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Melanin obtained from Aureobasidium pullulans and Cladosporium resinae was an efficient biosorbent for copper. Copper uptake could be expressed using various adsorption isotherms; melanin from A. pullulans obeyed Freundlich and Langmuir isotherms whereas C. resinae melanin followed the BET isotherm indicating a more complex type of adsorption than in A. pullulans. In general, uptake capacities of melanin were greater than for intact biomass and the higher uptake by pigmented rather than albino biomass could be correlated with the presence of melanin. Cu2+ was less readily desorbed from melanin by dilute mineral acids than from intact biomass and again, the relative ease of Cu2+ desorption from pre-loaded pigmented or albino biomass was correlated with the presence or absence of melanin. Mg2+ and Zn2+ appeared to be the most effective cations for desorption with Na+ and K+ the least effective. The addition of melanin to a coppercontaining culture of the albino strain of A. pullulans resulted in some reduction of toxicity.

Abstract Analytical and numerical investigation of methane–air lean combustibility limit (LCL) in reciprocal flow filtration combustion reactor was performed. Practically important parameters (heat loss coefficient, reactor length, pressure, particles size, porosity) were varied and corresponding sets of LCL curves were built. Existence of extremum at LCL – gas flow rate function is found. Numerical study shows that the porous media particle size is the most important factor for LCL control. Smaller particles provide lower LCL and reduce steepness of the growing branch of the LCL-gas flow rate function. For the particles smaller than 2 mm the corresponding LCL line goes down monotonously. High pressure in the system provides better LCL, which may be used for stabilization of the reactors operating at near LCL regimes.

The estimation of leak and break frequencies in piping systems is part of the probabilistic safety assessment of technical plants. In this paper, a statistical method based on the evaluation of German operational experience for piping systems with different diameters is described because an earlier estimation has been updated and extended introducing new methodical aspects and data. A major point is the inclusion of structural reliability models based on fracture mechanics calculation procedures. As an example of application the statistical estimation method for leak and break frequencies of piping systems with a nominal diameter of 50 mm (the volume control system of a German pressurized water reactor) was updated. Moreover, the evaluation of the operational experience was extended to 341 years with respect to cracks, leaks and breaks in the volume control system of German pressurized water reactors (PWR). Using the actual database, new calculations of leak and break frequencies have been performed and the results have been compared with previous values.

Abstract Post-combustion solvent-based carbon capture is a promising technology that potentially can offset the greenhouse gas emissions from fossil-driven power generation systems. The challenge is that CO2 absorption (similar to other CCS technologies) imposes energetic penalties, and constrains the operational flexibility. In this paper, we build upon our recent contributions in the field (Sharifzadeh et al., 2016; Sharifzadeh and Shah, 2016), and study the dynamic response of such process to the electricity load changes in the power plant. The key research question is to investigate if the steady-state integrated process design and control framework applied in the previous studies, can also ensure controllability under a wide range of disturbances. The present study considers the mutual interactions between the power plant and capture process. Other features of interest include the implications of key design and operational decisions such as reboiler temperature, solvent circulation flow rate, solvent concentration and the rate of power load change or CO2 setpoint tracking for flexible process operation. The results suggest that the capture process exhibits a high degree of flexibility and the integrated design and control framework could be the key enabler for the commercialization of post-combustion solvent-based carbon capture.

Abstract A building integrated cooling facade is proposed in this paper. It is a fan-assisted system that consists of two vertical plenums. The first plenum was made of black aluminium transpired plate and a sandtile wall, while the second plenum is formed by the sandtile wall and the building wall. The aluminium plate served as a solar collector and the sandtile wall was an evaporative pad. The reverse side of the sandtile wall that contacted with the air in the second plenum was coated with a water-resistant layer, hence the air was cooled without adding any moisture into it. The facade cooling performance under various operating conditions is investigated through experiment and theoretical analyses. It is found that inlet water temperature is the key factor affecting the cooling performance. In terms of cooling efficiency, the energy consumption to generate 1 kW of cooling that cooling the air to 293 K is only 0.52 W, which is similar to the amount of energy required by some of the solar indirect evaporative cooling and desiccant cooling systems.

Abstract In many cases, hazardous wastes are subject to thermal treatment at elevated temperatures. Some types of wastes do not have a sufficient calorific value to cover the heat demand of the high temperature process. For thermal treatment of e.g. filter residues, dusts, sulfuric acid, aluminium dross, foundry sand, or waste water, supplementary energy supply is needed. The specific energy demand ranges from 0.5 to 2.5 kWh/kg (2–10 MJ/kg). An important aim of process optimisation is the reduction of (fossil) energy consumption and exhaust gas flow. Concentrated solar energy promises advantages when applied to high energy consuming waste treatment processes with regard to substitute fossil or electric energy consumption, to reduce CO2 emissions, and exhaust gas flow. In parallel to conceptional studies, a solar-heated rotary kiln mini-plant has been designed and constructed for tests in the DLR solar furnace. The tests will give indications of boundary conditions for solar thermal treatment or conversion of selected hazardous materials.

Abstract The kinetics of methane hydrate decomposition was studied using a semibatch stirred-tank reactor. The decomposition was accomplished by reducing the pressure on a hydrate slurry in water to a value below the three-phase equilibrium pressure at the reactor temperature. The data were obtained at temperatures from 274 to 283 K and pressures from 0.17 to 6.97 MPa. The stirring rates were high enough to eliminate mass-transfer effects. Analysis of the data indicated that the decomposition rate was proportional to the particle surface area and to the difference in the fugacity of methane at the equilibrium pressure and the decomposition pressure. The proportionality constant showed an Arrhenius temperature dependence. An estimate of the hydrate particle diameters in the experiments permitted the development of an intrinsic model for the kinetics of hydrate decomposition.

Abstract Convective heat transfer at constant heat flux through unconsolidated porous media has been studied both experimentally and theoretically. Heat transfer measurements have been performed for convective heat transfer over a wide range of operational parameters at constant heat fluxes. In addition to heat transfer coefficients, pressure drop and temperature profiles both in radial and axial direction have been recorded. The equations of motion and energy which account for the non-Darcian effect are used to describe the flow and convective heat transfer through the porous medium. Mathematical models for the prediction of heat transfer coefficients and temperature profiles are presented which predict the experimental data with good accuracy.