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AbstractMembrane Technology and Research, Inc. has proposed a hybrid system combining amine scrubbing with membrane technology to reduce energy cost. Previous studies of CO2 absorption mainly focused on coal-fired flue gas with 12% CO2. However, in the hybrid process, the CO2 in the flue gas can be enriched to 20%. Natural gas turbines will have flue gas with as little as 3% CO2。 Based on the arrangement, the hybrid amine/membrane system provides a gas to the system that has double the CO2 concentration of normal flue gas, reduces the volume of gas sent to the capture unit, or reduces the removal requirements for the capture unit.The objective of this work is to minimize the total energy use of stripping concentrated piperazine (PZ) at rich loading when treating flue gas from 3 to 20% inlet CO2. The base-case stripping configuration is the advanced flash stripper with warm rich bypass and cold rich exchanger bypass. . This configuration includes two split cross-exchangers in series, a convective steam heater, a smaller stripper column, a low residence time flash tank, and stripping at high temperature to produce CO2 at 5 to 17bar. Rich loading in 5 and 8m PZ was varied from 0.37 to 0.43mol CO2/mol N. For each rich loading, lean loading was optimized to minimize the total equivalent work. The “Independence” model for PZ in Aspen Plus® was used to simulate the stripping performance.Because 5m PZ has a lower viscosity than 8m PZ, it can achieve a reduced approach temperature in the cross exchanger. The total energy performance for 5m PZ is practically the same as 8m PZ, even though the capacity of 5m PZ is lower. Significantly more energy is required to regenerate solvents with lower rich loading. As CO2 rich loading increases, the equivalent work requirement decreases for the same loading difference between rich and lean.Stripping data for 24 cases, including heat duty, equivalent work, CO2 output pressure, and optimal cold and warm rich bypass were used to build a correlation with CO2 rich and lean loading. The Second Law efficiency based on the ratio of stripping minimum work and total ideal work was introduced to make the most of stripping work. The Second Law efficiency has a maximum value at a specific CO2 loading.

AbstractBio-syngas from gasification of sugarcane bagasse is one of the most promising sources for renewable energy. As an agriculture-based biomass, sugarcane bagasse has a high content of moisture (46-52%), fibrous (43-52%) and low bulk density (80-120kg/m3). This quality of bagasse will tend to initiate agglomeration and cause de-fluidization. It will disturb the gasification process and finally will decrease yield and quality of syn-gas. Its chracteristics in low quality can be improved by pretreatment, i.e., torrefaction process, addressed by slow heating of biomass on wet or dry conditions on atmosphere pressure for 1hour before it is used as feedstock gasification.This preliminary work features an experimental investigation of torrefaction process of Indonesian sugarcane cane bagasse. Temperature of torrefaction varies from 150, 175, 200, 225, 250 and 300°C. For bagasse gasification process, the optimum temperature of dry torrefaction is 150°C. At this temperature, yield of syngas will higher than other torrefaction temperature. Temperature of dry torrefaction will give energy saving opportunities than that's of wet torrefaction (180°C, 1 hr).Analysis ultimate and proximate also indicate that sugarcane bagasse with temperature torrefaction 150°C give better result than other torrefaction's temperature in high content of hydrogen and low content of carbon.

AbstractAlthough the road-map of the oxy-fuel process seems to be very advanced, there are still plenty of open questions. One of the significant ones is the corrosive behaviour of the heat exchanger surfaces. The Institute of Combustion and Power Plant Technology, University of Stuttgart, performs research on the fireside corrosion under oxy-fuel and conventional combustion conditions for the current and supercritical power plants considering the influence of combustion modus, gas atmosphere and fly ash deposits on the waterwall and superheater surfaces. Since the oxy-fuel-combustion atmosphere is composed of recirculated flue gases and pure oxygen, significantly higher concentrations of CO2, SO2 and H2O are present compared to the conventional combustion of coal with air as an oxidizer. In the here presented study the influence of an oxy-fuel combustion of a hard-coal on the surface of selected superheater materials is discussed and compared to the results obtained for lignite. Especially the interactions between the flue gas atmosphere, ash deposits and heat exchanger materials are studied in detail. The investigation encompassed in this paper has been focused on impacts of oxide-scale growth, carbon enrichment of the materials and sulphur-induced corrosion.Increased sulphur-induced corrosion has been observed in samples exposed to the oxy-combustion atmosphere. The noticed higher depth of corrosive attack of the oxy-fuel samples might be explained by a higher partial pressure of SO2 which is characteristic for oxy-fuel process. Moreover in certain cases the sulphur might be released by the deposits. Beside that, the oxy-fuel samples were exposed to much higher partial pressures of carbon dioxide comparing to the air-case leading apparently to rapid and massive internal carbon enrichment in the oxide scale. Moreover dependence between the chromium content and oxidation ability of the austenitic materials surfaces was noticed under oxy-fuel conditions.

AbstractOver the past 35 years, the oil and gas industry has developed many technology improvements and operating practices for injecting carbon dioxide (CO2) for enhanced oil recovery (EOR). Over this time, the US oil and gas industry has operated over 13,000 CO2 EOR wells, over 3,500 miles of high pressure CO2 pipelines and has injected over 600 million tons of CO2 without any significant safety or environmental endangerment events. Today, the US produces over 245,000 barrels of oil per day as a direct result of CO2 EOR. This presentation will describe many of the technical improvements and operational practices that have been developed as a result of the oil and gas industry’s experiences with CO 2 EOR. When these technologies and practices are applied, operators can expect facility and wellbore integrity at levels equivalent to those seen for conventional oil an d gas operations. Many of the technologies and practices that have been developed for CO2 EOR may have applicability in carbon capture and storage (CCS) projects, recognizing however, that each project should be designed to meet its site specific conditio ns. The CO2 EOR experiences of the oil and gas industry represent the largest collective base of technical information available on CO2 injection and, as such, provide valuable information for development and implementation of CCS field projects as they move forward.

AbstractThe future European energy supply system will have a high share of renewable energy sources (RES) to meet the greenhouse gas emission policy of the European Commission. Such a system is characterized by the need for a strongly interconnected energy transport grid as well as a high demand of energy storage capacities to compensate the time fluctuating characteristic of most RE generation technologies. With the RE generators at the location of high harvest potential, the appropriate dimension of storage and transmission system between different regions, a cost efficient system can be achieved. To find the preferred target system, the optimization tool GENESYS (Genetic Optimization of a European Energy System) was developed. The example calculations under the assumption of 100% self-supply, show a need of about 2,500 GW RES in total, a storage capacity of about 240,000 GWh, corresponding to 6% of the annual energy demand, and a HVDC transmission grid of 375,000 GWkm. The combined cost for generation, storage and transmission excluding distribution, was estimated to be 6.87 ct/kWh.

The European Geosciences Union (EGU) brings together geoscientists from all over the world covering all disciplines of the Earth, planetary and space sciences. This geoscientific interdisciplinarity is needed to tackle the challenges of the future. One major challenge for humankind is to provide adequate and reliable supplies of affordable energy and other resources in efficient and environmentally sustainable ways. This Energy Procedia issue provides an overview of the contributions of the Division on Energy, Resources & the Environment (ERE) at the EGU General Assembly 2017.

Abstract This research is conducted to determine the limiting values of the geometric concentration when used with solar thermal system (thermoelectric generator) (TEG) to maintain desired hot and cold side temperatures for power generation. Experiments were conducted to determine the optimum solar concentration (aperture area/target area) using a thermoelectric generator sandwiched between the target plate and passive heat sink. A computer model is developed to solve the energy balance equations and find the optimum values for geometric concentration. It was observed that for the single configuration of heat sink and thermoelectric generator in a system, the trend of temperature difference between the hot and cold sides remain the same at different geometric concentrations. The optimum geometric concentration is determined for heat sinks in study. It is observed that with solar radiation intensity of 800 W/m2 and heat sink fin length of 0.15m the optimum geometric concentration is 13.

AbstractState of the art technologies like air-to-water heat pumps have become popular because of their high efficiencies and their supply by electricity rather than by gas or oil. As a direct result of this supply substitution and due to high load- shifting potential, electricity demand of heat pumps have to be taken into account into energy management strategies of the overall building. In this paper a new controller is discussed, which has predictive and adaptive properties and is able to optimize the running-times of non-modulating heat pumps.