CO emission below 10 ppm in the majority of the cases. NO emission varied between 60 and 183 ppm at straight flame cases and decreased below 20 ppm when the flame was lifted since the combustion occurred in a large volume. This operation mode fulfills the 2015/2193/EU directive for gas combustion by 25%, which is twice as strict as liquid fuel combustion regulations. The 90% NO emission reduction was also concluded when compared to a lean premixed prevaporized burner under similar conditions. This favorable operation mode was named as Mixture Temperature-Controlled (MTC) Combustion. The chemiluminescent emission of lifted flames was also low, however, the OH* emission of straight flames was clearly observable and followed the trends of NO emission. The MTC mode may lead to significantly decreased pollutant emission of steady-operating devices like boilers, furnaces, and both aviation and industrial gas turbines, meaning an outstanding contribution to more environmentally friendly technologies.

Abstract Catalyst layer structural changes in polymer electrolyte membrane fuel cells have significant impact on the cell performance and durability. In this study, ex-situ experiments are designed to investigate the effect of humidity and/or thermal cycles on the structural changes of catalyst layers. The relative humidity and temperature are controlled by an environmental chamber and the catalyst layer structure is characterized by scanning electron microscopy and optical microscopy. The experimental results indicate that crack growth and development, catalyst agglomerate detachment, and surface bulges are the main structural changes of the catalyst layers. Applying relative humidity and thermal cycling simultaneously causes the most significant crack growth, while applying thermal cycling alone causes no appreciable changes. This indicates that the absolute humidity is the key parameter for the crack growth. Through cyclic voltammetry analysis, it is shown that the electrochemical active surface area decreases from 64.1 m2 g−1 to 49.1 m2 g−1 after 500 combined relative humidity and thermal cycles. Analyses of electrochemical impedance spectroscopy show that the charge transfer resistance and ohmic resistance increase significantly after 500 combined relative humidity and thermal cycles, causing the cell performance degradation.