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Increasing biogas production in the Three Seas Initiative countries (3SI) is a good way to reduce greenhouse gas emissions and to increase energy self-sufficiency by replacing some of the fossil energy sources. An assessment of the biogas production potential carried out for the 3SI at the NUTS 1 and NUTS 2 level shows that the potential of this energy carrier was stable for the period (from 2010–2021). The results showed that it can cover from approximately 10% (Hungary, Slovakia) to more than 34% (Estonia, Slovenia) of natural gas consumption; moreover, there is strong variation in the value of potential at the regional level (NUTS 2) in most of the countries studied. The biogas production forecast was carried out with the ARIMA model using four regressors, which are GDP, biogas potential utilisation, natural gas consumption and investments in RES (renewable energy sources) infrastructure, including changes in the EU energy policy after 24 February 2022. In the most promising scenario (four regressors), the results obtained for the period from 2022–2030 predict a rapid increase in biogas production in the 3SI countries, from 32.4 ± 11.3% for the Czech Republic to 138.7 ± 27.5% for Estonia (relative to 2021). However, in the case of six countries (Bulgaria, Lithuania, Hungary, Austria, Poland and Romania) the utilisation of 50% of the potential will most likely occur in the fifth decade of the 21st century. The above results differ significantly for those obtained for three regressors, where the highest rise is predicted for Bulgaria at 33.5 ± 16.1% and the lowest for Slovenia, at only 2.8 ± 14.4% (relative to 2021).

Stringent environmental regulations and efforts to improve the shipping operations sustainability have resulted in designing and employing more complex configurations for the ship power plants systems and the implementation of digitalised functionalities. Due to these systems complexity, critical situations arising from the components and subsystem failures, which may lead to accidents, require timely detection and mitigation. This study aims at enhancing the safety of ship complex systems and their operation by developing the concept of an integrated monitoring safety system that employs existing safety models and data fusion from shipboard sensors. Detailed Fault Trees that model the blackout top event, representing the sailing modes of a cruise ship and the operating modes of its plant, are employed. Shipboard sensors’ measurements acquired by the cruise ship alarm and monitoring system are integrated with these Fault Trees to account for the acquired shipboard information on the investigated power plant configuration and its components operating conditions, thus, facilitating the estimation of the blackout probability time variation as well as the dynamic criticality assessment of the power plant components. The proposed concept is verified by using a virtual simulation environment developed in Matlab/Simulink. This study supports the dynamic assessment of the ship power plants and therefore benefits the decision-making for enhancing the plant safety during operations.

The Energy Performance of Buildings Directive (EPBD) has set a target to achieve carbon-neutral building stock and generate 80% of its electricity from renewable sources by 2050. While Model Predictive Control (MPC) can contribute significantly to energy flexibility in buildings, its remote implementation remains relatively unexplored, especially in the residential sector. The purpose of this research is to demonstrate the reliability, robustness, and computational efficiency of a cloud-based application of an MPC called Smart Energy Management (SEM) on a multi-family residential building. The SEM was tested on a virtual building model in TRNSYS using an open-source distributed event streaming platform for data exchange and synchronization. Simplified models for thermal behavior prediction, including an R3C3 model of the building, were developed in C++. The SEM was evaluated in eight scenarios with varying weather conditions, optimization criteria, and runtime periods. The results demonstrate that the SEM maintains stability and robustness over a 2-week period with a 15-minute planning resolution while ensuring thermal comfort. The C++ implementation of the optimization algorithm enables SEM deployment on low-spec servers, supporting cost-effective applications in real buildings with minimal intervention.

Herein, the nitridophosphate Na3V(PO3)3N is synthesized by solid state method. X-ray diffraction (XRD) and Rietveld refinement confirm the cubic symmetry with P213 space group. The material exhibits very good thermal stability and high operating voltage of 4.0 V vs. Na/Na+ due to V3+/V4+ redox couple. In situ X-ray diffraction studies confirm the two-phase (de-)sodiation process to occur with very low volume changes. The refinement of the sodium occupancies reveal the low accessibility of sodium cations in the Na2 and Na3 sites as the main origin for the lower experimental capacity (0.38 eq. Na+, 28 mAh g−1) versus the theoretical one (1.0 eq. Na+, 74 mAh g−1). These observations provide valuable information for the further optimization of this materials class in order to access their theoretical electrochemical performance as a potentially interesting zero-strain and safe high-voltage cathode material for sodium-ion batteries.

As a workable substitute for toxic PbTe-based thermoelectrics, GeTe-based materials are emanating as reliable alternatives. To assess the suitability of LiI as a dopant in thermoelectric GeTe, a prelusive study of thermoelectric properties of GeTe1−xLiIx (x = 0–0.02) alloys processed by Spark Plasma Sintering (SPS) are presented in this short communication. A maximum thermoelectric figure of merit, zT ~ 1.2, was attained at 773 K for 2 mol% LiI-doped GeTe composition, thanks to the combined benefits of a noted reduction in the thermal conductivity and a marginally improved power factor. The scattering of heat carrying phonons due to the presumable formation of Li-induced “pseudo-vacancies” and nano-precipitates contributed to the conspicuous suppression of lattice thermal conductivity, and consequently boosted the zT of the Sb-free (GeTe)0.98(LiI)0.02 sample when compared to that of pristine GeTe and Sb-rich (GeTe)x(LiSbTe2)2 compounds that were reported earlier.

This paper describes a study of the relative influences of different system design decisions upon the performance of an organic Rankine cycle (ORC) used to generate electricity from foundry waste heat. The design choices included concern the working fluid, whether to use a regenerator and the type of condenser. The novelty of the research lies in its inclusion of the influence of both the ORC location and the auxiliary electricity used by the pumps and fans in the ORC power system. Working fluids suitable for high temperature applications are compared, including three cyclic siloxanes, four linear siloxanes and three aromatic fluids. The ORC is modelled from first principles and simulation runs carried out using weather data for 106 European locations and a heat input profile that was derived from empirical data. The impact of design decisions upon ORC nominal efficiency is reported followed by the impact upon annual system efficiency in which variations in heat input and the condition of outdoor air over a year are considered. The main conclusion is that the location can have a significant impact upon the efficiency of ORC systems due to the influence of climate upon the condenser and auxiliary electricity requirements.

The following paper presents thermodynamic and optical investigations of hydrogen-enriched methane combustion, showing the potential of a hydrogen admixture as a means to decarbonize stationary power generation. The optical investigations are carried out through a fisheye optical system directly mounted into the combustion chamber, replacing one exhaust valve. All of the tests were carried out with constant fuel energy producing 16 bar indicated mean effective pressure. The engine under investigation is a port-fueled 4.8 L single-cylinder large-bore research engine. The test series compared the differences between a conventional spark plug and an unscavenged pre-chamber spark plug as an ignition system. The fuel blends under investigation are 5 and 10%V hydrogen mixed with methane and pure natural gas acting as a reference fuel. The thermodynamic results show a beneficial influence of the hydrogen admixture on both ignition systems and for all variations concerning the lean running limit, combustion stability and indicated efficiency, with the most significant influence being visible for the tests using conventional spark plugs. With the unscavenged pre-chamber spark plug and the combustion of the 10%V hydrogen admixture, an increase in the indicated efficiency of 0.8% compared to NG is achievable. The natural chemiluminescence intensity traces were observed to be predominantly influenced by the air–fuel equivalence ratio. This results in a 20% higher intensity for the unscavenged pre-chamber spark plug for the combustion of 10%V hydrogen compared to the conventional spark plug. This is also visible in the evaluations of the flame color derived from the dewarped combustion image series. The investigation of the torch flames also shows a difference in the air–fuel equivalence ratio but not between the different fuels. The results encourage the development of hydrogen-based fuels and the potential to store surplus sustainable energy in the form of hydrogen in existing gas grids.