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Production of biodiesel from yellow grease (waste cooking oil and waste animal fats) is fast emerging as a promising alternative to address the twin challenges before the biodiesel industry today-fluctuation in prices of vegetable oil and the food versus fuel debate. Yellow grease has a high percentage of free fatty acids (FFA) and proves to be an unsuitable feedstock for biodiesel production from commercially viable alkali-catalyzed production systems due to saponification problems.“Green” methodologies based on heterogeneous solid acid catalyzed reactions have the potential to simultaneously promote esterification and transesterification reactions of yellow grease to produce biodiesel without soap formation and offer easy catalyst separation without generation of toxic streams. This paper presents kinetic studies for the conversion of model yellow grease feeds to biodiesel using a heteropolyacid supported on alumina (HSiW/Al2O3) using a batch autoclave. Three model yellow grease feeds were prepared using canola oil with added FFA such as palmitic, oleic and linoleic acid. A pseudo homogeneous kinetic model for the parallel esterification and transesterification was developed. The rate constants and activation parameters for esterification and transesterification reactions for the model yellow grease feeds were determined. The rate constants for esterification are higher than the transesterification rate constants. The kinetic model was validated using the experimental biodiesel data obtained from processing a commercial yellow grease feed. The kinetic model could be used to design novel processes to convert various low-value waste oils, fats and non-food grade oils to sustainable biodiesel. Keywords: Yellow grease, Canola oil, Free fatty acids, Heteropolyacid, Kinetics for esterification and transesterification

This study focuses on formulating the most sustainable concrete by incorporating recycled concrete aggregates and other products retrieved from construction and demolition (C&D) activities. Both recycled coarse aggregates (RCA) and recycled fine aggregates (RFA) are firstly used to fully replace the natural coarse and fine aggregates in the concrete mix design. Later, the cement rich ultrafine particles, recycled glass powder and mineral fibres recovered from construction and demolition wastes (CDW) are further incorporated at a smaller rate either as cement substituent or as supplementary additives. Remarkable properties are noticed when the RCA (4–12 mm) and RFA (0.25–4 mm) are fully used to replace the natural aggregates in a new concrete mix. The addition of recycled cement rich ultrafines (RCU), Recycled glass ultrafines (RGU) and recycled mineral fibres (RMF) into recycled concrete improves the modulus of elasticity. The final concrete, which comprises more than 75% (wt.) of recycled components/materials, is believed to be the most sustainable and green concrete mix. Mechanical properties and durability of this concrete have been studied and found to be within acceptable limits, indicating the potential of recycled aggregates and other CDW components in shaping sustainable and circular construction practices. The authors wish to acknowledge the financial support from EU Horizon 2020 Project VEEP ‘‘Cost-Effective Recycling of C&DW in High Added Value Energy Efficient Prefabricated Concrete Compo-nents for Massive Retrofitting of our Built Environment” (No.723582).

Abstract Transportation de-carbonization is a complex problem involving the economy, population, technology and environment. Implementing the pathway simulation based on systematic methods will help to optimize the transportation sustainability plan. This study’s key motivation is that earlier research ignored the relationship between driving factors and the transmission process. To quantitatively identify the path and process of emission reduction, a hybrid system dynamics STIRPAT-SD model is proposed to explore the transportation optimization’s de-carbonization ability. This study fully considers the composition of elements and subsystems based on the STIRPAT theoretical model and visually shows the system’s feedback relationship. Transportation structural and technical optimization scenarios are set to identify the threshold reduction paths. It is found these optimization strategies have significant de-carbonization effects. And transportation structure policy has the highest de-carbonization efficiency, the emission intensity decreased by 9.1% under the TSS2 scenario (Transportation structure scenario). This study proposes a novelty model combining dynamic simulating processes with a significantly theoretical model to improve simulation and factor composition accuracy. And the joint scenario setting identifies the most effective de-carbonization pathway and clarifies the threshold of all possible pathways. Research findings can effectively track, test, predict the achievement of policy goals, and provide policy optimization references for the sustainable development related to the transportation system in practice.

As a relatively mature technology, biomass molded fuel (BMF) is widely used in distributed and centralized heating in China and has received considerable government attention. Although many BFM incentive policies have been developed, decreased domestic traditional fuel prices in China have caused BMF to lose its economic viability and new policy recommendations are needed to stimulate this industry. The present study built a regionalized net present value (NPV) model based on real production process simulation to test the impacts of each policy factor. The calculations showed that BMF production costs vary remarkably between regions, with the cost of agricultural briquette fuel (ABF) ranging from 86 US dollar per metric ton (USD/t) to 110 (USD/t), while that of woody pellet fuel (WPF) varies from 122 USD/t to 154 USD/t. The largest part of BMF’s cost composition is feedstock, which accounts for up 50%–60% of the total; accordingly a feedstock subsidy is the most effective policy factor, but in consideration of policy implementation, it would be better to use a production subsidy. For ABF, the optimal product subsidy varies from 26 USD/t to 57 USD/t among different regions of China, while for WPF, the range is 36 USD/t to 75 USD/t. Based on the data, a regional BMF development strategy is also proposed in this study.

This study aims to explore the application of fractional order chaotic system (FOCS), based on the T-S fuzzy model, in the design of secure communication (SC) and this SC system’s role in the construction of efficiency evaluation system for dispatching operation of energy saving and power generation under a low carbon economy (LCE). First, the definition of fractional order differential equations and the stability theory of FOCS are discussed. T-S fuzzy control is introduced to analyse the stability of FOCS. Then, based on the adaptive synchronisation theory, the combined FOCS is designed for SC, and the performance of the system constructed here is analysed in a MATLAB environment. Next, an evaluation index system of the dispatching operation effect of energy saving and power generation under LCE is constructed. The confidential communication system constructed here is used to transmit the index data. The particle swarm optimisation (PSO) algorithm is then used to optimise the back propagation neural network (BPNN) model. The BPNN algorithm based on PSO (PSO-BPNN) is obtained, and the evaluation model is constructed. After training this model, it is applied to the evaluation of the dispatching operation effect for energy saving and power generation in 10 provinces in China. The simulation results show that the FOCS based on the T-S fuzzy model can acquire the criterion of system stability. Furthermore, the constructed SC system can effectively undertake the secure transmission of square and sine waves. The performance of the PSO-BPNN model seems to be better than other algorithms. After analysing the data on energy saving and power generation from 10 provinces in China using this model, the comprehensive evaluation value of province 5 is found to be the highest and good (0.802), while that of province 4 is the lowest and general (0.600). Summarising, the FOCS based on T-S fuzzy model constructed here is applied to the design of SC. This can improve the confidentiality of data transmission and reduce the transmission error. Moreover, the BPNN evaluation model based on PSO can effectively achieve the evaluation of the dispatching operation effect of energy saving and power generation under LCE.

Given the global energy and environmental situation, the European Union has been issuing directives with increasingly demanding requirements in term of the energy efficiency in buildings. The international competition of sustainable houses, Solar Decathlon Europe (SDE), is aligned with these European objectives. SDE houses are low energy solar buildings that must reach the near to zero energy houses’ goal. In the 2012 edition, in order to emphasize its significance, the Energy Efficiency Contest was added. SDE houses’ interior comfort, functioning and energy performance is monitored. The monitoring data can give an idea about the efficiency of the houses. However, a jury comprised by international experts is responsible for carrying out the houses energy efficiency evaluation. Passive strategies and houses services are analyzed. Additionally, the jury's assessment has been compared with the behavior of the houses during the monitoring period. Comparative studies make emphasis on the energy aspects, houses functioning and their interior comfort. Conclusions include thoughts related with the evaluation process, the results of the comparative studies and suggestions for the next competitions.

Energy is consumed at every stage of the cycle of water production, distribution, end use, and recycled water treatment. Understanding the nexus of energy and water may help to minimize energy and water consumption and reduce environmental emissions. However, the interlinkages between water and energy have not received adequate attention. To address this gap, this paper disaggregates and quantifies the energy consumption of the entire water cycle process in Beijing. The results of this study show that total energy consumption by water production, treatment and distribution, end use, and recycled water reuse amounts to 55.6 billion kWh of electricity in 2015, or about 33% of the total urban energy usage. While water supply amount increased by only 10% from 2005 to 2015, the related energy consumption increased by 215% due to water supply structural change. The Beijing municipal government plans to implement many water saving measures in the area from 2016 to 2020, however, these policies will increase energy consumption by 74 million kWh in Beijing. This study responds to the urgent need for research on the synergies between energy and water. In order to achieve the goal of low-energy water utilization in the future, water and energy should be integrated in planning and management.