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Alkylated furan derivatives, such as 2,5-dimethylfuran (2,5-DMF) and 2-methylfuran (2-MF), have shown, at laboratory scale, a relatively high tendency to form soot. However, soot emissions from die...

Alkylated furan derivatives, such as 2,5-dimethylfuran (2,5-DMF) and 2-methylfuran (2-MF), have shown, at laboratory scale, a relatively high tendency to form soot. However, soot emissions from die...

AbstractAlloy anodes composed of microsized particles receive increasing attention recently, which outperform the nanostructured counterparts in both the manufacturing cost and volumetric energy density. However, the pulverization of particles and fracture of solid electrolyte interphase (SEI) during cycling brings about fast capacity degradation. Herein, it is shown how normally considered fragile SEI can become highly elastic through electrolyte chemistry regulation. Compared to the SEI constructed in classic carbonate electrolyte, the atomic force microscopy tests reveal that the one built in ether‐based electrolyte doubles the maximum elastic strain to accommodate the repeated swelling‐contracting. Such an SEI effectively encapsulates the microsized Sb anodes to prevent the capacity loss from particle isolation. Coupled with an intercalation‐assisted alloying reaction mechanism, a sustained capacity of ≈573 mAh g−1 after 180 cycles at 0.1 A g−1 with outstanding initial Coulombic efficiency is obtained, which is among the highest values achieved in K‐ion batteries. This study emphasizes the significance of building robust SEI, which offers the opportunity to enable stable microsized alloy anodes.

AbstractAlloy anodes composed of microsized particles receive increasing attention recently, which outperform the nanostructured counterparts in both the manufacturing cost and volumetric energy density. However, the pulverization of particles and fracture of solid electrolyte interphase (SEI) during cycling brings about fast capacity degradation. Herein, it is shown how normally considered fragile SEI can become highly elastic through electrolyte chemistry regulation. Compared to the SEI constructed in classic carbonate electrolyte, the atomic force microscopy tests reveal that the one built in ether‐based electrolyte doubles the maximum elastic strain to accommodate the repeated swelling‐contracting. Such an SEI effectively encapsulates the microsized Sb anodes to prevent the capacity loss from particle isolation. Coupled with an intercalation‐assisted alloying reaction mechanism, a sustained capacity of ≈573 mAh g−1 after 180 cycles at 0.1 A g−1 with outstanding initial Coulombic efficiency is obtained, which is among the highest values achieved in K‐ion batteries. This study emphasizes the significance of building robust SEI, which offers the opportunity to enable stable microsized alloy anodes.

With fewer emissions, higher efficiency, and quicker response than traditional coal-fired thermal power plants, the combined-cycle units (CCUs), as gas-fired generators, have been increasingly adapted in the U.S. power system to enhance the smart grids operations. Meanwhile, due to the inherent uncertainties in the deregulated electricity market, e.g., intermittent renewable energy output, unexpected outages of generators and transmissions, and fluctuating electricity demands, the electricity price is volatile. As a result, this brings challenges for an independent power producer (served in the self-scheduling mode) owning CCUs to maximize the total profit when facing the significant price uncertainties. In this paper, a data-driven risk-averse stochastic self-scheduling approach is presented for the CCUs that participate in the real-time market. The proposed approach does not require the specific distribution of the uncertain real-time price. Instead, a confidence set for the unknown distribution is constructed based on the historical data. The conservatism of the proposed approach is adjustable based on the amount of available data. Finally, numerical studies show the effectiveness of the proposed approach.

With fewer emissions, higher efficiency, and quicker response than traditional coal-fired thermal power plants, the combined-cycle units (CCUs), as gas-fired generators, have been increasingly adapted in the U.S. power system to enhance the smart grids operations. Meanwhile, due to the inherent uncertainties in the deregulated electricity market, e.g., intermittent renewable energy output, unexpected outages of generators and transmissions, and fluctuating electricity demands, the electricity price is volatile. As a result, this brings challenges for an independent power producer (served in the self-scheduling mode) owning CCUs to maximize the total profit when facing the significant price uncertainties. In this paper, a data-driven risk-averse stochastic self-scheduling approach is presented for the CCUs that participate in the real-time market. The proposed approach does not require the specific distribution of the uncertain real-time price. Instead, a confidence set for the unknown distribution is constructed based on the historical data. The conservatism of the proposed approach is adjustable based on the amount of available data. Finally, numerical studies show the effectiveness of the proposed approach.

The concept and a new method for the shielded development of bottom gas hydrates have been proposed, the technological phases and constructive elements of their implementation have been substantiated. The research provides for the realization of the idea suggesting the simultaneous dissociation of the vast areas of a gas hydrate deposit, management of the targeted process of the penetration of methane recovered from gas hydrates into water space and its accumulation under the extensive gas-collecting shield wherefrom it is removed by bottom pipe transportation facilities. To do hydraulic fracturing, a well is drilled into the plane of the junction of the surface of a gas hydrate deposit and the rocks of a roof, the open system of fissures in the rocks of a roof is made through which produced gas is released to a gas-collecting blanket in a water.

The concept and a new method for the shielded development of bottom gas hydrates have been proposed, the technological phases and constructive elements of their implementation have been substantiated. The research provides for the realization of the idea suggesting the simultaneous dissociation of the vast areas of a gas hydrate deposit, management of the targeted process of the penetration of methane recovered from gas hydrates into water space and its accumulation under the extensive gas-collecting shield wherefrom it is removed by bottom pipe transportation facilities. To do hydraulic fracturing, a well is drilled into the plane of the junction of the surface of a gas hydrate deposit and the rocks of a roof, the open system of fissures in the rocks of a roof is made through which produced gas is released to a gas-collecting blanket in a water.

202407 bcch ; Others ; National Natural Science Foundation of China ; Published ; 24 months ; Green (AAM)