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Abstract Microorganisms used in syngas fermentation require nutrients to grow and convert syngas (CO, H2 and CO2) into various products. Many of the essential nutrients can be provided by biochar. Poultry litter biochar (PLBC) contains minerals and trace metals and has a high pH buffering capacity, making it suitable as a nutrient supplement. The effects of PLBC loadings from 1 to 20 g L−1 on syngas fermentation were determined in 250 ml bottle assays. Results showed that 10 and 20 g L−1 PLBC significantly increased ethanol production compared to standard yeast extract (YE) medium. Fermentations in a 3L continuous stirred tank reactor (CSTR) with 10 g L−1 PLBC with and without 4-morpholineethanesulfonic acid (MES) showed 64% and 36% more ethanol production, respectively, than standard medium. The acetic acid accumulated at the beginning of fermentation was completely converted to ethanol in all media tested in the CSTR. These results demonstrate the feasibility of using PLBC medium without costly MES in the CSTR to enhance ethanol production from syngas for potential use at commercial scale.

Abstract This paper presents a novel multi-time-stage input–output-based modeling framework for simulating the dynamics of bioenergy supply chains. One of the key assumptions used in the model is that the production level at the next time-stage of each segment of the energy supply chain adjusts to the output surplus or deficit relative to targets at the current time period. Furthermore, unlike conventional input–output models, the technology matrix in this approach need not be square, and thus can include coefficients denoting flows of environmental goods, such as natural resources or pollutants. Introducing a feedback control term enables the system to regulate the dynamics, thus extending the model further. This is an important feature since the uncontrolled dynamic model exhibits oscillatory or unstable behavior under some conditions; in principle, the control term allows such undesirable characteristics to be suppressed. Numerical simulations of a simple, two-sector case study are given to illustrate dynamic behavior under different scenarios. Although the case study uses only a hypothetical system, preliminary comparisons are made between the simulation results and some broad trends seen in real bioenergy systems. Finally, some of the main policy implications of the model are discussed based on the general dynamic characteristics seen in the case study. In particular, insights from control theory can be used to develop policy interventions to impart desirable dynamic characteristics to nascent or emerging biofuel supply chains. These interventions can be used to guide the growth of bioenergy supplies along final demand trajectories with minimal fluctuation and no instability.

Abstract Advanced combustion engine (ACE) research is typically carried out on single-cylinder research engines. These engines are designed to tightly control fueling and conditions at intake valve closure (IVC) and to precisely measure in-cylinder conditions and emissions. However, to be able to measure and control engine operation so precisely, these research engines typically do not feature intake and exhaust tracts that resemble those in production engines, specifically in regards to turbomachinery, heat exchangers, and exhaust gas recirculation (EGR) systems. For this reason, these research engines are effective for understanding in-cylinder combustion parameters such as heat release rate, burn duration, combustion efficiency, pollutant formation, and exhaust valve opening (EVO) conditions. This paper applies high fidelity simulations to determine the feasibility of achieving a chosen single cylinder engine operating point on a production type homogeneous charge compression ignition (HCCI) engine, using a partial fuel stratification (PFS) strategy. To accomplish this, a Converge 3 dimensional (3D) – computational fluid dynamics (CFD) model of the experimental combustion chamber and intake and exhaust runners was created to simulate the experimental engine. This model was used to simulate an operating point achieved experimentally, as well as to determine the sensitivity of the operating point to variations in intake pressure, intake temperature, injection timing, injected mass, and EGR fraction. The results from these simulations were fed into a 1-dimensional engine simulation created in AVL Boost, featuring production-type intake and exhaust systems, including turbomachinery and heat exchangers necessary to create the required IVC conditions. This full engine simulation was used to assess the cycle efficiency of the engine at the experimental operating condition, and to assess whether changes to this operating point in intake temperature, intake pressure, direct injection timing, or fueling are beneficial to the cycle efficiency and engine-out emissions. In addition, the sensitivity of promising engine operating points to injection timing and injection mass are determined to evaluate the potential stability of these operating points.

Abstract In the past, most studies considered solar as a drawback to road pavement, especially the asphalt pavement. Not only its radiation causes the asphalt aging, simultaneously with high temperature, asphalt pavement contributes to the urban heat island (UHI) effect. In recent, as the world becomes more supportive towards implementing sustainable energy as the alternatives to the scarcity of non-renewable resources, utilizing the abundant solar radiation as the main source of energy has gradually attracted attention from both industries and academia with its potentials, including solar application on roads. Nevertheless, more researches have focused on the potential energy collection with less consideration to simultaneously overcome the side effects of abundant solar radiation on its lifecycle. This study found the necessity to review a comprehensive correlation between solar radiation and asphalt pavement from both positive and negative effects. The negative effects included asphalt aging and its effects on surroundings i.e. UHI effect. Meanwhile, the positive effects included exhaust purification and solar energy conversion into other forms of energy that can be used by humans using pavement solar heat collection for winter snowmelt, thermoelectric technology and photoelectric technology to convert solar energy into electrical energy. The cases in various application scenarios were analysed and summarized and the existing problems in the current research were proposed in this paper. Also, the reflection on the transformation of road design concept from “avoiding harm” to “seeking profit” was included. Finally, a new concept of “solar-road harmonious symbiosis” for future road application was proposed based on a comprehensive review of previous published works. It is also the new suggestion to scholars on the treatment of solar diseases on roads to prolong its symbiosis functions.

Abstract With the increase of energy consumption and wastes generation due to human activities, anaerobic digestion (AD), a technology which turns wastes into bio-energy, is receiving more and more attention in the world. It is well known that there are at least three stages involved in anaerobic digestion, i.e., hydrolysis, acidification, and methanogenesis. Until now, however, the advances in enhancing acidification and methanogenesis have not been reviewed. This review provides a comprehensive overview of the methods reported to enhance each step involved in anaerobic digestion. More important, enzymes are the key to anaerobic digestion, and the strategies for improving enzyme activity are summarized. As electron transfer has been reported to play an important role in anaerobic digestion, the research progress of the approaches for the acceleration of direct interspecies electron transfer in methane production is also introduced. In addition, the recent advances in increasing the reduction of carbon dioxide to methane, which has been widely observed in methanogenesis step, are reviewed. Furthermore, the techno-economic assessment of anaerobic digestion is made, and the key points for future studies are proposed.

Abstract Wind power technology is one of the cleanest electricity generation technologies that are expected to have a substantial share in the future electricity mix. Nonetheless, the expected increase in the market share of wind technology has led to an increasing concern of the availability, production capacity and geographical concentration of the metals required for the technology, especially the rear earth elements (REE) neodymium (Nd) and the far less abundant dysprosium (Dy), and the impacts associated with their production. Moreover, Nd and Dy are coproduced with other rare earth metals mainly from iron, titanium, zirconium, and thorium deposits. Consequently, an increase in the demand for Nd and Dy in wind power technology and in their traditional applications may lead to an increase in the production of the host metals and other companion REE, with possible implications on their supply and demand. In this regard, we have used a dynamic material flow and stock model to study the impacts of the increasing demand for Nd and Dy on the supply and demand of the host metals and other companion REE. In one scenario, when the supply of Dy is covered by all current and expected producing deposits, the increase in the demand for Dy leads to an oversupply of 255 Gg of total REE and an oversupply of the coproduced REE Nd, La, Ce and Y. In the second and third scenarios, however, when the supply of Dy is covered by critical REE rich deposits or Dy rich deposits, the increase in Dy demand results in an oversupply of Ce and Y only, while the demand for Nd and La exceeds their supply. In the case of an oversupply of REEs, the environmental impacts associated with the REEs production should be allocated to Dy and consequently to the technologies that utilize the metal. The results also show that very large quantities of thorium will be co-produced as a result of the demand for Dy. The thorium would need to be carefully disposed of, or significant thorium applications would need to be found.

Abstract This study aimed to investigate the applicability of the solar heating system in different geographical regions with different meteorological conditions, of which parabolic trough solar collectors (PTCs) were operated with the absorption heat pumps (AHP) and oil/water heat exchanger (OWHE) at medium and low operating temperature respectively. The heat transfer model for PTCs was constructed with a lumped parameter method and validated by experimental results. The thermal performance of the system was evaluated by the index of primary energy ratio (PER). The results showed that on overcast days with low direct normal irradiance (DNI), the operation of the PTC + AHP/OWHE system was not cost-effective. On cloudy days with high DNI lasting for a short period (e.g. 2 h), the operation of the PTC + OWHE system was better than that of the PTC + AHP system as the latter needed more preheating energy before the system operation. While on sunny days with high DNI lasting for a longer period (e.g. 8 h), the PTC + AHP system was suggested to be operated as it owned higher PER values. Besides, the solar energy distributions in China could be divided into four categories, i.e. rich (S1), relatively rich (S2), available (S3) and absent (S4). In S1 region the PTC + AHP system was suggested to be operated. In S4 region the PTC + AHP/OWHE system was not suggested to be operated. While in S2 and S3 region, whether the operation of the PTC + AHP/OWHE system was suggested depending on the meteorological conditions. With these findings the developing strategy of the solar heating system in different geographical regions can be devised and the operating strategy on a specific day with different weather conditions can be developed, which is helpful to guide the application of solar energy and improve the energy structure in domestic heating.

Abstract The correlation between effectiveness of multiple operating parameters is a complicated issue and significant to the safe operation of solid oxide fuel cell/gas turbine (SOFC/GT) hybrid system. This paper presents a numerical analysis on biogas-fueled SOFC/GT hybrid system with a recirculation process using combustor exhaust gas. With consideration of safety constraints for critical components (fuel cell thermal crack, reformer carbon deposition, turbine blade overheat), the interaction mechanism of recirculation ratio, steam/carbon ratio and fuel/air ratio is studied from the perspective of thermodynamic analysis. Results show that the recirculation process could increase the electrical efficiency of system from 58.18% to 62.8%. However, for the safety consideration of SOFC, the acceptable recirculation ratio should be controlled between 0.17 and 0.32. Meanwhile, there exists a minimum point of turbine inlet temperature at the recirculation ratio of 0.3. With recirculation ratio switched from 0.1 to 0.3, impact of steam/carbon ratio variation on SOFC temperature gradient shrinks from 52.5% to 17.9% of the reference value. On the other hand, effect of fuel/air ratio variation on SOFC temperature gradient is promoted from 20.8% to 44.3% of the reference value, due to that oxidation reaction of biogas becomes a dominant factor. Based on these results, a parametric comparison is carried out to quantitatively describe the impact of recirculation process on the effectiveness of other parameters. Short discussion is conducted on parameter selection to acquire higher system efficiency and sufficient safety range, in which case the total output power of 176.8 kW and electrical efficiency of 61.78% could be achieved.

Abstract The automotive operating protocols is a comprehensive expression of a country or a region’s road, climatic environment and driving habits. It is the foundation of energy consumption, test method and limit method for automobile products. It has direct impact on R & D, production and government access management of enterprises. For fuel cells vehicles, the lifetime is one of the main factors restricting their commercialization. Furthermore, the lifetime evaluation methods and its standard specifications of vehicular proton exchange membrane fuel cell are the critical factors to its technological development, but there is no authoritative recognized life evaluation method and test protocols so far. A logical fuel cell durability test protocol is the fundamental for developing the fuel cell life evaluation methods. A review on the state-of-art in the world for fuel cell accelerated test protocols was given, the research circumstances of different universities and research institutions in China, America, the European Union, Japan and so on are analyzed and summarized in detail. Then the essential characteristics and applicable environments of a comprehensive and effective durability test protocol are summarized based on the analysis and demonstration of the existing durability test protocols in literature. The work in this paper focuses on the research of durability test protocols of the fuel cell stack for the first time. The final conclusion will provide theoretical basis for establishing fuel cell durability test specifications and proposing life evaluation methods, and make a contribution to the long life research of vehicular fuel cells.