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In this paper, the performances of two iron-based syngas-fueled chemical looping (SCL) systems for hydrogen (H2) and electricity production, with carbon dioxide (CO2) capture, using different reactor configurations were evaluated and compared. The first investigated system was based on a moving bed reactor configuration (SCL-MB) while the second used a fluidized bed reactor configuration (SCL-FB). Two modes of operation of the SCL systems were considered, namely, the H2 production mode, when H2 was the desired product from the system, and the combustion mode, when only electricity was produced. The SCL systems were modeled and simulated using Aspen Plus software. The results showed that the SCL system based on a moving bed reactor configuration is more efficient than the looping system with a fluidized bed reactor configuration. The H2 production efficiency of the SCL-MB system was 11 % points higher than that achieved in the SCL-FB system (55.1 % compared to 44.0 %). When configured to produce only electricity, the net electrical efficiency of the SCL-MB system was 1.4 % points higher than that of the SCL-FB system (39.9 % compared to 38.5 %). Further, the results showed that the two chemical looping systems could achieve >99 % carbon capture efficiency and emit ~2 kg CO2/MWh, which is significantly lower than the emission rate of conventional coal gasification-based plants for H2 and/or electricity generation with CO2 capture.

Solar Energy Materials and Solar Cells, 116 + (2013) 176-181. doi:10.1016/j.solmat.2013.04.019

Hot water heat stores with stratification are a common technology used in solar energy systems and reuse of waste heat. Adding a PCM module at the top of the water tank would give the system higher storage density, and compensate heat loss in the top layer. The work presented here includes experimental results and numerical simulation of the system using an explicit finite-difference method. Experiments and simulations were carried out using different cylindrical PCM modules. With only 1/16 of the volume of the store being PCM, 3/16 of water at the top of the store was held warm for 50% to 200% longer and the average energy density was increased by 20% to 45%. Furthermore, these 3/16 of water were reheated by the heat from the module after being cooled down in only 20 min.

Searching suitable panchromatic QD sensitizers for expanding the light-harvesting range, accelerating charge separation, and retarding charge recombination is an effective way to improve power conversion efficiency (PCE) of quantum-dot-sensitized solar cells (QDSCs). One possible way to obtain a wide absorption range is to use the exciplex state of a type-II core/shell-structured QDs. In addition, this system could also provide a fast charge separation and low charge-recombination rate. Herein, we report on using a CdTe/CdSe type-II core/shell QD sensitizer with an absorption range extending into the infrared region because of its exciplex state, which is covalently linked to TiO2 mesoporous electrodes by dropping a bifunctional linker molecule mercaptopropionic acid (MPA)-capped QD aqueous solution onto the film electrode. High loading and a uniform distribution of QD sensitizer throughout the film electrode thickness have been confirmed by energy dispersive X-ray (EDX) elemental mapping. The accelerated electron injection and retarded charge-recombination pathway in the built CdTe/CdSe QD cells in comparison with reference CdSe QD-based cells have been confirmed by impedance spectroscopy, fluorescence decay, and intensity-modulated photocurrent/photovoltage spectroscopy (IMPS/IMVS) analysis. With the combination of the high QD loading and intrinsically superior optoelectronic properties of type-II core/shell QD (wide absorption range, fast charge separation, and slow charge recombination), the resulting CdTe/CdSe QD-based regenerative sandwich solar cells exhibit a record PCE of 6.76% (J(sc) = 19.59 mA cm(-2), V(oc) = 0.606 V, and FF = 0.569) with a mask around the active film under a full 1 sun illumination (simulated AM 1.5), which is the highest reported to date for liquid-junction QDSCs.

The transition to a low carbon future is starting to affect landscapes around the world. In order for this landscape transformation to be sustainable, renewable energy technologies should not cause critical trade-offs between the provision of energy and that of other ecosystem services such as food production. This literature review advances the body of knowledge on sustainable energy transition with special focus on ecosystem services-based approaches and methods. Two key issues emerge from this review: only one sixth of the published applications on the relation between renewable energy and landscape make use of the ecosystem service framework. Secondly, the applications that do address ecosystem services for landscape planning and design lack efficient methods and spatial reference systems that accommodate both cultural and regulating ecosystem services. Future research efforts should be directed to further advancing the spatial reference systems, the use of participatory mapping and landscape visualizations tools for cultural ecosystem services and the elaboration of landscape design principles.

Since 2007, a range of new modeling approaches and tools have been developed for sustainability impact assessment (SIA), but a lack of universal acceptance of SIA tools in applied policy making is observed. The current article gives an overview of experiences from several European and international projects, critically reviews the selected SIA tools and then discusses a number of reasons for the observed disconnect of the tools with the potential users. Largely based on the experiences of the presented SIA tools focusing land use policy advice, a decision tree is designed, which may facilitate an adequate, region and developmental phase specific selection of tool-box components for the development of SIA tools in future. Elements to ensure end-user participation are also integrated in the decision tree in order to increase the likelihood of the tool in applied land use policy advice. In addition, the Challenges in SIA tool development and use are further discussed.

Abstract In recent years, the overall energy consumption is increasing significantly and the energy consumption in the building sector represents over 30% of the global ones in developed countries. Thermal energy storage (TES) using phase change materials (PCM), which are materials able to store high amounts of energy as latent heat, is suggested as a possible solution to decrease the energy consumption. The authors of this paper developed materials able to encapsulate/stabilize PCM in addition to isolate an industrial residue from the steel recycling process: electrical arc furnace dust (EAFD). This waste is a hazardous dust, and when it is combined with a polymeric matrix produce dense sheet materials suitable for multilayered constructive systems. In this paper the physical, mechanical, thermal and acoustical characterization of two new materials with EAFD and PCM in a polymeric matrix for constructive system is presented. The results are compared with those obtained for one commercial dense sheet material available in the market, Texsound commercialized by TEXSA (Spain). The new dense sheet materials developed in this paper have similar acoustic properties compared to the results obtained for the commercial material and are competitive with it, even better because the new material incorporates PCM which increases the thermal inertia of final constructive system.

The Vietnamese Mekong Delta (VMD) is one of the world’s most vulnerable deltas to climate change and sea level rise. Adequate understandings of future hydrological changes are crucial for effective water management and risk-proofing, however, this knowledge body is currently very limited. This study quantifies the responses of the VMD’s river flow regime to multiple stimuli, namely future upstream inflow variation, local climate change, and sea level rise. The one-dimensional hydrodynamic model MIKE 11 was used to simulate discharges and water levels across the delta. We developed four scenarios to represent changes in the upstream discharges, precipitation changes and sea level rise, covering the 2036–2065 period. We downscaled climate data and applied three bias-correction methods for five General Circulation Models (GCM), and two Representative Concentration Pathways (RCPs). The climate change projections show similar trends of increasing wet season precipitation and decreasing dry season precipitation. However, cross-scenario variations are sometimes large, depending on the individual GCMs, the RCPs and specific locations. The hydraulic simulation results indicate that, under discharge changes between −20% and +10%, combined with in-delta precipitation variations during the dry season, river discharges at the four representative stations could reduce substantially from −2.5% to −100.2%. During the wet season, the calculated river discharges show increase between 7.3% and 46.7% under four considered scenarios. Substantial changes in the VMD’s river flow regime could have potentially serious implications for water management, especially saltwater intrusion, and therefore calling for timely adaptation measures.