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Bioplastics are alternatives of conventional petroleum-based plastics. Bioplastics are polymers processed from renewable sources and are biodegradable. This study aims at conducting an environmental impact assessment of the bioprocessing of agricultural wastes into bioplastics compared to petro-plastics using an LCA approach. Bioplastics were produced from potato peels in laboratory. In a biochemical reaction under heating, starch was extracted from peels and glycerin, vinegar and water were added with a range of different ratios, which resulted in producing different samples of bio-based plastics. Nevertheless, the environmental impact of the bioplastics production process was evaluated and compared to petro-plastics. A life cycle analysis of bioplastics produced in laboratory and petro-plastics was conducted. The results are presented in the form of global warming potential, and other environmental impacts including acidification potential, eutrophication potential, freshwater ecotoxicity potential, human toxicity potential, and ozone layer depletion of producing bioplastics are compared to petro-plastics. The results show that the greenhouse gases (GHG) emissions, through the different experiments to produce bioplastics, range between 0.354 and 0.623 kg CO2 eq. per kg bioplastic compared to 2.37 kg CO2 eq. per kg polypropylene as a petro-plastic. The results also showed that there are no significant potential effects for the bioplastics produced from potato peels on different environmental impacts in comparison with poly-β-hydroxybutyric acid and polypropylene. Thus, the bioplastics produced from agricultural wastes can be manufactured in industrial scale to reduce the dependence on petroleum-based plastics. This in turn will mitigate GHG emissions and reduce the negative environmental impacts on climate change.

Abstract Recharging infrastructure (RI) deployment plays a vital role in improving the public recharging availability for transport electrification. Decarbonizing transportation using low-emission electricity requires massive RI network. Even though the consumers are reluctant to purchase electric vehicles (EVs) until RIs are sufficiently placed, the investors are not willing to invest in RIs due to recharging demand uncertainties. Therefore, a scientific planning framework is needed to ensure the sustainable deployment of EV-RIs in complex networks. In this study, a lifecycle thinking-based multi-period infrastructure-planning framework is proposed to develop sustainable public EV-RIs in an urban context. This framework consists of a temporal model to find the dynamic EV-RI demands, a stochastic model to obtain travel distances, and a multi-objective optimization model to select the best desirable capacities and locations for potential EV-RIs. A case study of a typical medium-scale municipality in Canada was assessed using the proposed framework and validated using conventional infrastructure planning scenarios. The geo-processing data, regional travel behaviors, and recharging characteristics were used as model inputs. The results of the case study showed that the proposed framework can be used to estimate multi-period public recharging demands, minimize lifecycle costs, maximize service coverage and infrastructure utilization, and ensure reasonable paybacks compared to conventional planning approaches. Moreover, this framework can be used to compare different investment assistances, which are required in the early stages of the RI deployment process to encourage investors. Furthermore, government and private institutions can use this framework to identify recharging demands, permitting, and developing RIs in the long-run.

Abstract The residential sector accounts for most of energy-consumption in developing countries in the form of traditional energy. The use of commercial energy is nominal and confined mostly to urban areas where fuelwood is already monetized. A model, based on an end-use/process analysis approach, is developed on a spreadsheet, which is capable of simulating scenarios to address issues of increasing traditional energy-demand caused by population growth, sustainable supply capacity of the existing energy resources, potential for development of new and renewable energy resources, technology. This paper is divided into two parts: general energy issues and the modelling approach, and the application of this approach to Nepal in the context of fuelwood-supply sustainability.

Highly efficient nanocatalysts which can selectively decompose hydrous hydrazine for hydrogen production are introduced.

AbstractConcrete is a valuable construction material with high mechanical strength and durability, used extensively in the construction industry. It is produced by mixing sand, stones, cement, and water in different proportions depending on the desired quality of the final product. Water reducers are additional chemical ingredients used in concrete to reduce the quantity of water required in the concrete mixture. When added to concrete, water reducers increase the workability and flowability of concrete in the freshly mixed state and improve the mechanical strength and durability of the final hardened product. This review paper describes the different types and applications of concrete water reducers used in the construction industry including their working mechanisms and fluidity effects on concrete properties. It discusses the production of synthetic and bio‐based concrete water reducers and reviews the present challenges involved in the preparation of bio‐based concrete water reducers from renewable resources. © 2023 Society of Industrial Chemistry and John Wiley & Sons Ltd.

Abstract A variety of novel, recyclable and reusable, construction materials has already been studied within literature during the past years, aiming at improving the overall energy efficiency ranking of the building envelope. However, several studies show that a delicate control of indoor climating elements can lead to a significant performance improvement by exploiting the building’s savings potential via smart adaptive HVAC regulation to exogenous uncertain disturbances (e.g. weather, occupancy). Building Optimization and Control (BOC) systems can be categorized into two different groups: centralized (requiring high data transmission rates at a central node from every corner of the overall system) and decentralized 1 (assuming an intercommunication among neighboring constituent systems). Moreover, both approaches can be further divided into two subcategories, respectively: model-assisted (usually introducing modeling oversimplifications) and model-free (typically presenting poor stability and very slow convergence rates). This paper presents the application of a novel, decentralized, agent-based , model-free BOC methodology (abbreviated as L4GPCAO) to a modern non-residential building (E.ON. Energy Research Center’s main building), equipped with controllable HVAC systems and renewable energy sources by utilizing the existing Building Management System (BES). The building testbed is located inside the RWTH Aachen University campus in Aachen, Germany. A combined rule criterion composed of the non-renewable energy consumption (NREC) and the thermal comfort index – aligned to international comfort standards – was adopted in all cases presented herein. Besides the limited availability of the specified building testbed, real-life experiments demonstrated operational effectiveness of the proposed approach in BOC applications with complex, emerging dynamics arising from the building’s occupancy and thermal characteristics. L4GPCAO outperformed the control strategy that was designed by the planers and system provider, in a conventional manner, requiring no more than five test days.

Abstract Communication between vehicles and road infrastructure can enable more efficient use of the road network and hence reduce congestion in urban areas. This improvement can be enhanced by distributed control due to its lighter computational load and higher reliability. Despite favourable impacts on traffic, little is known about the effects of such systems on near-road air quality. In this study, an End-To-End (E2E) dynamic distributed routing algorithm in Connected and Automated Vehicles (CAVs) was applied in downtown Toronto, to identify whether benefits to network throughput were associated with lower near-road NO2 concentrations. We observe significant reductions in the emissions of Greenhouse Gases (GHGs) with increased penetration of CAVs. Nonetheless, at times, the emissions of nitrogen oxides (NOx) increased with higher CAVs. Besides, a higher frequency and severity of NO2 hot-spots were observed under a 100% CAV scenario. Impacts of the proposed system on electric energy consumption in a full electric vehicle network were also investigated, indicating that the addition of CAVs that are electric did not contribute to high energy savings. We propose that such new transformative technologies in transportation should be designed with air pollution and public health goals.

Abstract Conversion of carbon contained in the solid residues (tars + biochar) derived from urban biomass gasification named herein TC would allow enhancing the yield of carbon species (CO/CO2) in synthetic gas. For this purpose, three low cost materials have been tested as possible catalysts: iron species (reduced Fe), bone meal (BM), and ashes (ash) recovered from biochar complete oxidation. The parametric study used the following as variables: air GHSV, onset of reaction temperature, reaction time to optimize CO/CO2 molar ratio and tar content in the produced gas. Results showed an autocatalytic effect of biochar leading to the catalytic conversion of approximately 78% of tars by the native metals contained in TC. The catalytic effect was further enhanced by adding Fe, BM, and extra ash. Addition of Fe catalyst resulted in significant heat generation (temperature increase of ca. 500 °C) and a twofold decrease in reaction time to consume all the carbon. Use of ash and BM as catalysts exhibit heat generation comparable to Fe, along with an improved reaction time, complete tars conversion and a CO/CO2 molar ratio to above 1.3 in the produced gas.

SummaryThe German government has adopted a law that requires sewage plants to go beyond the recovery of phosphorus from wastewater and to promote recycling. We argue that there is no physical global short‐ or mid‐term phosphorus scarcity. However, we also argue that there are legitimate reasons for policies such as those of Germany, including: precaution as a way to ensure future generations’ long‐term supply security, promotion of technologies for closed‐loop economics in a promising stage of technology development, and decrease in the current supply risk with a new resource pool.