• Energy Research
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Voluntary environmental management programs for firms have become an increasingly popular instrument of environmental policy. However, the literature’s conclusion on the effectiveness of suchprograms is ambiguous, and for the European region there is a lack of evidence based on a large control group. We seek to fill this gap with an evaluation of the Eco-Management and Audit Scheme (EMAS), introduced in 1995 by the European Union as a premium certification of continuous pro-environmental efforts above regulatory minimum standards. It is more demanding than other voluntary programsdue to annual public reports of the environmental performance and targets for improvements. We use official firm-level production census data on the German manufacturing sector, a major energy consumer and emitter in Europe. To account for the self-selection of firms, we combine the Coarsened Exact Matching approach with a Difference-in-Differences estimation. Our results do not suggest reductions of firms’ CO2 intensity and energy intensity neither before nor after certification. Moreover, program participants do not increase renewable energy consumption or investments into the protection of the environment and climate. Our results are robust to a variety of checks and call into question the effectiveness of the EMAS program concerning these particular outcome variables.

Voluntary environmental management programs for firms have become an increasingly popular instrument of environmental policy. However, the literature’s conclusion on the effectiveness of suchprograms is ambiguous, and for the European region there is a lack of evidence based on a large control group. We seek to fill this gap with an evaluation of the Eco-Management and Audit Scheme (EMAS), introduced in 1995 by the European Union as a premium certification of continuous pro-environmental efforts above regulatory minimum standards. It is more demanding than other voluntary programsdue to annual public reports of the environmental performance and targets for improvements. We use official firm-level production census data on the German manufacturing sector, a major energy consumer and emitter in Europe. To account for the self-selection of firms, we combine the Coarsened Exact Matching approach with a Difference-in-Differences estimation. Our results do not suggest reductions of firms’ CO2 intensity and energy intensity neither before nor after certification. Moreover, program participants do not increase renewable energy consumption or investments into the protection of the environment and climate. Our results are robust to a variety of checks and call into question the effectiveness of the EMAS program concerning these particular outcome variables.

Abstract In many cases, hazardous wastes are subject to thermal treatment at elevated temperatures. Some types of wastes do not have a sufficient calorific value to cover the heat demand of the high temperature process. For thermal treatment of e.g. filter residues, dusts, sulfuric acid, aluminium dross, foundry sand, or waste water, supplementary energy supply is needed. The specific energy demand ranges from 0.5 to 2.5 kWh/kg (2–10 MJ/kg). An important aim of process optimisation is the reduction of (fossil) energy consumption and exhaust gas flow. Concentrated solar energy promises advantages when applied to high energy consuming waste treatment processes with regard to substitute fossil or electric energy consumption, to reduce CO2 emissions, and exhaust gas flow. In parallel to conceptional studies, a solar-heated rotary kiln mini-plant has been designed and constructed for tests in the DLR solar furnace. The tests will give indications of boundary conditions for solar thermal treatment or conversion of selected hazardous materials.

Abstract In many cases, hazardous wastes are subject to thermal treatment at elevated temperatures. Some types of wastes do not have a sufficient calorific value to cover the heat demand of the high temperature process. For thermal treatment of e.g. filter residues, dusts, sulfuric acid, aluminium dross, foundry sand, or waste water, supplementary energy supply is needed. The specific energy demand ranges from 0.5 to 2.5 kWh/kg (2–10 MJ/kg). An important aim of process optimisation is the reduction of (fossil) energy consumption and exhaust gas flow. Concentrated solar energy promises advantages when applied to high energy consuming waste treatment processes with regard to substitute fossil or electric energy consumption, to reduce CO2 emissions, and exhaust gas flow. In parallel to conceptional studies, a solar-heated rotary kiln mini-plant has been designed and constructed for tests in the DLR solar furnace. The tests will give indications of boundary conditions for solar thermal treatment or conversion of selected hazardous materials.

AbstractChemical looping combustion is a highly efficient CO2 separation technology without direct contact between combustion air and fuel. A metal oxide is used as an oxygen carrier in dual fluidized beds to generate clean CO2. The use of biomass is the focus of current research because of the possibility of negative CO2 emissions and the utilization of biogenic carbon. The most commonly proposed OC are natural ores and residues, but complete combustion has not yet been achieved. In this work, the direct utilization of CLC exhaust gas for methane synthesis as an alternative route was investigated, where the gas components CO, CH4 and H2 are not disadvantageous but benefit the reactions in a methanation step. The whole process chain, the coupling of an 80 kWth pilot plant with gas cleaning and a 10 kW fluidized bed methanation unit were for this purpose established. As OC, ilmenite enhanced with limestone was used, combusting bark pellets in autothermal operation at over 1000 °C reaching high combustion efficiencies of up to 91.7%. The fuel reactor exhaust gas was mixed with hydrogen in the methanation reactor at 360 °C and converted with a methane yield of up to 97.3%. The study showed especially high carbon utilization efficiencies of 97% compared to competitor technologies. Based on the experimental results, a scale-up concept study showed the high potential of the combination of the technologies concerning the total efficiency and the adaptability to grid injection. Graphical Abstract

AbstractChemical looping combustion is a highly efficient CO2 separation technology without direct contact between combustion air and fuel. A metal oxide is used as an oxygen carrier in dual fluidized beds to generate clean CO2. The use of biomass is the focus of current research because of the possibility of negative CO2 emissions and the utilization of biogenic carbon. The most commonly proposed OC are natural ores and residues, but complete combustion has not yet been achieved. In this work, the direct utilization of CLC exhaust gas for methane synthesis as an alternative route was investigated, where the gas components CO, CH4 and H2 are not disadvantageous but benefit the reactions in a methanation step. The whole process chain, the coupling of an 80 kWth pilot plant with gas cleaning and a 10 kW fluidized bed methanation unit were for this purpose established. As OC, ilmenite enhanced with limestone was used, combusting bark pellets in autothermal operation at over 1000 °C reaching high combustion efficiencies of up to 91.7%. The fuel reactor exhaust gas was mixed with hydrogen in the methanation reactor at 360 °C and converted with a methane yield of up to 97.3%. The study showed especially high carbon utilization efficiencies of 97% compared to competitor technologies. Based on the experimental results, a scale-up concept study showed the high potential of the combination of the technologies concerning the total efficiency and the adaptability to grid injection. Graphical Abstract

Growing concerns over the use of limited fossil fuels and their negative impacts on the ecological niches have facilitated the exploration of alternative routes. The use of conventional plastic material also negatively impacts the environment. One such green alternative is polyhydroxyalkanoates, which are biodegradable, biocompatible, and environmentally friendly. Recently, researchers have focused on the utilization of waste gases particularly those belonging to C1 sources derived directly from industries and anthropogenic activities, such as carbon dioxide, methane, and methanol as the substrate for polyhydroxyalkanoates production. Consequently, several microorganisms have been exploited to utilize waste gases for their growth and biopolymer accumulation. Methylotrophs such as Methylobacterium organophilum produced highest amount of PHA up to 88% using CH4 as the sole carbon source and 52–56% with CH3OH. On the other hand Cupriavidus necator, produced 71–81% of PHA by utilizing CO and CO2 as a substrate. The present review shows the potential of waste gas valorization as a promising solution for the sustainable production of polyhydroxyalkanoates. Key bottlenecks towards the usage of gaseous substrates obstructing their realization on a large scale and the possible technological solutions were also highlighted. Several strategies for PHA production using C1 gases through fermentation and metabolic engineering approaches are discussed. Microbes such as autotrophs, acetogens, and methanotrophs can produce PHA from CO2, CO, and CH4. Therefore, this article presents a vision of C1 gas into bioplastics are prospective strategies with promising potential application, and aspects related to the sustainability of the system.