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Biofuels have been identified as a mid-term GHG emission abatement solution for decarbonising the transport sector. This study examines the techno-economic analysis of biofuel production via biomass fast pyrolysis and subsequent bio-oil upgrading via zeolite cracking. The aim of this study is to compare the techno-economic feasibility of two conceptual catalyst regeneration configurations for the zeolite cracking process: (i) a two-stage regenerator operating sequentially in partial and complete combustion modes (P-2RG) and (ii) a single stage regenerator operating in complete combustion mode coupled with a catalyst cooler (P-1RGC). The designs were implemented in Aspen Plus® based on a hypothetical 72 t/day pine wood fast pyrolysis and zeolite cracking plant and compared in terms of energy efficiency and profitability. The energy efficiencies of P-2RG and P-1RGC were estimated at 54% and 52%, respectively with corresponding minimum fuel selling prices (MFSPs) of £7.48/GGE and £7.20/GGE. Sensitivity analysis revealed that the MFSPs of both designs are mainly sensitive to variations in fuel yield, operating cost and income tax. Furthermore, uncertainty analysis indicated that the likely range of the MFSPs of P-1RGC (£5.81/GGE  £11.63/GGE) at 95% probability was more economically favourable compared with P-2RG, along with a penalty of 2% reduction in energy efficiency. The results provide evidence to support the economic viability of biofuel production via zeolite cracking of pyrolysis-derived bio-oil.

Since the invention of fluorescent light sources, there is strong interest in Eu3+ activated phosphors as they are able to provide a high color rendering index (CRI) and luminous efficacy, which will also hold for phosphor converted light emitting diodes. Due to an efficient U6+ to Eu3+ energy transfer in Gd3Li3Te2O12:U6+,Eu3+, this inorganic composition shows red photoluminescence peaking at 611 nm. That means Eu3+ photoluminescence can be nicely sensitized via excitation into the U6+ excitation bands. Therefore, photoluminescence properties, such as temperature dependent emission and emission lifetime measurements, are presented. Charge transfer bands were investigated in detail. Additionally, density functional theory calculations reveal the band structure of the pure, i.e., non-doped host material. Obtained theoretical results were evaluated experimentally by the aid of diffuse UV reflectance spectroscopy.

The ‘4 per mille Soils for Food Security and Climate’ was launched at the COP21 with an aspiration to increase global soil organic matter stocks by 4 per 1000 (or 0.4 %) per year as a compensation for the global emissions of greenhouse gases by anthropogenic sources. This paper surveyed the soil organic carbon (SOC) stock estimates and sequestration potentials from 20 regions in the world (New Zealand, Chile, South Africa, Australia, Tanzania, Indonesia, Kenya, Nigeria, India, China Taiwan, South Korea, China Mainland, United States of America, France, Canada, Belgium, England & Wales, Ireland, Scotland, and Russia). We asked whether the 4 per mille initiative is feasible for the region. The outcomes highlight region specific efforts and scopes for soil carbon sequestration. Reported soil C sequestration rates globally show that under best management practices, 4 per mille or even higher sequestration rates can be accomplished. High C sequestration rates (up to 10 per mille) can be achieved for soils with low initial SOC stock (topsoil less than 30 t C ha− 1), and at the first twenty years after implementation of best management practices. In addition, areas which have reached equilibrium will not be able to further increase their sequestration. We found that most studies on SOC sequestration only consider topsoil (up to 0.3 m depth), as it is considered to be most affected by management techniques. The 4 per mille number was based on a blanket calculation of the whole global soil profile C stock, however the potential to increase SOC is mostly on managed agricultural lands. If we consider 4 per mille in the top 1m of global agricultural soils, SOC sequestration is between 2-3 Gt C year− 1, which effectively offset 20–35% of global anthropogenic greenhouse gas emissions. As a strategy for climate change mitigation, soil carbon sequestration buys time over the next ten to twenty years while other effective sequestration and low carbon technologies become viable. The challenge for cropping farmers is to find disruptive technologies that will further improve soil condition and deliver increased soil carbon. Progress in 4 per mille requires collaboration and communication between scientists, farmers, policy makers, and marketeers.

Abstract Social acceptance of innovative technologies is a key element of an effective transition towards more sustainable energy economies. However, innovative technologies like genetic modification also tend to spark controversy and backlash. So far, efforts to inform the public about any risks and benefits of novel technologies not only have struggled to foster acceptance but also neglect the interdependent foundations of consumer decision-making. Through a controlled experiment with German consumers (N = 322), we examine whether consumer support and rejection of genetic modification in bioenergy crops is influenced by the statements and actions of actors throughout the supply chain. In specific, we show that the decision of energy companies to sell and support GM bioenergy positively impacts consumer decisions to support. To ensure that decision outcomes were specifically impacted by the expressions of corporate actors, we controlled for the content and valence of information by random assignment to one of three treatments in which participants received positive, negative, or balanced (risks and benefits) information. We find that negative messaging diminished support and increased rejection relative to the other treatments. Lastly, the statements and actions of corporate actors also exerted an indirect influence on consumer decisions through their interactions with social trust and labels, e.g. greater support by farmers had a positive influence only for those who are more generally trustworthy. Given these results, we anticipate more attention to the importance of actors such as farmers and energy companies for the social acceptance of novel technologies in the energy sphere.

Spinel LiNi0.5Mn1.5O4 as one of the high-energy positive electrode materials for next generation Li-ion batteries has attracted significant interest due to its economic and environmental advantages. However, the sensitivity of this type of material upon short to long term ambient storage conditions and the impact on the electrochemical performances remains poorly explored. Nevertheless, this remains an important aspect for practical large-scale synthesis, storage and utilization. Herein, we study and compare the evolution of surface chemistry, bulk crystal structure and elemental content evolution and distribution of LiNi0.5Mn1.5O4 using a variety of characterization techniques including XPS and STEM-EDS-EELS, as well as electrochemical analysis. We show that Mn species dominate the outer surface (0–5 nm), while Ni and Li are preferentially located further away and in the bulk. The studied LiNi0.5Mn1.5O4 material is found to be stable, with minor changes in surface or bulk characteristics detected, even after 12 months of storage under ambient air conditions. The low surface reactivity to air also accounts for the minor changes to the electrochemical performance of the air-exposed LiNi0.5Mn1.5O4, compared to the pristine material. This study provides guidance for the appropriate storage, handling and processing of this high-performance cathode material.

Parabolic trough power plants are currently the most commercially applied systems for CSP power generation. To improve their cost-effectiveness, one focus of industry and research is the development of processes with other heat transfer fluids than the currently used synthetic oil. One option is the utilization of water/steam in the solar field, the so-called direct steam generation (DSG). Several previous studies promoted the economic potential of DSG technology [1–3]. Analyses’ results showed that live steam parameters of up to 500°C and 120 bars are most promising and could lead to a reduction of the levelized electricity cost (LEC) of about 11% [4]. However, all of these studies only considered plants without thermal energy storage (TES). Therefore, a system analysis including integrated TES was performed by Flagsol GmbH and DLR together with Solar Millennium AG, Schott CSP GmbH and Senior Bergho¨fer GmbH, all Germany. Two types of plants are analyzed and compared in detail: a power plant with synthetic oil and a DSG power plant. The design of the synthetic oil plant is very similar to the Spanish Andasol plants [5] and includes a molten salt two-tank storage system. The DSG plant has main steam parameters of 500 °C and 112 bars and uses phase change material (PCM) for the latent and molten salt for the sensible part of the TES system. To enable comparability, both plants share the same gross electric turbine capacity of 100 MWel, the same TES capacity of nine hours of full load equivalent and the same solar multiple of the collector field of about two. This paper describes and compares both plants’ design, performance and investment. Based on these results, the LEC are calculated and the DSG plant’s potential is evaluated. One key finding is that with currently proposed DSG storage costs, the LEC of a DSG plant could be higher than those of a synthetic oil plant. When considering a plant without TES on the other hand, the DSG system could reduce the LEC. This underlines the large influence of TES and the still needed effort in the development of a commercial storage system for DSG.