• Energy Research
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Abstract. The impact of multiphase reactions involving nitrogen dioxide (NO2) and aromatic compounds was simulated in this study. A mechanism (CAPRAM 2.4, MODAC Mechanism) was applied for the aqueous phase reactions, whereas RACM was applied for the gas phase chemistry. Liquid droplets were considered as monodispersed with a mean radius of 0.1 µm and a liquid content (LC) of 50 µg m-3. The multiphase mechanism has been further extended to the chemistry of aromatics, i.e. reactions involving benzene, toluene, xylene, phenol and cresol have been added. In addition, reaction of NO2 with dissociated hydroxyl substituted aromatic compounds has also been implemented. These reactions proceed through charge exchange leading to nitrite ions and therefore to nitrous acid formation. The strength of this source was explored under urban polluted conditions. It was shown that it may increase gas phase HONO levels under some conditions and that the extent of this effect is strongly pH dependent. Especially under moderate acidic conditions (i.e. pH above 4) this source may represent more than 75% of the total HONO/NO2 - production rate, but this contribution drops down close to zero in acidic droplets (as those often encountered in urban environments).

Bioplastics are alternatives of conventional petroleum-based plastics. Bioplastics are polymers processed from renewable sources and are biodegradable. This study aims at conducting an environmental impact assessment of the bioprocessing of agricultural wastes into bioplastics compared to petro-plastics using an LCA approach. Bioplastics were produced from potato peels in laboratory. In a biochemical reaction under heating, starch was extracted from peels and glycerin, vinegar and water were added with a range of different ratios, which resulted in producing different samples of bio-based plastics. Nevertheless, the environmental impact of the bioplastics production process was evaluated and compared to petro-plastics. A life cycle analysis of bioplastics produced in laboratory and petro-plastics was conducted. The results are presented in the form of global warming potential, and other environmental impacts including acidification potential, eutrophication potential, freshwater ecotoxicity potential, human toxicity potential, and ozone layer depletion of producing bioplastics are compared to petro-plastics. The results show that the greenhouse gases (GHG) emissions, through the different experiments to produce bioplastics, range between 0.354 and 0.623 kg CO2 eq. per kg bioplastic compared to 2.37 kg CO2 eq. per kg polypropylene as a petro-plastic. The results also showed that there are no significant potential effects for the bioplastics produced from potato peels on different environmental impacts in comparison with poly-β-hydroxybutyric acid and polypropylene. Thus, the bioplastics produced from agricultural wastes can be manufactured in industrial scale to reduce the dependence on petroleum-based plastics. This in turn will mitigate GHG emissions and reduce the negative environmental impacts on climate change.

The construction industry is considered as one of the least productive, highest energy consuming, and least digitized industries. The Lean Management (LM) philosophy became a significant way for eliminating non-value-added activities and wastes during a building’s lifecycle. However, studies have shown that philosophies are not efficient by themselves to solve the issues of the construction industry. They need to be supported with the appropriate technologies and tools. Therefore, the integrated use of Building Information Modelling (BIM) with LM or Value Engineering (VE) were proposed in the literature. Nonetheless, it was also seen that BIM can provide more insights and improvements when BIM is integrated with data analysis tools to analyze BIM data. In the literature, the synergies between these concepts are generally addressed pairwise, and there is no comprehensive framework which identifies their relationships. Therefore, this study aims to develop a maturity framework that facilitates the adoption of LM, VE, BIM, and Big Data Analytic (BDA) concepts to address long-standing productivity and digitalization issues in the Architecture, Engineering, and Construction (AEC) industry. Design Science Research (DSR) methodology and its three-cycle view (relevance, rigor, and design cycle) were applied to build the proposed maturity framework. Two interviews were performed to identify and observe research problem in relevance cycle. In the rigor cycle, a comprehensive literature review was performed to create a base for the development of the maturity framework. In addition to the developed base of the framework, lean processes were added to this cycle. In the design cycle, the developed framework was evaluated and validated by five experts through face-to-face interviews. The importance of employer’s requirements to adopt the proposed methodologies, the negative impact of change orders, the importance of pre-construction phases to facilitate value creation and waste elimination, and the usage of common data environment with BIM were identified as the prominent application and adaptation issues.

In a former study, a German lignite extract exhibited toxicity to Danio rerio and Caenorhabditis elegans and was shown to have mutagenic and dioxin-like activity. Besides the comparatively low content of known toxic polycyclic aromatic hydrocarbons (PAH), highly intensive peaks of m/z 274 and m/z 324 were observed during the chromatographic analysis. These compounds are assumed to be alkylated chrysenes and picenes (3,3,7-trimethyl-1,2,3,4-tetrahydrochrysene, 1,2-(1'-isopropylpropano)-7-methylchrysene and an isomer of the latter, 1,2,9-trimethyl-1,2,3,4-tetrahydropicene and 2,2,9-trimethyl-1,2,3,4-tetrahydropicene). These compounds are intermediates in the diagenetic formation of chrysene and picene from triterpenoids. Due to their general high abundance in lignites and the toxicity observed for the lignite extract, the mechanism-specific toxicity and bioavailability of these compounds were investigated in the present study using the approach of effect-directed analysis. After the separation of the compounds from other PAH, their mutagenic activity (Ames Fluctuation test) and dioxin-like activity (EROD activity) were studied. Both, mutation induction factor (up to 2.9±2.7) and dioxin-like activity (Bio-TEQ of 224±75 pg/g; represents the amount (pg) 2,3,7,8-tetrachlorodibenzo-p-dioxin per g coal that would provoke the same toxic effect) were rather low. Bioavailability estimated by the bioaccumulation test with Lumbriculus variegatus was also very limited. Based on the obtained results, the environmental risk of the highly abundant alkylated chrysenes and picenes in lignites is concluded to be low.

The adoption of clean cooking technologies goes beyond mere product acquisition and requires attention to issues of cooking traditions, user engagement, gender dynamics, culture, and religion to effect correct and consistent use.

Spatial planning has to deal with trade-offs between various stakeholders’ wishes and needs as part of planning and management of landscapes, natural resources and/or biodiversity. To make ecosystem services (ES) trade-off research more relevant for spatial planning, we propose an analytical framework,which puts stakeholders, their land-use/management choices, their impact on ES and responses at the centre. Based on 24 cases from around the world, we used this framing to analyse the appearance and diversity of real-world ES trade-offs. They cover a wide range of trade-offs related to ecosystem use, including: land-use change, management regimes, technical versus nature-based solutions, natural resource use, and management of species. The ES trade-offs studied featured a complexity that was far greater than what is often described in the ES literature. Influential users and context setters are at the core of the trade-off decision-making, but most of the impact is felt by non-influential users. Provisioning and cultural ES were the most targeted in the studied trade-offs, but regulating ES were the most impacted. Stakeholders’ characteristics, such as influence, impact faced, and concerns can partially explain their position and response in relation to trade-offs. Based on the research findings, we formulate recommendations for spatial planning.