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Abstract The kinetics of methane hydrate decomposition was studied using a semibatch stirred-tank reactor. The decomposition was accomplished by reducing the pressure on a hydrate slurry in water to a value below the three-phase equilibrium pressure at the reactor temperature. The data were obtained at temperatures from 274 to 283 K and pressures from 0.17 to 6.97 MPa. The stirring rates were high enough to eliminate mass-transfer effects. Analysis of the data indicated that the decomposition rate was proportional to the particle surface area and to the difference in the fugacity of methane at the equilibrium pressure and the decomposition pressure. The proportionality constant showed an Arrhenius temperature dependence. An estimate of the hydrate particle diameters in the experiments permitted the development of an intrinsic model for the kinetics of hydrate decomposition.

The design and assessment of net-zero buildings commonly focus exclusively on the operational phase, ignoring the embodied environmental impacts over the building life cycle. An analysis is presented on the consequences of integrating embodied impacts into the assessment of the environmental advantageousness of net-zero concepts. Fundamental issues needing consideration in the design process - based on the evaluation of primary energy use and related greenhouse gas emissions - are examined by comparing three net-zero building design and assessment cases: (1) no embodied impacts included, net balance limited to the operation stage only; (2) embodied impacts included but evaluated separately from the operation stage; and (3) embodied impacts included with the operation stage in a life cycle approach. A review of recent developments in research, standardization activities and design practice and the presentation of a case study of a residential building in Norway highlight the critical importance of performance indicator definitions and system boundaries. A practical checklist is presented to guide the process of incorporating embodied impacts across the building life cycle phases in net-zero design. Its implications are considered on overall environmental impact assessment of buildings. Research and development challenges, as well as recommendations for designers and other stakeholders, are identified.

(Abstract) This paper proposes a new power line communication (PLC) architecture for monitoring and remote control of Distributed Generators (DG) and Energy Storage Systems (ESS) connected to low voltage distribution networks. The final aim is to improve the performance of the PLC link in terms of robustness and efficiency in devices addressing. The proposed solution is based on a concentrator, to be installed in secondary substation, and a new PLC bridge, to be linked both to inverters and interface protection systems of DGs or ESSs. In this way, a communication link is obtained between distribution system operator (DSO) and DG or ESS owners. The proposed system is able to provide advanced functions for the remote control of DGs and ESSs inverters, not only in terms of remote disconnection but also in terms of adjusting the inverter operating modes.

In this paper, we address the problem of determining the optimal day-ahead generation profile for a wind power producer by exploiting wind speed forecasts provided by a meteorological service. In the considered framework, the wind power producer is called to take part in the responsibility of system operation by providing day-ahead generation profiles and undergoing penalties in case of deviations from the schedule. Penalties are applied only if the delivered hourly energy deviates from the schedule more than a given relative tolerance. The optimal solution is obtained analytically by formulating and solving a stochastic optimization problem aiming at maximizing the expected profit. The proposed approach consists in exploiting wind speed forecasts to classify the next day into one of several predetermined classes, and then selecting the optimal solution derived for each class. The performance of the bidding strategy is demonstrated using real data from an Italian wind plant and weather forecasts provided by a commercial meteorological service.

<div class="section abstract"><div class="htmlview paragraph">The introduction of new light-duty vehicle emission limits to comply under real driving conditions (RDE) is pushing the diesel engine manufacturers to identify and improve the technologies and strategies for further emission reduction. The latest technology advancements on the after-treatment systems have permitted to achieve very low emission conformity factors over the RDE, and therefore, the biggest challenge of the diesel engine development is maintaining its competitiveness in the trade-off “CO₂-system cost” in comparison to other propulsion systems. In this regard, diesel engines can continue to play an important role, in the short-medium term, to enable cost-effective compliance of CO₂-fleet emission targets, either in conventional or hybrid propulsion systems configuration. This is especially true for large-size cars, SUVs and light commercial vehicles.</div><div class="htmlview paragraph">In this framework, a comprehensive approach covering the whole powertrain is of primary importance in order to simultaneously meet the performance, efficiency, noise and emission targets, and therefore, further development of the combustion system design and injection system represent important levers for additional improvements. For this purpose, a dedicated 0.5 dm³ single-cylinder engine has been developed and equipped with, a state-of-the-art Euro 6 combustion system, and an advanced common rail fuel injection system (FIS) offering higher flexibility in terms of injection strategy and higher quantity accuracy. Three injector nozzles with different hydraulic flow rates (HF) have been selected and employed for the overall combustion process optimization.</div><div class="htmlview paragraph">The optimization has been performed by means of an extensive DoE-based test campaign in which the engine and FIS operating parameters have been parametrized with the aim to carry out a proper combination in terms of HF and injection strategy. The results at partial load conditions evidence significant advantages in applying an advanced injection pattern, while the HF reduction can significantly improve the smoke emission and combustion noise without fuel consumption penalties. Therefore, a proper combination and optimization of the HF and injection strategy can provide low noise and engine-out smoke while maintaining the rated power performance targets.</div></div>

Abstract For the option of “carbon capture and storage”, an integrated assessment in the form of a life cycle analysis and a cost assessment combined with a systematic comparison with renewable energies regarding future conditions in the power plant market for the situation in Germany is done. The calculations along the whole process chain show that CCS technologies emit per kWh more than generally assumed in clean-coal concepts (total CO2 reduction by 72–90% and total greenhouse gas reduction by 65–79%) and considerable more if compared with renewable electricity. Nevertheless, CCS could lead to a significant absolute reduction of GHG-emissions within the electricity supply system. Furthermore, depending on the growth rates and the market development, renewables could develop faster and could be in the long term cheaper than CCS based plants. Especially, in Germany, CCS as a climate protection option is phasing a specific problem as a huge amount of fossil power plant has to be substituted in the next 15 years where CCS technologies might be not yet available. For a considerable contribution of CCS to climate protection, the energy structure in Germany requires the integration of capture ready plants into the current renewal programs. If CCS retrofit technologies could be applied at least from 2020, this would strongly decrease the expected CO2 emissions and would give a chance to reach the climate protection goal of minus 80% including the renewed fossil-fired power plants.

Abstract Thermal energy storage (TES) will improve the efficiency and output of solar power plants. TES based on thermochemical cycles is an interesting option as thermochemical cycles can provide high energy storage densities and allow longer heat storage time. The use of multivalent solid oxide reduction–oxidation (REDOX) reactions for thermochemical heat storage is a promising option. Several concepts are feasible for coupling solar energy to the redox reaction. Among those a directly irradiated rotary kiln is one of the most interesting because it is able to provide high mass flow rates and high amounts of active material. A solar-heated rotary kiln was set-up and operated in the solar furnace of DLR for thermal reduction and oxidation of cobalt oxide. The redox material was fed into the reactor batch wise and reduced on-sun at temperatures of about 900 °C and re-oxidized off-sun in the same rotary kiln. Both steps were carried out in an air atmosphere. Thirty cycles were performed with one batch showing no evident degradation of the material. The results confirm that the rotary kiln is a feasible reactor set-up for the solar reduction of metal oxides and, hence, for thermochemical energy storage.