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A new environmental ban has forced the restructure of open dumps in China since 1 July 2011. A technical process was established in this study that is feasible for the upgrade of open dumps through restructuring. The feasibility of restructuring and the benefit of greenhouse gas emission reductions were assessed according to field surveys of five landfills and four dumps in Nanjing. The results showed that the daily processing capacities of the existing landfills have been unable to meet the growth of municipal solid waste (MSW), making restructuring of the landfills imperative. According to an assessment of the technical process, only four sites in Nanjing were suitable for upgrading. Restructuring the Jiaozishan landfill effectively reduced the leachate generation rate by 5.84% under its scale when expanded by 60.7% in 2015. CO2 emissions were reduced by approximately 55,000–86,000 tons per year, in which biogas power generation replaced fossil fuels Fossil fuels accounted for the largest proportion, up to 45,000–60,000 tons. Photovoltaic power generation on the overlying land has not only reduced CO2 emissions to 26,000–30,000 tons per year but has also brought in continuing income from the sale of electricity. The funds are essential for developing countries such as China, which lack long-term financial support for landfill management after closure.

In this study, we investigated the influence of overall financial development and its components on energy consumption using the panel data of 120 countries and the generalized method of moments (GMM). By dividing the sample into developed and developing countries, we further examined the national differences of the impact of financial development on energy consumption. The empirical results indicate that the overall financial development significantly positively impacts energy consumption from a worldwide perspective, and its two components (financial institution and the financial market) have the same effect. The analysis of national differences indicates that the financial development also positively impacts energy consumption in developing countries but with no obvious effect in developed countries. The results also suggest that financial development cannot be used to restrain the increase in energy consumption from the global perspective, and policymakers in developing countries must balance the relationship between the development of the financial sector and energy consumption.

Upwelling processes bring nutrient-rich waters from the deep ocean to the surface. Areas of upwelling are often associated with high productivity, offering great economic value in terms of fisheries. The sensitivity of spring/summer-time coastal upwelling systems to climate change has recently received a lot of attention. Several studies have suggested that their intensity may increase in the future while other authors have shown decreasing intensity in their equatorward portions. Yet, recent observations do not show robust evidence of this intensification. The Senegalo-Mauritanian upwelling system (SMUS) located at the southern edge of the north Atlantic system (12°N–20°N) and most active in winter/spring has been largely excluded from these studies. Here, the seasonal cycle of the SMUS and its response to climate change is investigated in the database of the Coupled Models Inter comparison Project Phase 5 (CMIP5). Upwelling magnitude and surface signature are characterized by several sea surface temperature and wind stress indices. We highlight the ability of the climate models to reproduce the system, as well as their biases. The simulations suggest that the intensity of the SMUS winter/spring upwelling will moderately decrease in the future, primarily because of a reduction of the wind forcing linked to a northward shift of Azores anticyclone and a more regional modulation of the low pressures found over Northwest Africa. The implications of such an upwelling reduction on the ecosystems and local communities exploiting them remains very uncertain.

Abstract In this study, crude cellulose derived from cornstalk, after bleaching, was used as raw material for the synthesis of sodium carboxymethyl cellulose (CMC) by reacting with the cellulose with NaOH and chloroacetic acid at 75 °C for 1.5 h. Effects of alkali dosage, concentration of chloroacetic acid on the physical and chemical properties of the CMC products were investigated. It was revealed that the reactants alkali reagent/chloroacetic acid/cellulose at the molar ratio of 4.6:2.8:1and 4:2.5:1, or at the molar ratio of NaOH/ClCH 2 COOH ≈1.6–1.64, resulted in CMC products of relatively high water solubility. The viscosity-average molecular weight M v of these two CMC products obtained at molar ratios of 4.0:2.5:1 and 4.6:2.8:1 is in the range of 1.94 × 10 4 –2.48 × 10 4 g mol −1 , and the average DS of the two products are 0.57 and 0.85, respectively. As the solute concentration is above 2 wt%, the viscosity of the CMC-water solution exhibits nonlinear (exponential) increasing with increasing the solute concentration (typical of non-Newton fluids).

Wide‐bandgap (WBG) perovskite solar cells (PSCs) are acknowledged as promising candidates for tandem solar cells and building photovoltaics. It is well known that cesium‐based all‐inorganic halide WBG perovskites possess the comparable optoelectronic properties as the organic–inorganic counterparts, but exhibit superior thermal stability. Among them, CsPbIBr2 is considered a feasible material for tandem solar cells after balancing the bandgap and stability of the inorganic perovskite. However, CsPbIBr2 PSCs are often subjected to drastic interfacial charge recombination especially in carbon‐based device structure derived from the chemical bonding defects (i.e., uncoordinated Pb2+) naked on CsPbIBr2 soft lattice, which dramatically limits overall efficiency of CsPbIBr2 WBG PSCs. Herein, a trimethyl ammonium salt hexyltrimethylammonium bromide is presented for CsPbIBr2/carbon interfacial modification. Benefiting from the −N+(CH3)3 passivation effect and −C6H13 hydrophobic alkyl chain, the optimal device with highly smooth morphology and sufficient charge extraction exhibits a champion power conversion efficiency of 11.24% and improved long‐term stability with 99.7% and 79.7% efficiency retention under dry air atmosphere and continuous 85 °C thermal stress, indicating the valuable potential application of the lattice solidified CsPbIBr2 WBG PSCs.

To meet the increasing demands of precision agricultural and environmental management, more abundant and accurate information is needed to describe soil organic carbon (SOC) vertical variation. Based on 923 soil profiles (collected at the depths of 0–15, 15–30, 30–60, 60–90, 90–120, and 120–150 cm) in the central area of Changhua County, Taiwan, the distribution curve of the SOC content of each profile was fitted by the equal-area spline model, and it was possible to obtain the SOC content at all depths. Taking the 0–5 cm (L1), 5–10 cm (L2), and 10–15 cm (L3) sub-layers as examples, their SOC contents and stocks were compared to the mean values of the average 5-cm-thick sub-layers (Lm) derived from the value of the 0–15 cm layer. The results indicated that the SOC contents and stocks both reduced with increasing soil depths. The mean SOC contents of L1, L2, and L3 were 22.1, 21.0, and 18.7 g·kg−1, respectively, with significant variation, and the values of L2 and L3 were 5.0% and 15.4% lower than that of L1. Similarly, the mean SOC stocks were 1.29, 1.25, and 1.16 kg·m−2 of the L1, L2, and L3 layers, also with significant variation, and the values of L2 and L3 were 4.0% and 10.1% lower than that of L1. Meanwhile, it was found that the SOC content and stock of Lm were both close to the corresponding values in L2, but were significantly different to that of L1 and L3. Furthermore, the interpolation contours of the SOC contents and stocks in L1, L2, and L3 by digital soil mapping also presented regular variation with increasing soil depths, while the contours of Lm had nearly identical patterns to that of L2. The results demonstrate that the typically used mean SOC contents with certain thicknesses calculated from the sampling layer can only approximately inflect the SOC situation at intermediate depths, but the SOC content in the upper and lower parts within the sampling layer varies greatly. Therefore, the actual distribution of SOC varies gradually depending on the soil depth. This study indicates that the combination of the equal-area spline model and digital soil mapping can greatly enrich the current soil SOC database and provide more abundant and accurate SOC content and stock information for precision agricultural and environmental management based on legacy soil database.

The microbial electrolysis desalination and chemical-production cell (MEDCC) is a device to desalinate seawater, and produce acid and alkali. The objective of this study was to enhance the desalination and chemical-production performance of the MEDCC using two types of stack structure. Experiments were conducted with different membrane spacings, numbers of desalination chambers and applied voltages. Results showed that the stack construction in the MEDCC enhanced the desalination and chemical-production rates. The maximal desalination rate of 0.58 ± 0.02 mmol/h, which was 43% higher than that in the MEDCC, was achieved in the four-desalination-chamber MEDCC with the AEM-CEM stack structure and the membrane spacing of 1.5mm. The maximal acid- and alkali-production rates of 0.079 ± 0.006 and 0.13 ± 0.02 mmol/h, which were 46% and 8% higher than that in the MEDCC, respectively, were achieved in the two-desalination-chamber MEDCC with the BPM-AEM-CEM stack structure and the membrane spacing of 3mm.

The most severe failures in power grids are often characterized as cascading failures where an initial event triggers consequent failures all along the grid often leading to blackouts. Upon identifying a failure and its cascade potential, timely control actions should be performed by the grid operators to mitigate the effect of the cascade. These actions have to be delivered to one or more control devices, creating a dependency between the power grid and its control network. This paper examines the dependency of the operation of the power grid on the control network. Different from literature studies on failure control, our dependency model captures the impact of networking parameters. We formulate an algorithmic model that describes the impact of this dependency on cascade control. Based on this model, we propose an efficient cascade control algorithm using load shedding with consideration of delays in the communication network for power grids. Finally, we evaluate the impact of the power-communication network dependency with uncontrolled grids, ideal/simple control grids and our proposed control scheme. The results demonstrate that the proposed algorithm can significantly reduce the failure of power lines while sustaining larger power demand for users.