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Abstract Energy storage systems (ESS) are widely used in active distribution networks (ADN) to smoothen the drastic fluctuation of renewable energy sources (RES). In order to enhance the scalability and flexibility of ESS, a virtual energy storage system (VESS), which is composed of battery energy storage system (BESS), RES as well as flexible loads (FL), is developed in this paper to realize the functionalities of ESS in more cost-effective way in ADN. Aiming at achieving voltage regulation, dynamic pricing strategies based on system voltage condition are designed for VESS. A distributed real-time power management model containing dynamic pricing strategies is proposed to accomplish the voltage regulation and economic power sharing in VESS. Moreover, a set of distributed algorithms, over time-varying unbalanced directed networks, are designed for dynamic pricing strategies and optimal power management model. Furthermore, the convergence property, optimality and system voltage stability are explained by detailed mathematical analysis. Three various case studies which were ran on a real time digital simulator (OPAL-RT OP5600) were designed to validate the effectiveness of the strategy. Finally, simulation results show that the economic power dispatch and voltage regulation are achieved among VESS simultaneously, even in the presence of time-varying directed and unbalanced communication networks.

Abstract In this study, crude cellulose derived from cornstalk, after bleaching, was used as raw material for the synthesis of sodium carboxymethyl cellulose (CMC) by reacting with the cellulose with NaOH and chloroacetic acid at 75 °C for 1.5 h. Effects of alkali dosage, concentration of chloroacetic acid on the physical and chemical properties of the CMC products were investigated. It was revealed that the reactants alkali reagent/chloroacetic acid/cellulose at the molar ratio of 4.6:2.8:1and 4:2.5:1, or at the molar ratio of NaOH/ClCH 2 COOH ≈1.6–1.64, resulted in CMC products of relatively high water solubility. The viscosity-average molecular weight M v of these two CMC products obtained at molar ratios of 4.0:2.5:1 and 4.6:2.8:1 is in the range of 1.94 × 10 4 –2.48 × 10 4 g mol −1 , and the average DS of the two products are 0.57 and 0.85, respectively. As the solute concentration is above 2 wt%, the viscosity of the CMC-water solution exhibits nonlinear (exponential) increasing with increasing the solute concentration (typical of non-Newton fluids).

Wide‐bandgap (WBG) perovskite solar cells (PSCs) are acknowledged as promising candidates for tandem solar cells and building photovoltaics. It is well known that cesium‐based all‐inorganic halide WBG perovskites possess the comparable optoelectronic properties as the organic–inorganic counterparts, but exhibit superior thermal stability. Among them, CsPbIBr2 is considered a feasible material for tandem solar cells after balancing the bandgap and stability of the inorganic perovskite. However, CsPbIBr2 PSCs are often subjected to drastic interfacial charge recombination especially in carbon‐based device structure derived from the chemical bonding defects (i.e., uncoordinated Pb2+) naked on CsPbIBr2 soft lattice, which dramatically limits overall efficiency of CsPbIBr2 WBG PSCs. Herein, a trimethyl ammonium salt hexyltrimethylammonium bromide is presented for CsPbIBr2/carbon interfacial modification. Benefiting from the −N+(CH3)3 passivation effect and −C6H13 hydrophobic alkyl chain, the optimal device with highly smooth morphology and sufficient charge extraction exhibits a champion power conversion efficiency of 11.24% and improved long‐term stability with 99.7% and 79.7% efficiency retention under dry air atmosphere and continuous 85 °C thermal stress, indicating the valuable potential application of the lattice solidified CsPbIBr2 WBG PSCs.

The microbial electrolysis desalination and chemical-production cell (MEDCC) is a device to desalinate seawater, and produce acid and alkali. The objective of this study was to enhance the desalination and chemical-production performance of the MEDCC using two types of stack structure. Experiments were conducted with different membrane spacings, numbers of desalination chambers and applied voltages. Results showed that the stack construction in the MEDCC enhanced the desalination and chemical-production rates. The maximal desalination rate of 0.58 ± 0.02 mmol/h, which was 43% higher than that in the MEDCC, was achieved in the four-desalination-chamber MEDCC with the AEM-CEM stack structure and the membrane spacing of 1.5mm. The maximal acid- and alkali-production rates of 0.079 ± 0.006 and 0.13 ± 0.02 mmol/h, which were 46% and 8% higher than that in the MEDCC, respectively, were achieved in the two-desalination-chamber MEDCC with the BPM-AEM-CEM stack structure and the membrane spacing of 3mm.

Experimental investigation into the effects of different pilot amounts of dimethyl ether (DME) on the performance and emission of a single-cylinder directinjection DME engine is conducted. The results show that a DME engine can operate at a wider range of speeds and loads at quasi-homogenous charge compression ignition (QHCCI) mode. The brake thermal efficiency increases while the exhaust temperature decreases. NOx emission decreases by about 30%–50% although there is a slight increase in HC and CO emissions. NOx, HC and CO emissions increase with an increase in the amount of DME pilot. QHCCI is a good way to increase thermal efficiency and decrease NOx emission.

Abstract Predicting and optimizing radiative thermal properties have been acknowledged as an efficient way to improve thermal insulation performance of fibrous materials with high porosity. Based on experimental investigation of infrared spectral of ultrafine fibrous insulations with diameters of 520–650 nm, a method of calculating radiative thermal properties was presented by combining Rosseland equation, Mie scattering theory, Beer’s law and Subtractive Kramers–Kronig (SKK) relation. To ensure the calculation correct the uniqueness analysis was performed for Poly(vinylidene fluoride) (PVDF) fibers, which indicated the valid fiber diameter was less than 1.06 μm. The calculated thermal radiative conductivities by using the method agreed well with the measured data. The effect of fiber diameter on the thermal properties of the fibrous insulations was also investigated to minimize the radiative thermal conductivity. The results indicated that the minimized radiative thermal conductivities by regulating fiber diameters could be approximately 25% smaller than those for experimental fiber diameters. The method of predicting and minimizing radiative thermal conductivities of fibrous insulations demonstrated in this paper could be of great advantage to thermal engineering applications aiming to reducing heat loss and saving energy.

Reactive power consumption of the modern power system is a very important problem that to solve well. Due to the line commutated current source converter-based (LCC) HVDC system is a multivariable and strong coupling nonlinear system, it is difficult to model reactive power consumption of receiving end of LCC-HVDC by traditional analysis method. This paper proposes the reactive power consumption model of receiving end of LCC-HVDC on account of the radial basis function (RBF) neural network. The model with the turn-off angle for input, with reactive power loss on the inverter side of LCC-HVDC for output, using 500kV, 1000MW LCC-HVDC system PSCAD simulation test data training RBF neural network and testing network generalization ability. The results indicate that the reactive power loss model on account of the RBF neural network has much faster convergence speed and higher convergence precision.

Microwave-assisted alkali pre-treatment of wheat straw and its enzymatic hydrolysis were investigated and compared with the conventional alkali pre-treatment process. First, the effect of microwave power and pre-treatment time on the weight loss and composition of wheat straw was examined. The results show that the higher microwave power with shorter pre-treatment time and the lower microwave power with longer pre-treatment time had the same effect on the weight loss and composition at the same energy consumption. The comparison was then made between the effect of the microwave-assisted alkali pre-treatment and the conventional alkali one on the weight loss and composition of wheat straw. The wheat straw had a weight loss of 48·4% and a composition of cellulose 79·6%, lignin 5·7% and hemicellulose 7·8% after 25 min microwave-assisted alkali pre-treatment at 700 W, compared with a weight loss of 44·7% and a composition of cellulose 73·5%, lignin 7·2% and hemicellulose 11·2% after 60 min conventional alkali pre-treatment. The microwave-assisted alkali pre-treatment removed more lignin and hemicellulose from wheat straw with shorter pre-treatment time compared with the conventional alkali one. Finally, the enzymatic hydrolysis of pre-treated wheat straw (substrate concentration 50 g l−1, enzyme loading 20 mg g−1 substrate) was also investigated and the results indicate that the microwave-assisted alkali pre-treated wheat straw had higher hydrolysis rate, reducing sugar concentration and glucose content in the hydrolysate than the conventional alkali pre-treated one. Microwave-assisted alkali pre-treatment is a potential alternative of wheat straw pre-treatment for its enzymatic hydrolysis.

A template‐agent can affect defect formation as well as influence interface properties, due to the rapid growth of perovskite film from the solution. Herein, diethylammonium iodide (DAI) is used as an effective template‐agent to control the perovskite crystallization during preparation. It is found that a very small amount of DAI in chlorobenzene (CB) can slow down the perovskite growth of the CH3NH3PbI3 (MAPbI3) film with more large grain size and compacted crystal‐grains resulting in the lesser grain boundaries (GBs) in favor of carrier transport in perovskite solar cells (PSCs). Moreover, some redundant PbI2 can be digested to form DA2PbI4. One part of DA2PbI4 can form the sub‐grains with the composition of (DA2PbI4)0.2(PbI2)0.8 to passivate the GB defects, and other part can cover the surface to passivate the surface defects in large MAPbI3 grains. Using an optimized DAI concentration of 0.5 mg mL−1 in CB solution, the corrsponding MAPbI3 PSC achieves an increased power conversion efficiency of 20.31% with suppressed current–voltage hysteresis. This DAI passivation strategy provides a simple approach to effectively assist the grain‐growth for improved device performance.