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This study evaluated the environmental conditions of two watersheds selected on the basis of similarities in land use. The environmental conditions of the watersheds were analyzed using two geoprocessing methods and in situ evaluations by applying the rapid assessment protocol (RAP). Geospatial image processing was used to analyze land use, slope, soil classification, and rainfall, while RAP was used to evaluate the connectivity and size of riparian corridors. The results revealed varied uses of land with the landscape matrix in both watersheds, composed of agriculture, pasture, and urban centers. Urban centers were defined as spots and riparian zones as corridors. The analysis of environmental fragility considering all the geospatial variables, classified both watersheds as having medium fragility. The most fragile sites were the urban centers, which had a high slope and degraded riparian zone. Onsite assessments have shown that corridors do not have the size required by legislation; they are fragmented and unstructured, and they contain exotic species. We also propose that a multi-factorial approach be used to evaluate watersheds, associating geospatial assessments and onsite analyses that consider the limitations pointed out in each protocol. This reduces sampling errors and shows the actual state of conservation in riparian zones.

An ethanol-methyl- t-butyl ether (MTBE) fuel blend was used as a substitute for hydrated ethanol to improve the vehicle cold start and drivability characteristics during the warm-up period. The vehicle was tested in a cold box, reaching a lower ambient temperature limit of -6deg;C, which represents the most severe weather condition experienced in Brazil. Different concentrations of MTBE in ethanol were investigated. The results show satisfactory drivability characteristics for the tested conditions, comparable with those found in gasoline-fuelled vehicles, thus overcoming the existing cold start difficulties in production ethanol-fuelled vehicles.

Sugarcane biorefineries, despite their contribution to sustainable transportation fuels and mitigation of carbon emissions in the mobility sector, produce a large amount of carbon dioxide in their conversion processes. According to the Paris climate agreement, a carbon neutral energy system has to be launched in the years to come, and in this scenario, greenhouse gases emission free industrial processes and alternative carbon sources will be needed. Therefore, this paper presents the evaluation of carbon mass balance of a typical Brazilian ethanol mill to better understand its potential for energy and carbon yield improvement. Due to the fact that Brazilian sugarcane mills are evolving from first generation to integrated first and second generation plant, four different scenarios were analysed. For a first generation plant without (S-I) and with conversion of straw to electricity (S-II) and for the integrated plant (S-III), results of carbon mass balance showed that the harvested sugarcane carbon was mainly converted into CO2 and in a smaller proportion into ethanol. In the modelled cases S-I to S-III the conversion of sugarcane carbon into CO2 and ethanol ranged from 41% to 53% and 17%-22%, respectively. Because this carbon amount in the CO2 flows provides an interesting platform to both increase the bioenergy produced and the harvested carbon-to-fuels ratio, a fourth scenario (S-IV) that studies the integration of power-to-gas (PtG) technologies into the mill was also considered. PtG can increase the sugarcane fuels energy content from 9.3 kW/ha to 33.6 kW/ha using 1361.3 MWe of electricity, increasing the amount of sugarcane carbon transformed into sugarcane based fuels to 54% and converting CO2 into a high value added product.

In response to the intensification of eco-friendly routes as a strategy to access compounds of interest, extraction based on hydrothermal technologies is an efficient method to obtain high yields of compounds present in lignocellulosic materials. Accordingly, this study investigated the effects of the combination of ultrasonic pretreatments (energy density, 1.23 × 103-37.6 × 103 J/cm3; reaction time, 15 and 60 min) and subcritical water hydrolysis (SWH) (temperature, 220°C; flow rate, 10-30 mL/min; and reaction time, 0.5-15 min) on sugar yield profile from residual biomass of rice, soybean, and pecan. A characterization of the sugars present in the hydrolyzed solutions by high-performance liquid chromatography (HPLC) and a physicochemical evaluation of biomasses by Fourier-transform infrared spectroscopy (FT-IR) was performed. The highest yield reported were 23.8/100 g biomass, 14.4/100 g biomass, and 6.0/100 g biomass for pecan shell, rice shell, and soybean straw, respectively. Cellobiose, glucose, xylose, and arabinose were quantified by the HPLC, as well as inhibitors and organic acids. FT-IR indicated the compositions of the fresh and pretreated samples. Appropriately, the combined application of ultrasonic and SWH methods supported the valorization and optimization of high potential materials generated in agricultural processing.

Abstract Small-scale hydroelectric plants, primarily run-of-the-river designs, are regularly subjected to hard particle wear and cavitation erosion due to the wide range of operating points. Depending on the severity of the operating conditions and erosion damage experienced by the machine throughout its service life, the operating companies of these facilities will be impacted. The impact will be technical, operational, logistical, and economic. A small-scale generation plant located in Amaime River in Colombia, is one such case, where severe wear occurs in the turbine components, with a consequent reduction of efficiency. In this study, the analysis of the erosion damage has been expanded and supplemented by computational fluid dynamics (CFD). From this approach, correlations between the wear rate and power output were obtained. Likewise and in conjunction with the computer estimates, a methodology to analyse the costs associated with wear based on historical data of operation was developed, creating a strategy of operation based on a stopping criterion that depends primarily on sediment concentration, turbinated flow, and wear level. The methodology optimizes the use of generators, which takes into consideration the revenue generation and the costs associated with operation and maintenance of pieces under conditions of intrinsic erosion wear in the facility.

The black liquor is a byproduct of the kraft pulping process that contains more than half of the exergy content in the total woody biomass fed to the digester, representing a key supply of renewable energy to the pulping process. In this work, the conventional scenario of the black liquor use (i.e., concentration and combustion) is compared with the black liquor upgrading (via) gasification process for ammonia production in terms of economics, exergy efficiency and environmental impact. The combined energy integration and exergy analysis is used to identify the potential improvements that may remain hidden to the energy analysis alone, namely, the determination and mitigation of the process irreversibility. As a result, the exergy efficiencies of the conventional and the integrated cases average 40% and 42%, respectively, whereas the overall emission balance varies from 1.97 to −0.69 tCO2/tPulp, respectively. The negative CO2 emissions indicate the environmental benefits of the proposed integrated process compared to the conventional kraft pulp mill.

espanolSe presentan los resultados de un estudio sobre la significancia y la optimizacion de algunas variables (granulometria, velocidad de aire, contenido de biomasa y disposicion del reactor) en el poder calorifico del gas de sintesis obtenido de la gasificacion de biomasa (carbon vegetal y cuesco de palma africana). Mediante un diseno de experimento se evaluaron las cuatro variables que oscilaban entre 8-13mm para la granulometria, 0.8-1.4m/s para la velocidad del aire, 0-100 para el contenido de biomasa y ascendente-descendente para la disposicion del reactor. Se encontro que los factores correspondientes a la granulometria y el contenido de biomasa resultan ser los mas significativos en el poder calorifico del gas. Un poder calorifico maximo de 3.84MJ/Nm3 se obtuvo con la disposicion descendente del reactor, alimentacion de carbon vegetal con granulometria de 13mm y suministro maximo de flujo de aire. La verificacion del punto optimo de operacion mostro que tales condiciones de operacion favorecian la produccion de un gas con un alto poder calorifico. EnglishThe results of study on the significance and the optimization of some variables (particle size, air flow, biomass content and reactor disposition) in the calorific value of the synthesis gas obtained by gasification process of biomass (vegetal coal and biomass African palm) is presented. The four variables ranged from 8-13mm for the particle size, 0.8-1.4m/s for air flow, 0-100 for biomass content and updraft-downdraft disposition for the type of reactor were evaluated by an experimental design. It was found that the particle size and biomass content are the most significant factors to maximize the output calorific value of syngas. A maximum calorific value of 3.84MJ/Nm3 was obtained using the downdraft reactor with 13mm particle size and maximum air flow supply. The verification of the optimum operating point under these conditions showed that such operating conditions favored the production of a gas with high calorific value.

Abstract The use of photovoltaic solar power generation is rising as worldwide energy demand increases. Therefore, reliability, safety, life cycle, and improved efficiency of photovoltaic plants have all become a major concern in research nowadays. In this context, monitoring systems are necessary to guarantee the required operating productivity and to avoid overpriced maintenance costs. This paper studies the non-ideal operating conditions for grid-connected photovoltaic plants and proposes an anomaly detection methodology that combines the advantages of the 2-sigma, short-window simple-moving average control charts with shading strength and irradiance transition parameters to detect early deviation in photovoltaic plant operational data. The key aspect of proposed methodology is that it requires neither historical data for model training procedure nor parameters from previous simulation. Only instantaneous meteorological and electrical parameters are required. The efficiency of the condition monitoring methodology has been validated through experimental results conducted in actual operating conditions. Results demonstrated that the proposed methodology is effective to identify non-ideal operating conditions for grid-connected photovoltaic plants, i.e., (i) normal operating condition, (ii) natural dynamic shading, (iii) artificial dynamic shading, and (iv) artificial static shading. Moreover, a low-cost and non-invasive internet-of-things-based embedded architecture is proposed to monitor photovoltaic plant operation in real-time.

This work is the result to the study a different systems of exhaust pipes. The manufacturers of motorbike use a system with several volumes to reduce noise and use a catalyst to reduce emissions. In contrast, the manufacturers of exhaust system decided made a system using a perforated pipe and a rock wool to noise reducing. This system changes the pressure drop and temperature of exhaust gases and, therefore, request a different composition of catalyst.In this communication, it is shown the tests released in a test bench according with the cycle WLTC and the limits are the defined for EURO3. Where, we have changed the type of catalyst, the diameter of the end pipe and the calibration of electronic control unit of engine in order to measure following the test of homologation.The results of the different experiments indicate is very important the pressure drop in the replace exhaust system must be similar to the original system. The composition of the catalyst and the operating temperature are critical to reduce the emissions and the calibration of engine is the main influence. Keywords: Exhaust systems, Catalyst, Regulatory emissions, WLTC