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Abstract. The impact of multiphase reactions involving nitrogen dioxide (NO2) and aromatic compounds was simulated in this study. A mechanism (CAPRAM 2.4, MODAC Mechanism) was applied for the aqueous phase reactions, whereas RACM was applied for the gas phase chemistry. Liquid droplets were considered as monodispersed with a mean radius of 0.1 µm and a liquid content (LC) of 50 µg m-3. The multiphase mechanism has been further extended to the chemistry of aromatics, i.e. reactions involving benzene, toluene, xylene, phenol and cresol have been added. In addition, reaction of NO2 with dissociated hydroxyl substituted aromatic compounds has also been implemented. These reactions proceed through charge exchange leading to nitrite ions and therefore to nitrous acid formation. The strength of this source was explored under urban polluted conditions. It was shown that it may increase gas phase HONO levels under some conditions and that the extent of this effect is strongly pH dependent. Especially under moderate acidic conditions (i.e. pH above 4) this source may represent more than 75% of the total HONO/NO2 - production rate, but this contribution drops down close to zero in acidic droplets (as those often encountered in urban environments).

Bioplastics are alternatives of conventional petroleum-based plastics. Bioplastics are polymers processed from renewable sources and are biodegradable. This study aims at conducting an environmental impact assessment of the bioprocessing of agricultural wastes into bioplastics compared to petro-plastics using an LCA approach. Bioplastics were produced from potato peels in laboratory. In a biochemical reaction under heating, starch was extracted from peels and glycerin, vinegar and water were added with a range of different ratios, which resulted in producing different samples of bio-based plastics. Nevertheless, the environmental impact of the bioplastics production process was evaluated and compared to petro-plastics. A life cycle analysis of bioplastics produced in laboratory and petro-plastics was conducted. The results are presented in the form of global warming potential, and other environmental impacts including acidification potential, eutrophication potential, freshwater ecotoxicity potential, human toxicity potential, and ozone layer depletion of producing bioplastics are compared to petro-plastics. The results show that the greenhouse gases (GHG) emissions, through the different experiments to produce bioplastics, range between 0.354 and 0.623 kg CO2 eq. per kg bioplastic compared to 2.37 kg CO2 eq. per kg polypropylene as a petro-plastic. The results also showed that there are no significant potential effects for the bioplastics produced from potato peels on different environmental impacts in comparison with poly-β-hydroxybutyric acid and polypropylene. Thus, the bioplastics produced from agricultural wastes can be manufactured in industrial scale to reduce the dependence on petroleum-based plastics. This in turn will mitigate GHG emissions and reduce the negative environmental impacts on climate change.

The construction industry is considered as one of the least productive, highest energy consuming, and least digitized industries. The Lean Management (LM) philosophy became a significant way for eliminating non-value-added activities and wastes during a building’s lifecycle. However, studies have shown that philosophies are not efficient by themselves to solve the issues of the construction industry. They need to be supported with the appropriate technologies and tools. Therefore, the integrated use of Building Information Modelling (BIM) with LM or Value Engineering (VE) were proposed in the literature. Nonetheless, it was also seen that BIM can provide more insights and improvements when BIM is integrated with data analysis tools to analyze BIM data. In the literature, the synergies between these concepts are generally addressed pairwise, and there is no comprehensive framework which identifies their relationships. Therefore, this study aims to develop a maturity framework that facilitates the adoption of LM, VE, BIM, and Big Data Analytic (BDA) concepts to address long-standing productivity and digitalization issues in the Architecture, Engineering, and Construction (AEC) industry. Design Science Research (DSR) methodology and its three-cycle view (relevance, rigor, and design cycle) were applied to build the proposed maturity framework. Two interviews were performed to identify and observe research problem in relevance cycle. In the rigor cycle, a comprehensive literature review was performed to create a base for the development of the maturity framework. In addition to the developed base of the framework, lean processes were added to this cycle. In the design cycle, the developed framework was evaluated and validated by five experts through face-to-face interviews. The importance of employer’s requirements to adopt the proposed methodologies, the negative impact of change orders, the importance of pre-construction phases to facilitate value creation and waste elimination, and the usage of common data environment with BIM were identified as the prominent application and adaptation issues.

Introduction. The problem of Ukraine's economic development in modern conditions is directly related to the implementation of the Ukraine–European Union Association Agreement, so the national economy is facing new opportunities and challenges, including the lack of effective mechanisms to restrict timber exports. The research aimed at assessing the effectiveness of the export bans to the EU. Aim and tasks. The aim of the paper is to study the mechanisms of regulation of the timber market and their export to the EU. Results. The impact of the imposed moratorium on the declared goals is analyzed in the paper. Analyzed statistics show no effect moratorium on the reduction of deforestation and halt exports of unprocessed timber. It is also impossible to make a clear conclusion about the positive impact of the moratorium on the supply of raw materials of domestic enterprises woodworking and furniture industries. However, within the structure of Ukrainian exports, the share of products of woodworking and furniture industries has increased. This was due to the reduction of Ukrainian export volumes against the background of increasing the share of exports of timber and wood products, as well as the resumption of sales of the furniture industry. Conclusions. A study of the ban on raw wood showed that in general, the effect of the moratorium imposed is not obvious, since the number of woodworking enterprises has increased and the level of employment in these sectors has increased. Ukraine requires the adoption of a comprehensive targeted program that would combine measures to develop both the woodworking and forest industries. The national interest of Ukraine is the preservation and restoration of forests, and the moratorium introduced is an example of how partial, fragmentary unsystematic decisions are made. The practical significance of the results allows to analyze existing and find new alternative export balance, ensuring equal opportunities and non-discrimination between domestic and European Union market.

The article is devoted to main theoretical and practical questions concerning “green” investments in logistics infrastructure objects. This type of investments has certain peculiarities as it deals with the sphere which is related to any kind of business and human’s activity. Logistic infrastructure forms mobility. But no significant change in a separate facility will not give a significant result without a support to the relevant network and the highest intellectual level of its use. Planning of logistic infrastructure should be performed in such way that the positive effect on economic growth was maximal, and the negative impact on the environment is minimal. Thant’s why improving logistics infrastructure facilitates achieving sustainable goals as it works simultaneously for economic, environmental and social development. Thus it is extremely important to implement such tool from “green” economy concept as “green” investments towards logistics infrastructure objects. There were analyzed different theoretical approaches to the definition of “green” investments in the paper. The result of deep research of worlds’ best practical trends for “green” investing in logistics infrastructure objects is provided. There studied separately mentioned tendencies for all subtypes of hard logistics infrastructure: transport (electrification of vehicles, low-carbon transport systems, sustainable fuels), warehouse (automation, distribution centers decentralization, energy-efficient equipment and construction), packaging (suitable for processing packaging materials, moving from plastic to more environmental types of packaging), information infrastructure (energy-efficient servers, cloud computing, reducing the number of toxic materials and water required for the production of electronic devices), customs (The Green Customs Initiative), social (smart containers, automated food waste tracking systems and automated technologies of optical scanning). Also were studied main instruments to attract necessary finance support for “green” investments and analyzed ways how to implement them in Ukrainian market with its peculiarities.

The adoption of clean cooking technologies goes beyond mere product acquisition and requires attention to issues of cooking traditions, user engagement, gender dynamics, culture, and religion to effect correct and consistent use.