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Aromatization of furan and substituted furans over zeolite catalysts is a promising reaction to convert cellulose-derived compounds into valuable aromatic hydrocarbons and light olefins. A lack of understanding of the reaction mechanism however hinders further development of this process. Here, we propose the reaction mechanism, underlying the chemistry of furan and methanol co-aromatization over HZSM-5 zeolite catalyst. Applying 13C isotope labeling in a combination with NMR spectroscopy and high temporal resolution gas chromatography-mass spectrometry analysis, we demonstrate that aromatization of furan and methanol are not mechanistically separated and can be described within the dual-cycle hydrocarbon pool mechanism. Cofeeding furan with methanol leads to a significant enhancement of light aromatics selectivity and increased catalyst lifetime.

Abstract With the rapid advancement in wearable electronics, energy harvesting devices based on triboelectric nanogenerators (TENGs) have been intensively investigated for providing sustainable power supply for them. However, the fabrication of wearable TENGs still remains great challenges, such as flexibility, breathability and washability. Here, a route to develop a new kind of woven-structured triboelectric nanogenerator (WS-TENG) with a facile, low-cost, and scalable electrospinning technique is reported. The WS-TENG is fabricated with commercial stainless-steel yarns wrapped by electrospun polyamide 66 nanofiber and poly(vinylidenefluoride-co-trifluoroethylene) nanofiber, respectively. Triggered by diversified friction materials under a working principle of freestanding mode, the open-circuit voltage, short-circuit current and maximum instantaneous power density from the WS-TENG can reach up to 166 V, 8.5 µA and 93 mW/m2, respectively. By virtue of high flexibility, desirable breathability, washability and excellent durability, the fabricated WS-TENG is demonstrated to be a reliable power textile to light up 58 light-emitting diodes (LED) connected serially, charge commercial capacitors and drive portable electronics. A smart glove with stitched WS-TENGs is made to detect finger motion in different circumstances. The work presents a new approach for self-powered textiles with potential applications in biomechanical energy harvesting, wearable electronics and human motion monitoring.

Background: The global palm oil market experienced a remarkable boom since the year 2000. Since palm oil can be used for biodiesel production, the global expansion of oil palm cultivation has been associated with the global biofuel boom. Biofuel policies—especially those adopted in the European Union (EU)—have been blamed for the socio-environmental impacts of oil palm expansion. We explore how the global biofuel boom interacts with national geographies and social-economic and political processes to produce country-specific trajectories of biofuel crops expansion. We analyse the expansion of oil palm cultivation in Colombia between 2000 and 2010 from a political ecology perspective. Methods: The analysis is based on a framework that positions expansion of commodity frontiers within the ‘space-of-flows’ and the ‘space-of-place’. Through this approach, we identify the markets and geographies that define the country-specific trajectories of expansion of oil palm in Colombia, and their connections with general patterns of land control. The empirical analysis is based on primary data collected during fieldwork, and on an extensive review of secondary data about the palm oil sector and the socio-environmental effects of oil palm expansion in the country. Results: The contemporary oil palm expansion in Colombia was not specifically influenced by the international biofuel market. Expansion was characterized by an increasing production of palm oil for biodiesel, to supply a policy-driven national biofuel market controlled by national palm oil producers. The evidence shows that this oil palm expansion proceeded through a variety of land control practices that constitute forms of ‘accumulation by dispossession’ and ‘assimilation’. These are embedded in contextual factors that include the agrarian history of Colombia, the armed conflict, and government policies. Conclusions: Our study shows that the ways in which expansion of biofuel crops unfold in each producing country depend not only on the global biofuel market. They are also shaped by the country-specific geographies and political economies. Therefore, research and policies on the global expansion of energy crops should account for the complex and interrelated factors that mediate the specific ways in which the global demand for biofuels creates biofuel crop booms at country level.

Abstract Secondary concentrators are used in solar concentrating systems to redirect solar beams reflected by the primary concentrators to the focal point or line. These components allow to increase the concentrated solar flux density and hence to lower thermal radiation losses. Solar reflectors for secondary concentrators are permanently exposed to environmental conditions, high radiation fluxes and elevated temperatures that potentially cause stress and degradation throughout the time. Therefore, analyzing solar reflectors of secondary concentrators by simulating these conditions is crucial. No previous research works about the durability of solar reflector materials for secondary concentrators have been reported. The present work is focused on studying the degradation of the reflector materials by simulating accelerated aging, caused by several ambient parameters and the effect of concentrated radiation. Both cooled and uncooled systems for secondary concentrators are included in this study. According to results obtained, aluminum reflectors and thin silvered-glass reflectors glued to an aluminum structure showed minimum reflectance losses and structural degradation under the operation conditions of cooled 3D secondary concentrators (tower systems). Following critical aspects to avoid reflector degradation were identified: to select a suitable adhesive material to glue the thin silvered-glass reflector to the support aluminum structure, to properly protect reflectors edges, to design a suitable cooling system and to avoid the combination of high radiation fluxes with mechanical stress. In addition, laminated silvered-glass reflectors have shown to be suitable for uncooled 2D secondary concentrators (Fresnel collectors). Furthermore, a comparison with naturally aged secondary concentrators using silvered-glass reflectors glued to an aluminum structure revealed that the simulated degradation under accelerated conditions performed in this work did reproduce the most frequent degradation patterns suffered in real operating conditions.

This paper introduces a model predictive control (MPC) strategy for the purpose of fuel-optimal operation of a range-extender hybrid vehicle. The modern navigation system nowadays can provide abundant road information. Using this information, the proposed controller solves a global optimization problem offline in order to determine a preset trajectory of the state of charge (SoC). The online MPC uses the resulting SoC trajectory as set-points for the terminal state in every moving horizon. Repeating this process, the optimal energy management along the trip to be traveled can thus be calculated. This proposed control strategy is implemented in the commercial vehicle simulation environment IPG CarMaker. From the first simulation results, the proposed strategy shows a promising fuel saving potential with real-time capability.

This study focuses on formulating the most sustainable concrete by incorporating recycled concrete aggregates and other products retrieved from construction and demolition (C&D) activities. Both recycled coarse aggregates (RCA) and recycled fine aggregates (RFA) are firstly used to fully replace the natural coarse and fine aggregates in the concrete mix design. Later, the cement rich ultrafine particles, recycled glass powder and mineral fibres recovered from construction and demolition wastes (CDW) are further incorporated at a smaller rate either as cement substituent or as supplementary additives. Remarkable properties are noticed when the RCA (4–12 mm) and RFA (0.25–4 mm) are fully used to replace the natural aggregates in a new concrete mix. The addition of recycled cement rich ultrafines (RCU), Recycled glass ultrafines (RGU) and recycled mineral fibres (RMF) into recycled concrete improves the modulus of elasticity. The final concrete, which comprises more than 75% (wt.) of recycled components/materials, is believed to be the most sustainable and green concrete mix. Mechanical properties and durability of this concrete have been studied and found to be within acceptable limits, indicating the potential of recycled aggregates and other CDW components in shaping sustainable and circular construction practices. The authors wish to acknowledge the financial support from EU Horizon 2020 Project VEEP ‘‘Cost-Effective Recycling of C&DW in High Added Value Energy Efficient Prefabricated Concrete Compo-nents for Massive Retrofitting of our Built Environment” (No.723582).

In Cameroon, as in other countries of the Congo basin region, policy processes and activities related to climate change have been hitherto geared mostly towards mitigation and related questions, with limited concern about adaptation issues. However, the increasing vulnerability of Cameroon to climate variability and change makes adaptation significant to its national climate-change policy. Nonetheless, it remains a challenge to make both adaptation and mitigation occupy the same policy space in Cameroon. This paper builds partly on studies carried out in two community forest carbon initiatives in the southern rainforest of Cameroon. It also argues, supported by existing literature on adaptation and mitigation, that mitigation activities have the potential to produce adaptation outcomes; a situation which avoids duplication of efforts and waste of financial and technical resources, if synergetic options are anticipated and planned. However, whether such integrated approaches succeed and are subsequently reflected in national-level climate policy depends on how actors across different sectors and at different levels engage and carry out their roles. The paper discusses these roles and how they can support each other in pursuing integrated initiatives – a context which is vital for Cameroon.