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Abstract This study investigates the non-linear relationship between urbanization paths and CO2 emissions in selected South, South-East, and East Asian countries over the period 1971–2014. Based on the STIRPAT (Stochastic Impacts by Regression on Population, Affluence, and Technology) framework, we applied the advanced and robust methods of dynamic seemingly unrelated regression (DSUR), dynamic OLS (DOLS), and fully modified OLS (FMOLS) to estimate the long-term effects. The empirical findings revealed the inverted U-shaped effects of urbanization and urban agglomeration and the U-shaped impact of the largest city ratio on CO2 emissions. Urbanization and urban agglomerations improve environmental quality in the long-run and support ecological modernization theory. However, excessive concentration in the largest cities have severely affected the environmental quality and violates the notion of compact-city efficiencies. Moreover, energy intensity and economic growth positively affect CO2 emissions, while trade openness negatively influences CO2 emissions. Our robustness analysis at the country-level applies the augmented mean group (AMG) panel ARDL technique, which further supports the non-linear effect of urbanization paths on CO2 emissions except for a few countries. The results of the panel Granger non-causality approach unveil bidirectional causality of energy efficiency, economic growth, urbanization, and largest city ratio with CO2 emissions. In contrast, unidirectional causality runs from urban agglomeration to CO2 emissions. Our findings have important policy implications as we suggest green urban infrastructures, eco-friendly dwellings, smart cities, country-specific trade policies, and renewable energy options to improve the environmental quality.

In this study, levulinic acid (LA) was produced from rice straw biomass in co-solvent biphasic reactor system consisting of hydrochloric acid and dichloromethane organic solvent. The modified protocol achieved a 15% wt LA yield through the synergistic effect of acid and acidic products (auto-catalysis) and the designed system allowed facile recovery of LA to the organic phase. Further purification of the resulting extractant was achieved through traditional column chromatography, which yielded a high purity LA product while recovering ∼85% wt. Upon charcoal treatment of the resultant fraction generated an industrial grade target molecule of ∼99% purity with ∼95% wt recovery. The system allows the solvent to be easily recovered, in excess of 90%, which was shown to be able to be recycled up to 5 runs without significant loss of final product concentrations. Overall, this system points to a method to significantly reduce manufacturing cost during large-scale LA preparation.

Abstract As a burgeoning theoretical framework, energy justice has been mostly focused on the energy transition in Western countries, where socio-political settings are largely featured by liberalism and democracy, leaving an obvious gap in its application in other socio-political contexts. As a major energy consumer and a leader of the global low-carbon transition, China is characterized by a distinctive socio-political regime. An array of grand strategies to transform its coal-dominant energy structure have been initiated to ameliorate deteriorating environmental crises in particular and materialize a low-carbon transition in general. Based on extensive evidence, this article incorporates the energy justice framework into the analysis of an ongoing energy transition project in rural Northern China. It contributes to the related research in three dimensions. First, empirically, it demonstrates that the coal-to-gas heating transition project has been swamped with social injustices; the absence of measures to address these would lead this mega-project to profound failure. Second, theoretically, it illustrates that the concerns of justice are even more paramount in an authoritarian context where policy processes are characterized by strong political-administrative intervention and the pursuit of efficiency at all cost. In light of this, it stresses the indispensable role of restorative justice as a core tenet in achieving energy justice in authoritarian socio-political contexts, such as China. Third, this study advocates expanding the evaluation parameters of authoritarian environmentalism to include social consequences.

Microalgae have tremendous potential for producing liquid renewable fuel. Many methods for converting microalgae to biofuel have been proposed; however, an economical and energetically feasible route for algal fuel production is yet to be found. This paper presents a review on the comparison of the most promising conversion pathways of microalgae to liquid fuel: hydrothermal liquefaction (HTL), wet extraction and non-destructive extraction. The comparison is based on important assessment parameters of product quality and yield, nutrient recovery, GHG emissions, energy and the cost associated with the production of fuel from microalgae, in order to better understand the pros and cons of each method. It was found that the HTL pathway produces more oil than the wet extraction pathway; however, higher concentrations of unwanted components are present in the HTL oil produced. Less nutrients (N and P) can be recovered in HTL compared to wet extraction. HTL consumes more fossil energy and generates higher GHG emissions than wet extraction, while the production cost of fuel from HTL pathway is lower than wet extraction pathway. There is considerable uncertainty in the comparison of the energy consumption and economics of the HTL pathway and the wet extraction pathway due to different scenarios analysed in the assessment studies. To be able to appropriately compare methodologies, the conversion methods should be analysed from growth to upgradation of oil utilising sufficiently similar assumptions and scenarios. Based on the data in available literature, wet oil extraction is the more appropriate system for biofuel production than HTL. However, the potential of alternative extraction/conversion technologies, such as, non-destructive extraction, need to be further assessed.

It is now recognized that analytical chemistry must also be a target for green principles, in particular chromatographic methods which typically use relatively large volumes of hazardous organic solvents. More generally, high performance liquid chromatography (HPLC) is employed routinely for quality control of complex mixtures in various industries. Acetonitrile and methanol are the most commonly used organic solvents in HPLC, but they generate an impact on the environment and can have a negative effect on the health of analysts. Ethanol offers an exciting alternative as a less toxic, biodegradable solvent for HPLC. In this work we demonstrate that replacement of acetonitrile with ethanol as the organic modifier for HPLC can be achieved without significantly compromising analytical performance. This general approach is demonstrated through the specific example analysis of a complex plant extract. A benchmark method employing acetonitrile for the analysis of Bidens pilosa extract was statistically optimized using the Green Chromatographic Fingerprinting Response (GCFR) which includes factors relating to separation performance and environmental parameters. Methods employing ethanol at 30 and 80°C were developed and compared with the reference method regarding their performance of separation (GCFR) as well as by a new metric, Comprehensive Metric to Compare Liquid Chromatography Methods (CM). The fingerprint with ethanol at 80°C was similar to or better than that with MeCN according to GCFR and CM. This demonstrates that temperature may be used to replace harmful solvents with greener ones in HPLC, including for solvents with significantly different physiochemical properties and without loss in separation performance. This work offers a general approach for the chromatographic analysis of complex samples without compromising green analytical chemistry principles.

The present study is motivated by the need to decouple economic growth from environmental degradation given the new wave of chase for higher economic growth trajectories comes with its environmental cost implications, especially among developing blocs like the Emerging 7 (E7) countries. There is a consistent trade-off between economic growth versus environmental quality. Government apparatus are perpetually on the chase for low-carbon emission policies via the pursuit for green economy. To this end, this present study extends the conventional environmental Kuznets curve (EKC) argument by incorporating the role of institution in emerging industrialized economies (E7) and using second-generation panel analysis methods like mean group (MG), augmented mean group (AMG), common correlated effects mean group (CCEMG), and the Dumitrescu and Hurlin causality test for more robust estimates and inferences. To this end, we explore the long-run and causality relationship between economic growth, quadratic form of economic growth, institutional quality, trade flow, investment in energy sector, and financial development in an EKC environment. Empirical analysis established a long-run equilibrium relationship among the outlined variables over the study period. The long-run regression shows the presence of EKC in the E7. Thus, suggesting the preference for GDP growth over environmental quality at the earlier stage of growth curve. Interestingly, investment in energy, trade flow dynamics across the blocs, and financial development dampens the detrimental effect of environmental pollution as we observed negative relationship with the ecological footprint. On the contrary, quality of institution is weak as institutional quality increase (worsen) the quality of environment in the E7 economies. From a policy perspective, this current study proposed the need for more stringent environmental treaties and regulations and promotion of green economy without compromising economic growth. In the conclusion part of the study, more details and specifics about the policy blueprint are presented.

Robust mitigation options will play significant role in achieving the target of limiting global change to below 1.5 °C above pre-industrial levels by 2100. To support cooperation for mitigation development, we establish a real options-based model to evaluate the rational decisions of exercising the abandon option for carbon capture and storage-enhanced oil recovery (CCS-EOR) projects under oil market and geological uncertainties. Three possible cooperative mechanisms (fixed carbon dioxide (CO2) price, oil-indexed CO2 price, and joint venture contracts) among CO2-EOR stakeholders are evaluated. The results show that the conflicts in profit maximization targets for different stakeholders in cooperative mitigation are to a great extent unable to be avoided. A joint venture business model is preferred in cooperative mitigation as it can effectively weaken such conflicts. And it is more reasonable to provide incentives to the downstream of the CO2-EOR chain than compensating the adoption cost of carbon capture technologies in the upstream. From a global perspective, the inefficient cooperation can be a main barrier that hinders the development of deep-cutting options. Global mitigation strategies should not only focus on promoting technology progress but also the design of innovative business models to balance the benefits among stakeholders. A joint venture business model is recommended in both the developed and developing countries for seizing the early mitigation opportunities.

Renewable energy has become more popular since it is cost-effective and more efficient than conventional energy sources. Biomass-based renewable energy is primarily used in emerging economies to ensure environmental sustainability. This study examines the asymmetric correlation between biomass energy consumption and CO2 emissions in the top-10 biomass energy consumer countries (Brazil, Canada, Thailand, China, Italy, India, Germany, USA, UK, and Japan). A new approach "Quantile-onQuantile (QQ)" is employed by utilizing the data from 1991 to 2018. Biomass energy consumption, with the exception of Thailand, significantly mitigates CO2 emissions at various quantiles in selected countries. As a robustness check, we used the quantile regression test, whose findings are consistent with the outcomes from the quantile-on-quantile method. However, the degree of asymmetry in the biomass energy-CO2 nexus varies by country, necessitating extra attention and government vigilance when developing biomass energy and environmental policies.

Abstract Dolomite, a naturally occurring Ca-based sorbent, shows superior recycling stability in carbonation/calcination cycles for CO2 capture. However, the separation between Ca and Mg in sorbent during recycling weakens the resistance for sintering from MgO, leading to a drastic reduction in the CO2 carrying activity (spent sorbent). This paper presents a novel method for the reactivation of spent dolomite sorbents. Notable activity recovery is achieved by ball milling of the spent sorbent with H2O and dry ice. Powder X-ray diffraction (XRD) results confirm the transformation from oxide (CaO/MgO) to carbonate (CaCO3/CaMg(CO3)2), so that the segregated Ca and Mg in spent sorbent are re-mixed at the atomic level, which is mainly responsible for this effective reactivation. Water plays an irreplaceable role in this process by providing a liquid environment to accelerate the diffusion of the reactants and ionic reactions. In addition, thermogravimetric analysis was carried out on a series of samples with different ball-milling times to determine the suitable reactivation conditions for CO2 capture.